The invention relates to a white organic electroluminescent device and a preparation method thereof. The device consists of an ITO glass substrate, a buffer layer, a cavity transport layer, a single-subject blue light layer, a double-subject red light layer, an electronic transport layer and a composite cathode sequentially. Each structural layer is prepared by a vacuum evaporation method. In the structure of the invention, a luminous layer consists of the single-subject blue light layer and the red light layer with a double-subject structure, and the subject of the blue light layer and one of the subjects of the red light layer are made of the same material, and the other material of the subject of the red light layer is the same as the material of the electronic transport layer. The device with the structure has higher luminous efficiency, can effectively disperse excitons, enhances carrier infusion and transport balance, and inhibits color error and efficiency reduction under a higher drive current. With the structure, the white organic electroluminescent device with the structure can be widely applied on a hi-fi organic full-color display device.