Germanium-painting structure for insulating layer of mixed graphical monocrystaline silicon as well as method and application thereof
A technology of germanium on insulating layer and on insulating layer, applied in the field of germanium on insulating layer structure and its fabrication, can solve the problems of difficulty in obtaining high-quality single crystal germanium compared with silicon, large leakage current, small forbidden band width, etc. The effect of optoelectronic integration, reducing leakage current and improving working speed
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Embodiment 1
[0018] Embodiment 1: The preparation method of low-temperature GeOI structure film.
[0019] Steps such as figure 1 Shown:
[0020] 1. Boron ion, hydrogen ion implantation: Firstly, the dose is implanted on the germanium wafer with a dose of 5×10 15 cm -2 of boron ions, and then implanted 5×10 16 cm -2 The hydrogen ions 1 and 10 are defect layers caused by co-implantation of boron ions and hydrogen ions into germanium wafers.
[0021] 2. Plasma bonding: Chemically clean the silicon wafer covered with the silicon dioxide film 2 and the germanium wafer injected with perboron hydride ions to remove the surface sticking dirt, and then activate the surface with low-temperature nitrogen plasma after drying. The nitrogen plasma activation conditions are: air pressure 0.4 mbar, plasma power 100W, high-purity nitrogen gas flow rate 80 sccm. After activation, rinse with deionized water for 6 seconds, rinse with megasonic water for 6 seconds and then spin dry, then bond the two pie...
Embodiment 2
[0024]Embodiment 2: A method for preparing a GeOI structure of mixed patterned single crystal silicon.
[0025] 1. Pattern the germanium (GeOI) thin film on the insulating layer obtained in Example 1 according to the requirements, and use the same window mask to etch the top layer of germanium and the lower oxide layer. Reactive ion etching or wet etching is used to remove the top germanium layer and the underlying silicon dioxide insulating buried layer to expose the patterned bottom substrate (100) silicon.
[0026] 2. Use ultra-high vacuum chemical vapor deposition (UHVCVD) to carry out epitaxy of single crystal silicon in the etched window to obtain a GeOI structure containing patterned silicon, in which the single crystal silicon is in the (100) crystal orientation.
[0027] 3. Use CMP to remove the excess epitaxial silicon and silicon dioxide protective layer on the top layer of germanium, and polish the surface, and finally get the following figure 1 (a) shown.
Embodiment 3
[0028] Embodiment 3: GeOI structures of different insulating buried layers and preparation of silicon on patterned insulating layers with different crystal orientations.
[0029] 1. In embodiment 1, can select to deposit the substrate silicon chip of different insulating buried layers, as silicon nitride, aluminum nitride, a kind of of aluminum oxide or diamond-like carbon, or the compound structure that is formed by them to improve buried layer thermal conductivity. The crystal orientation of the substrate silicon wafer determines the crystal orientation of the epitaxial silicon, which can be (110) or (100). (100) substrates can be selected for electron-type working devices on patterned silicon, and (110) substrates can be selected for hole-type working devices.
[0030] 2. Similar to the method of embodiment 2, the germanium (GeOI) film on the insulating layer obtained in embodiment 1 is patterned photolithography according to the requirements, and the window of the epitaxi...
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Abstract
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