Cosmetic composition comprising a polyester and a branched hydrocarbon compound
A cosmetic composition and composition technology, applied in the field of lipstick, can solve problems such as inappropriate
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[0156] The polycondensate can be prepared by esterification / polycondensation methods commonly used by those skilled in the art. As an illustration, general preparation methods include:
[0157] - mixing said polyol and said aromatic and non-aromatic monocarboxylic acid,
[0158] - heating the mixture under an inert atmosphere, first to the melting point (typically 100-130°C) and then to a temperature of 150 to 220°C until the monocarboxylic acid has been completely consumed (acid number less than or equal to 1 is reached) , preferably simultaneously distilling off the water formed as it forms, and then
[0159] - optionally cooling the mixture to a temperature of 90 to 150° C.,
[0160] - adding polycarboxylic acid and / or cyclic anhydride and optionally silicone with hydroxyl or carboxyl functionality all at once or sequentially, then
[0161] - Reheating to a temperature lower than or equal to 220°C, especially 170 to 220°C, preferably while continuing to remove the water ...
Embodiment 1
[0342] Embodiment 1: the synthesis of pentaerythritol base benzoate / isophthalate / isostearate
[0343] Add 20 g of benzoic acid, 280 g of isostearic acid and 100 g of pentaerythritol into a reactor equipped with a mechanical stirrer, an argon inlet and a distillation system, then gradually heat the mixture to 110-130 °C to obtain a homogeneous solution. The temperature was then gradually increased to 180°C and maintained at this temperature for about 2 hours. The temperature was raised again to 220°C and maintained until an acid number less than or equal to 1 was obtained, which required about 11 hours. The mixture was cooled to a temperature of 100 to 130°C, then 100 g of isophthalic acid was added, and the mixture was gradually heated again to 220°C for about 11 hours.
[0344] This gives 405 g of a pentaerythritolylbenzoate / isophthalate / isostearate polycondensate in the form of a very thick oil.
[0345] The polycondensate exhibits the following characteristics:
[034...
Embodiment 2
[0352] Embodiment 2: the synthesis of pentaerythritol base benzoate / isophthalate / isostearate
[0353] Add 35 g of benzoic acid, 270 g of isostearic acid and 80 g of pentaerythritol into a reactor equipped with a mechanical stirrer, an argon inlet and a distillation system, then gradually heat the mixture to 110-130 °C to obtain a homogeneous solution. Next, the temperature was gradually increased to 180° C. and maintained at this temperature for about 2 hours. The temperature was raised again to 220°C and maintained until an acid number less than or equal to 1 was obtained, which required about 11 hours. The mixture was cooled to a temperature of 100 to 130°C, then 65 g of isophthalic acid was added, and the mixture was gradually heated again to 220°C for about 5 hours.
[0354] This gave 380 g of a pentaerythritolylbenzoate / isophthalate / isostearate polycondensate in the form of an oil.
[0355] The polycondensate exhibits the following characteristics:
[0356] - 50% by...
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