106 results about "Cesium bromide" patented technology

A lamp unit for emitting near-infrared light by electric discharge, has: a hollow discharge tube; a cesium halide enclosed in the hollow of the discharge tube; a near-infrared penetration filter covering around the discharge tube. The cesium halide may include at least one of cesium iodide and cesium bromide. Also, an indium halide and thallium halide may further be enclosed in the hollow discharge tube.

The invention relates to a method for preparing a perovskite LED device based on surface ligand control, including the following steps: applying an organic solution of a hole injection layer materialto the surface of a conductive substrate, and forming a hole injection layer after annealing; dissolving cesium bromide, lead bromide and phenethylamine bromide in an organic solvent under the effectof a 3-(decyl dimethyl ammonium) propane-1-sulfonic acid inner salt surfactant to obtain a perovskite precursor solution, applying the perovskite precursor solution to the surface of the hole injection layer and obtaining a perovskite film after annealing; treating the surface of the perovskite film with an alkylamine organic solution to form a light-emitting layer; and successively preparing an electron transport layer, an electron injection layer and a metal cathode electrode on the surface of the light-emitting layer. The method of the invention is simple and convenient, has a wide range ofmaterials and good repeatability, and can achieve the device performance. Through surface ligand exchange, the flatness and uniformity of the perovskite film are improved, the formation of defects iseffectively suppressed, and the overall performance of the device is significantly improved.

The present invention provides an all-inorganic perovskite solar cell based on transition metal ions doped CsPbBr<3> and a preparation method and an application thereof. Specifically, the invention isthat conductive glass is first spin-coated with an electron transfer layer and subsequently spin-coated with a lead bromide solution mixed with transition metal ions, then is spin-coated with a cesium bromide solution repeatedly; the non-porous perovskite film with a high crystallinity and a large grain size is prepared; and finally the all-inorganic perovskite solar cell based on transition metal ions doped CsPbBr<3> is assembled by blade coating of carbon back electrode. The invention reduces the defect density in the perovskite film by doping transition metal ions, simultaneously the energy band structure is adjusted; the energy loss of charge migration is reduced; and the separation, extraction and transfer of photogenerated charges and charge recombination are reduced, thereby the photoelectric conversion efficiency and long-term operation stability of the cell are improved. The invention has the advantages such as simple and feasible preparation method, large optimization spaceof material combination, no noble metal back electrode or hole transporting layer and low cost.

The invention belongs to the technical field of display of fully-organic perovskite quantum dots, and discloses a CsPbBr3 (cesium-lead-bromide) perovskite quantum dot fluorescent glass for display ofwide color gamut and a preparation method and application thereof. The CsPbBr3 perovskite quantum dot fluorescent glass comprises the following components in percentage by mole: 0 to 45% of SiO2 (silicon dioxide), 0 to 45% of GeO2 (germanium dioxide), 30 to 40% of B2O3 (boron oxide), 2 to 8% of Al2O3 (aluminum oxide), 3 to 7% of MCO3 (metal carbonate), 1 to 5% of ZnO (zinc oxide), 5 to 15% of CsBr(cesium bromide) or Cs2CO3 (cesium carbonate), 2 to 10% of PbBr2 (lead bromide) or PbO (lead oxide), and 3 to 15% of NaBr (sodium bromide) or KBr (potassium-bromide), wherein M is Ca (calcium) or Sr(strontium); the sum of the components in percentage by mole is 100%. The CsPbBr3 perovskite quantum dot fluorescent glass has the advantages that the technology is simple, and the operation is easy;after in-situ crystallization, the quantum efficiency is higher, the light emitting stability is obviously improved, and the broad application prospect is realized.

The invention belongs to the technical field of photoelectric functional materials and particularly relates to a phase-change-controllable totally-inorganic perovskite thin film preparation method anddevice application. The method comprises the steps that (1), precursor lead bromide and cesium bromide are placed into a vapor deposition device correspondingly, a substrate is placed in a depositionarea, and vacuum pumping is performed on the whole device; (2), an inert gas is introduced into the vapor deposition device; (3), the deposition temperature and deposition time are set, the deposition temperature is selected from 500-800 DEG C, and at the different deposition temperature, perovskite thin film has different composition and crystal forms. The phase-change-controllable totally-inorganic perovskite thin film preparation method and the device application adopt a chemical vapor deposition method, are simple in process condition, easy to control accurately and suitable for industrial production; meanwhile, the thin film has good uniformity and has good adhesiveness and spreadability with the substrate material, and the prepared optoelectronic thin film has broad application prospects; and by means of change of the deposition temperature, controllable growth of perovskite phase from CsPb2Br5 to CsPbBr3 is realized, and a photoelectric detector prepared on base of the perovskite thin film obtained by the phase-change-controllable totally-inorganic perovskite thin film preparation method shows good photoelectric response and switching characteristics.

The invention discloses a thermal battery electrolyte with low melting point and high electric conductivity and a preparation method thereof. The thermal battery electrolyte is composed of the following component in percentage by weight: 25%-35% of analytically pure lithium bromide (LiBr), 10%-22% of analytically purepatassium bromide (KBr), 45%-53% of analytically pure cesium bromide (CsBr) and 8%-13% of analytically pure lithium iodide (LiI). The thermal battery electrolyte with low melting point and high electric conductivity is prepared by sintering a eutectic salt composed by the four inorganic salts (LiBr, KBr, CsBr and LiI) according to a certain proportion under protection of an inert gas; the eutectic melting point is lower than 200 DEG C; and the electric conductivity is greater than 1.8S/cm at 500 DEG C. The thermal battery electrolyte with low melting point and high electric conductivity can obviously prolong working time of thermal cells, as well as reduce the surface temperature of thermal cells at work.

The invention discloses a method for preparing a layered structure inorganic perovskite negative electrode material by using a gas phase method, and relates to the technical field of preparation of lithium ion battery negative electrode materials. The method comprises: sequentially or simultaneously depositing lead bromide and cesium bromide on a copper foil substrate under a vacuum condition through a gas phase method, and carrying out heating annealing in air to obtain the layered structure inorganic perovskite negative electrode material. According to the present invention, according to theprinciples of physical vapor deposition and chemical vapor deposition, inorganic lead bromide and cesium bromide are used as raw materials and are deposited on the surface of the copper foil substrate through heating evaporation, the evaporation rate, the deposition thickness and the thickness ratio are regulated, and the subsequent annealing treatment is performed to prepare the dense and uniform pure inorganic perovskite material. With the applications of the layered structure inorganic perovskite negative electrode material in lithium ion battery negative electrode materials, good thermodynamic stability and excellent physical and chemical properties can be achieved, and the process is simple.

The invention discloses a preparation method of a two-dimensional inorganic perovskite anode material for a lithium battery. The preparation method comprises the following steps of adding lead bromideand cesium bromide into N,N-dimethylformamide, heating and stirring, and introducing protective gas in the stirring process, so as to obtain a mixture; drying the mixture under the vacuum condition,so as to obtain a precursor material; adding toluene into the precursor material, centrifuging and separating, and drying the obtained centrifuged solid material under the vacuum condition, so as to obtain the two-dimensional inorganic perovskite anode material for the lithium battery. The preparation method of the two-dimensional inorganic perovskite anode material for the lithium battery has theadvantages that the simple one-step synthesis technology is adopted; by performing simple dissolving and extracting process, the perovskite material with high purity and high crystallizing degree canbe obtained; the problems of complicated preparation technology of graphitizing and carbon coating at high temperature and higher cost in the conventional anode material of the lithium battery are solved.

The invention discloses a method for preparing a two-dimensional inorganic perovskite negative electrode material by solid-liquid phase reaction. The method comprises the following steps of adding lead bromide and cesium bromide into N,N-dimethylformamide, heating and stirring, and drying under the vacuum condition, so as to obtain precursor powder; mixing the precursor powder and the lead bromide, performing ball milling, grinding, and drying under the vacuum condition, so as to obtain the two-dimensional inorganic perovskite negative electrode material. The method for preparing the two-dimensional inorganic perovskite negative electrode material by the solid-liquid phase reaction has the advantages that by adopting the simple solution synthesizing and ball milling technology, the precursor material is in contact with an interface in the high-energy impacting process, and then reacts, so as to obtain the inorganic perovskite material with high crystallizing degree; the problems of complicated preparation technology and higher cost due to graphitizing and carbon coating required by the existing negative electrode material of the lithium ion battery at high temperature are solved; the large-batch synthesizing preparation purpose is realized, the production process of the negative electrode material is greatly shortened, and the material cost is greatly reduced.

The invention discloses a method for preparing a pure inorganic perovskite film under assistance of polyethylene glycol. The method comprises steps as follows: a polyethylene glycol solution is mixed with a solution containing lead bromide and cesium bromide and stirred at room temperature, a mixed liquid is obtained, then the mixed liquid is subjected to spin coating and thermal treatment sequentially, and the pure inorganic perovskite film is obtained; alternatively, lead bromide and cesium bromide are directly dissolved in the polyethylene glycol solution serving as a solvent and stirred at room temperature, and a mixed liquid is obtained; the mixed liquid is subjected to spin coating and thermal treatment sequentially, and the pure inorganic perovskite film is obtained. The preparation process is simple, the product can be obtained only through one-step spin coating and thermal treatment, industrial production is facilitated, the prepared pure inorganic perovskite film has a compact and flat surface, has the quantum efficiency nearly 3 times that of a film without polyethylene glycol and can be widely applied to solar cells, laser and LEDs.

The invention discloses a method for synthesizing CsPbBr3 nanocrystal through centrifugal stirring. The method comprises the following steps: dissolving cesium bromide and lead bromide into dimethyl sulfoxide, then transferring to a centrifuge for centrifugation, standing after completion of the centrifugation, removing a supernatant, washing the dimethyl sulfoxide, filtering, and performing vacuum drying to obtain CsPbBr3 nanocrystal powder. The CsPbBr3 nanocrystal synthesized by the method provided by the invention has high fluorescence efficiency, can be unquenched for a long time at high temperature, has a wide application prospect; meanwhile, by the method provided by the invention, a technology is simple, any surface modifier and any toxic solvent are added, environment friendlinessis achieved, raw materials are cheap, operation is convenient, the efficiency is high, and industrial production is facilitated.

The invention discloses a composite perovskite material with CsPbBr3 doped in CsPb2Br5 and a preparation method thereof. The doped perovskite material is formed by doping a small amount of CsPbBr3 ina CsPb2Br5 material. The design of the preparation method provided by the invention is skillful, firstly, a metal organic framework Pb-MOF taking lead as a framework is synthesized by utilizing a trimesic acid ligand and lead ions, then a cesium bromide aqueous solution and the Pb-MOF react under an ultrasonic condition in an alcoholic solution, and after the Pb-MOF is dissociated in the reaction,a composite material with a small amount of CsPbBr3 doped in CsPb2Br5 is obtained. The synthesis process has few steps, the process is easy to implement, heating and inert gas protection are not needed, and energies are saved. Used synthetic solvents are only pure water and ethanol and are environment-friendly, and little pollution is caused to the environment.

The invention belongs to the technical field of nano materials and inorganic perovskite light-emitting materials, and particularly relates to an all-bromo perovskite blue light quantum dot based on arecrystallization theory and a preparation method of the all-bromo perovskite blue light quantum dot. The preparation method comprises the following steps: preparing a precursor solution by a one-potmethod, taking cesium bromide and lead bromide as reactants, taking oleic acid and oleylamine as ligands, and taking N, Ndimethylformamide (DMF) as a solvent; adding a proper amount of methylbenzene into the precursor solution to form a mixed solution, so that the solution system is in a supersaturated state; at the moment, a small amount of the mixed solution is taken out, methylbenzene with thevolume being 1050 times that of the mixed solution is injected again, the CsPbBr3 blue light quantum dots which are extremely small in size and approximately uniform in size are obtained under the recrystallization effect, the fluorescence quantum yield reaches up to 87.20%, and the obtained emission peak wavelength ranges from 460-480 nm. The method skillfully uses the principle, is simple to operate, quick and efficient, and provides a new thought and a new method for the synthesis of the high-performance blue light material.

The invention provides an all-inorganic perovskite solar cell based on an inorganic perovskite nanocrystalline interface layer and a preparation method and an application thereof. The method is characterized in that the lead bromide is spin-coated on a surface of a conductive glass-supported titanium dioxide electron transport layer by the multi-step spin coating technique, a high-purity CsPbBr3 light absorbing layer is prepared by spin coating of cesium bromide in multiple steps, n-hexane solution with the inorganic perovskite nanocrystals is then spin-coated onto the CsPbBr3 layer for interfacial modification, and lastly, a carbon coated back cell is assembled into the all-inorganic perovskite solar cell. The method is advantaged in that high hole conductivity and energy level adjustability of the inorganic perovskite nanocrystal are fully utilized, electron-hole separation is promoted, energy loss is reduced, perovskite is treated with the n-hexane solvent, the perovskite grain sizeis increased, defect density and charge recombination are reduced, energy conversion efficiency of the cell is effectively improved, the preparation process is simple, cost is controllable, the material optimization space is large, and the commercial production prospect is further wide.

The invention discloses a red perovskite light-emitting diode based on mixed halogen and a preparation method thereof. The light-emitting diode sequentially comprises a transparent substrate, an anode, a hole injection layer, a hole transport layer 1, a hole transport layer 2, a perovskite light-emitting layer, an electron transport layer, an electron injection layer and a cathode, wherein the perovskite light-emitting layer is prepared by spin-coating a perovskite precursor solution; dropwise adding an anti-solvent in the spin coating process, wherein the perovskite precursor solution is prepared by dissolving cesium iodide CsI, cesium bromide CsBr, lead bromide PbBr2, lead iodide PbI2, organic ammonium bromide salt LBr and organic ammonium iodide salt LI in a polar solvent. By combininglarge-size organic cations with mixed halogens, the generation of a non-luminous active perovskite phase is inhibited, the movement of halogen ions is reduced, and the spectral stability is realized while the brightness and efficiency of the red perovskite LED are improved.

Belonging to the technical field of preparation of semiconductor nanomaterials, the invention discloses a method for efficient synthesis of Cs2AgBr3 non-lead all-inorganic perovskite. The method includes: firstly mixing cesium bromide and silver bromide according to a molar ratio of 2:1, then adding tri-n-octyl phosphorus, performing grinding, gradually hardening the mixture from fluffy faint yellow powder, and attaching the mixture to the wall of a container, gradually turning the faint yellow powder to white powder along with the grinding, performing monitoring by a 302nm ultraviolet lamp inthe grinding process, and stopping the action when the brightness of the product does not increase any more; and subjecting the obtained product to heat treatment in a vacuum oven at 80-300DEG C for3h, and then conducting freezing treatment at a temperature ranging from -10DEG C to -50DEG C for 1h-3h, thus obtaining the Cs2AgBr3 non-lead all-inorganic perovskite with improved fluorescence yield.The method provided by the invention has the advantages of short time, easy operation and suitability for large-scale production.

The invention relates to a method for synthesizing copper-based perovskite powder by a low-temperature solvent method. The method comprises the following steps: adding CsX and CuX into a polar organicmixed solution, and stirring for 4-6 hours at 40-70 DEG C, wherein the polar organic mixed solution is a mixed solution of N, N-dimethylformamide (DMF)and dimethyl sulfoxide (DMSO), the CsX is cesiumchloride, cesium bromide or cesium iodide, and the CuX is copper chloride, copper bromide or copper iodide. According to the synthesis process, constant-temperature growth on a hot plate is not needed, synthesis is directly conducted on a magnetic stirrer, the synthesis process has the advantages of being short in manufacturing period, low in cost, simple in growth step, environmentally friendlyand the like, and Cs3Cu2X5 powder with high crystallization quality is separated out within 5 hours.

The invention discloses a preparation method of an inorganic perovskite derivative phase used as a negative electrode material for lithium ions, which relates to the technical fields of preparation and research of the negative electrode material of lithium ion batteries and the like. The precursor of lead bromide and cesium bromide was evaporated by vacuum thermal deposition process and depositedon the copper foil of cathode current collector. The cathode material was homogeneous and dense by subsequent heating and baking. The invention utilizes the principle of chemical solid state reactionand thermal evaporation vapor deposition, Using inorganic lead bromide and cesium bromide as raw materials, the pure inorganic perovskite materials were prepared by vacuum heating and evaporation on current collector copper foil substrate. The evaporation rate of precursor material was adjusted and the thickness and thickness ratio of the precursor material were adjusted during the reaction. Applying it to the cathode material of lithium ion battery, it exhibits good thermodynamic stability and excellent physicochemical properties, and the process is simple.

An electro-optical switch includes an optical assembly arranged to transmit laser-radiation. The optical assembly comprises an active optical crystal. On one of two opposite surfaces of the crystal is an optical window formed from a material having a refractive index lower than the material of the crystal. Heat deposited, as a result of transmission of the laser-radiation, at the surface of the crystal in contact with the widow is transferred to the window, thereby reducing the potential for optical damage to the crystal surface. The window is sufficiently thick that it has an odd integer multiple of quarter-wavelengths optical thickness at a wavelength about equal to a wavelength of the laser-radiation, thereby behaving as an antireflection device for the crystal at that wavelength. In one embodiment of the optical assembly, the active optical crystal is a cadmium telluride crystal and the window is formed from cesium bromide.

The invention provides a preparation method and an application of a CsPbBr3 inorganic perovskite film. The preparation method of the CsPbBr3 inorganic perovskite film comprises the steps of firstly, preparing a magnesium doped titanium dioxide compact layer by adopting a mode of chemical bath deposition, and then depositing lead bromide and cesium bromide on the magnesium doped titanium dioxide compact layer according to a two-step deposition process by adopting ultrasonic spraying. The prepared CsPbBr3 inorganic perovskite film is enabled to be generated in a large area, and the application range of the CsPbBr3 inorganic perovskite film is improved. According to the invention, the magnesium element is taken as an effective doping agent and introduced into the titanium dioxide compact layer in a simple way, thereby enabling the Fermi level of titanium dioxide to move up, thus optimizing the interface energy level structure between a CsPbBr3 perovskite layer and a titanium dioxide electron transport layer, increasing the free carrier concentration of the film, enabling the resistance of TiO2 to be reduced, and reducing the series resistance of the whole device. The photoelectric conversion efficiency of all-inorganic perovskite solar cells doped with magnesium can reach up to 5.75%.

The present document describes a screening composition comprising a marker compound, chosen from at least one of iodine, and fluorescein; eosin Y, erythrosine, ponceau S, calcein, a catalyst, chosen from at least one boron trioxide (B₂O₃), potassium (K), Gallium (III) oxide (Ga₂O₃), Nickel (II) oxide (NiO), Vanadium (V) oxide (V₂O₅), magnesium oxide (MgO), a bismuth oxide chosen from bismuth subcarbonate [Bi₂O₂(CO₃)], bismuth chloride oxide (BiClO), and bismuth oxide (Bi₂O₃), cesium bromide (CsBr), lanthanum (III) oxide (La₂O₃), molybdenum (VI) oxide (MoO₃), neodymium oxide (Nd₂O₃), Nickel (II) carbonate anhydrous (NiCO₃); and a pigment, chosen from at least one of scandium (III) oxide (Sc₂O₃), Lead (IV) oxide (PbO₂), Sulfur (S) powder, and Tungsten (VI) oxide (WO₃), chromium (III) oxide (Cr₂O₃), copper (II) oxide (CuO), copper (I) oxide (Cu₂O), iron (III) oxide (Fe₂O₃), lead (II) oxide (PbO). The document also describes method of using the same.

The invention provides a room-temperature synthetic method of an ultra pure inorganic halogen perovskite blue light nanosheet. The method comprises the following steps: 1) preparing mixed liquor of oleylamine, oleic acid and toluene; 2) adding a precursor of lead bromide in the mixed liquor after the reaction in the step 1) is completed, uniformly stirring the materials, and adding a precursor ofcesium bromide; taking the precursor of lead bromide as a solvent of dimethyl sulfoxide; taking a hydrobromic acid solution with 40% weight ratio of the precursor of cesium bromide as a solvent; 3) injecting a butanol solution in the mixed liquor after the reaction in the step 2) is completed, fully reacting the materials, and performing centrifugation collection to obtain a supernatant; and 4) performing microwave heating on the supernatant and performing re-centrifugation, and depositing and dispersing the centrifuged precipitate at a ground floor in a toluene solution. The method has the advantages of simple operation and high efficiency, the luminescence property of the ultra pure inorganic halogen perovskite blue light nanosheet is excellent, and the shortage of the low luminescence efficiency and non stabilization of an inorganic halogen perovskite blue light nano-material in the prior art can be effectively made up.

The invention discloses a preparation method of an inorganic perovskite-coated MXene two-dimensional layered anode material and relates to the technical field of preparation of lithium ion battery anode materials. The preparation method comprises the following steps: adding lead bromide and cesium bromide into N,N-dimethyl formamide, introducing protective gas, heating and stirring, so that an inorganic perovskite material precursor is obtained; adding Ti3AlC2 into HF aqueous solution, stirring and reacting, centrifuging, washing, and performing vacuum drying, so that Ti3C2 powder is obtained;adding the Ti3C2 powder into the inorganic perovskite material precursor, heating, and stirring, so that precursor solution is obtained; adding methylbenzene into the precursor solution, centrifuging, and performing vacuum drying, so that the inorganic perovskite-coated MXene two-dimensional layered anode material is obtained. The preparation method disclosed by the invention enhances structuralstability of a MXene two-dimensional layered anode material Ti3C2 by coating the MXene two-dimensional layered anode material Ti3C2 with the inorganic perovskite material, so that the anode material has good stability and excellent physical and chemical properties; meanwhile, compared with the conventional high-cost technology that a lithium battery anode material needs to be graphitized and coated with carbon at high temperature, the preparation method disclosed by the invention is simple in technology and low in cost.

The invention belongs to the technical field of light-emitting diodes, and discloses a blue-light perovskite thin film, preparation thereof and an inverted quasi-two-dimensional blue-light perovskite light-emitting diode. The method comprises the following steps of: 1) preparing lead bromide, large-group organic halide and cesium bromide into a perovskite precursor solution by adopting an organic solvent; and 2) spin-coating the precursor solution, dropwise adding an anti-solvent in the spin-coating process, and removing the solvent to obtain the blue-light perovskite thin film. The inverted quasi-two-dimensional blue-light perovskite light-emitting diode comprises a cathode, an electron transport layer, an interface layer, a light-emitting layer, a hole transport layer, a hole injection layer and an anode distributed from bottom to top sequentially, wherein the light-emitting layer is the blue-light perovskite thin film. According to the method, the exciton binding energy of the blue-light perovskite can be increased, the morphology of the thin film is improved, meanwhile, formation of a low-dimensional phase (n = 1) is inhibited, and the luminous efficiency of the quasi-two-dimensional blue-light perovskite is improved. The blue light perovskite thin film is used for a light emitting diode, and therefor, blue light emission is achieved, and the light emitting efficiency is improved.

The invention discloses a method for solid-phase synthesis of green fluorescent perovskite, and belongs to the technical field of perovskite fluorescent materials. The preparation method comprises: uniformly mixing lysine, cesium bromide and lead bromide to obtain mixed powder; putting the mixed powder into a centrifugal tube, carrying out light-shielding treatment on the centrifugal tube, puttingthe light-shielding centrifugal tube into a vortex mixer, carrying out an oscillating mixing reaction for 1-30 min, and carrying out light-shielding placement treatment for 1-30 min so as to obtain agreen fluorescent CsPbBr3 material; or grinding the mixed powder for 1-5 min or carrying out stirring mixing treatment for 5-30 min to obtain a green fluorescent CsPbBr3 material. According to the invention, high-stability and high-fluorescence-intensity CsPbBr3 is synthesized in one step by using cesium bromide, lysine and lead bromide as synthesis raw materials without a solution substrate, sothat the synthesis method is simple, the synthesis raw materials are easy to obtain, and the consumed time is short.