The invention discloses a cold rolling work roller used for non-ferrous metal calendaring and a preparing method of the cold rolling work roller and belongs to the field of cold rolling roller materials. The cold rolling roller comprises, by weight percent, 1.65%-1.92% of C, 0.32%-0.40% of Si, 1.25%-1.60% of Mn, 4.6%-6.5% of Cr, 1.55%-2.40% of Ni, 0.5%-1.0% of Mo, 4.30%-5.4% of W, 1.40%-1.65% of V, 0.3%-0.45% of Zr, 0.40%-0.65% of Ag, 0.20%-0.35% of Zn, smaller than or equal to 0.04% of S, smaller than or equal to 0.03% of P and the balance Fe. A preparing method of the cold rolling work roller comprises the steps that annealing treatment is conducted on a forging blank firstly, then rough turning is conducted, then semifinishing is conducted after quenching and tempering treatment, then tempering is conducted again after heat treatment, and finally the roller is obtained through finish grinding. The roller has high strength and high wear resistance, meanwhile, the roller has good heat conductivity and heat dissipation, heat distribution of the roller is even in the rolling process, local overheat is effectively avoided, the probability of metal calendaring material sticking can be lowered, the service life of the roller is prolonged, and the quality of rolled products is improved.