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Modified paligorskite water purification agent and preparation thereof

A kind of stone water purifier and palygorskite technology, which is applied in the field of modified palygorskite water purifier and its preparation, and can solve the problems of weak adsorption performance and the like

Inactive Publication Date: 2010-06-16
NORTHWEST NORMAL UNIVERSITY +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0016] The purpose of the present invention is to provide a modified palygorskite water purifier with strong adsorption capacity for organic matter in order to overcome the shortcoming that ordinary palygorskite is not strong in adsorption to organic matter

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0044] Purification of palygorskite: Add 100 parts of palygorskite to 500 parts of water, mechanically stir for 10 minutes, let it stand for 1 minute, take only the upper and middle turbid liquid, centrifuge, dry at 110 ° C, grind into powder, and pass through a 320-mesh sieve ,spare.

[0045] Modification of palygorskite: Add 0.1 part of vinyltrimethoxysilane and 0.1 part of cetyltrimethylammonium chloride to 100 parts of purified palygorskite, stir and mix evenly, then add Water at 60°C, so that the solid-liquid ratio of the system is 1 / 5. After stirring mechanically at room temperature for 5 minutes, add 1.0 parts of activated carbon powder to the mixture system, continue stirring for 5 minutes, and add 0.5 parts of activated carbon powder while stirring. The concentration is 0.1mol / L sodium hydroxide solution, then dried at 110°C, and ground into a powder with a particle size of 100 mesh to 250 mesh.

Embodiment 2

[0047] The purification of palygorskite: same as embodiment 1.

[0048] Modification of palygorskite: Add 0.3 part of γ-aminopropyltriethoxysilane and 0.05 part of cetyltrimethylammonium bromide to 100 parts of net purified palygorskite, stir and mix evenly, and add Add water at 70°C to the mixing system to make the solid-to-liquid ratio of the system 1 / 4. After stirring mechanically at room temperature for 10 minutes, add 2.0 parts of activated carbon powder to the mixture system, continue stirring for 2 minutes, and add 0.3 parts of concentration while stirring. It is 1mol / L sodium hydroxide solution, then dried at 100°C, and ground into a powder with a particle size of 100 mesh to 250 mesh.

Embodiment 3

[0050] The purification of palygorskite: same as embodiment 1.

[0051] Modification of palygorskite: Add 0.5 part of γ-(2,3-epoxypropoxy)propyl trimethoxysilane to 100 parts of net purified palygorskite, 0.01 part of dodecyl trimethyl chloride Ammonium, after stirring and mixing evenly, add water at 80°C to the mixing system to make the solid-to-liquid ratio of the system 1 / 2, mechanically stir at room temperature for 8 minutes, then add 2.0 parts of activated carbon powder to the mixture system, and continue stirring for 8 minutes , Add 0.2 parts of 0.5mol / L sodium hydroxide solution while stirring, then dry at 105°C, and grind it into a powder with a particle size of 100 mesh to 250 mesh.

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PUM

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Abstract

The invention provides a modified palygorskite purifier with strong organic adsorption capacity, the method is that certain amount of silane coupling agent, alkyl ammonium salt, water, activated carbon powder and sodium hydroxide solution are added into purified palygorskite, then stirred, dried and grinded into powders to obtain the modified palygorskite purifier of the invention. Experiment shows that the modified palygorskite purifier prepared by the invention has strong adsorption, extremely strong decolourising property, good deodorization capacity and extremely high processing capacity of oil contamination waste water with high concentration, wherein, compared with activated carbon particles, the waste water treatment speed is much quicker by the modified palygorskite purifier and the cost is much lower.

Description

technical field [0001] The invention belongs to the technical field of sewage treatment, and relates to a water purifying agent for waste water treatment, in particular to a modified palygorskite water purifying agent and a preparation method thereof. Background technique [0002] Chemical wastewater treatment methods currently mainly include: physical and chemical methods, chemical methods, and biological methods. [0003] Physical and chemical treatment methods include: filtration, adsorption, coagulation, etc., mainly for the treatment of high-concentration wastewater. [0004] ① The main equipment used in the filtration method is a screen and a filter. The disadvantage of the screen is that it is easy to clog. The filter material is the core part of the filter. Commonly used filter materials are: quartz sand, dolomite particles, anthracite particles and polystyrene foamed plastic balls. Filtration treatment of wastewater is fast and cheap, but the treatment is not th...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J20/30C02F1/28
Inventor 雷自强李天辉张哲赵旭涛秦勇程海
Owner NORTHWEST NORMAL UNIVERSITY