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Flame-retardant polymer/montmorillonite nano fat liquoring complex agent

A nano-composite, montmorillonite technology, applied in the direction of small raw hide/big raw hide/leather/fur treatment, small raw hide/big raw hide/leather skin/fur chemical treatment, leather impregnation, etc., which can solve the requirements of flame retardancy. To achieve the effect of soft crust leather, good flame retardancy and full grain surface

Inactive Publication Date: 2010-01-27
SHAANXI UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Functional fatliquor has become the trend of market development. In recent years, fatliquor with filling and waterproof properties have come out one after another, but there are few research reports on fatliquor with flame retardancy, while sofa leather, The requirements for flame retardancy are getting higher and higher for automobile seat cushion leather

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0014] Embodiment one: 1) in there-necked flask, add 50g rapeseed oil, 1.8g ethylenediamine and 0.6gAl 2 o 3 , heat up to 110°C, temperature control reaction for 2h; slowly add 9.36g acrylic acid, heat up to 126°C, temperature control reaction time 4h; cool down to 65°C (natural cooling), slowly add dropwise 45g saturated sodium bisulfite solution, temperature control The reaction time is 1.5h. Then slowly add 70 g of ammonia water (1:3 dilution) to the above-mentioned reactant until the appearance of the reactant is light yellow paste, add a certain amount of hot water, adjust the solid content to 40%, and obtain the modified rapeseed oil fatliquoring agent.

[0015] 2) Take 50g of the above-mentioned modified vegetable oil fatliquoring agent and 1.2g of montmorillonite and add them into a three-necked flask, raise the temperature to 40°C, stir at the temperature for 20min, transfer it into a 100ml beaker, set the ultrasonic power to 600w, ultrasonic time / interval time 2s / ...

Embodiment 2

[0016] Embodiment two: 1) in there-necked flask, add 50g rapeseed oil, 1.8g ethylenediamine and 0.6gAl 2 o 3 , heat up to 110°C, temperature control reaction for 2h; slowly add 9.36g acrylic acid, heat up to 126°C, temperature control reaction time 4h; cool down to 65°C (natural cooling), slowly add dropwise 45g saturated sodium bisulfite solution, temperature control The reaction time is 1.5h. Then slowly add 70 g of ammonia water (1:3 dilution) to the above-mentioned reactant until the appearance of the reactant is light yellow paste, add a certain amount of hot water, adjust the solid content to 40%, and obtain the modified rapeseed oil fatliquoring agent.

[0017] 2) Take 50g of the above-mentioned vegetable oil fatliquor and 1.8g of montmorillonite into a three-necked flask, raise the temperature to 50°C, stir for 40min under temperature control, transfer it into a 100ml beaker, set the ultrasonic power to 700w, and the ultrasonic time / interval time is 3s / 1s, ultrasoni...

Embodiment 3

[0018] Embodiment three: 1) in there-necked flask, add 50g rapeseed oil, 1.8g ethylenediamine and 0.6gAl 2 o 3 , heat up to 110°C, temperature control reaction for 2h; slowly add 9.36g acrylic acid, heat up to 126°C, temperature control reaction time 4h; cool down to 65°C (natural cooling), slowly add dropwise 45g saturated sodium bisulfite solution, temperature control The reaction time is 1.5h. Then slowly add 70 g of ammonia water (1:3 dilution) to the above-mentioned reactant until the appearance of the reactant is light yellow paste, add a certain amount of hot water, adjust the solid content to 40%, and obtain the modified rapeseed oil fatliquoring agent.

[0019] 2) Take 50g of the above-mentioned modified vegetable oil fatliquoring agent and 3.6g of montmorillonite and add them together into a three-necked flask, raise the temperature to 70°C, stir for 40min under temperature control, transfer to a 100ml beaker, set the ultrasonic power to 800w, ultrasonic time / inter...

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PUM

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Abstract

The invention belongs to the field of skin collagen treatment, and provides flame-retardant nano fat-liquoring complex agent, particularly flame-retardant polymer / montmorillonite nano fat-liquoring complex agent. The functional fat-liquoring agent prevails in the market development, and the fat-liquoring agents having the properties of filling and water-resisting are invented one after another inrecent years, however, few research reports concerning the flame-retardant fat-liquoring agent are published, whereas sofa leather, automobile cushion leather and other leather require higher flame-retardant performance. The flame-retardant polymer / montmorillonite nano fat-liquoring complex agent of the invention is prepared through the following steps: performing the partial amidation reaction between low-cost rapeseed oil and diethylamine; then, performing the reaction with acrylic acid to prepare polymer modified fat-liquoring agent; and further subjecting the polymer modified fat-liquoring agent and the nano material montmorillonite to processing methods, such as mechanical stirring and ultrasonic treatment. The fat-liquoring agent can be used alone or combined with other anionic, cationic and non-ionic fat-liquoring agent. The fat-liquored crust leather is soft, the grain surface is full, and the fat-liquored crust leather has higher flame-retardant performance.

Description

technical field [0001] The invention belongs to the field of skin collagen treatment, and specifically relates to a preparation method of a flame-retardant polymer / montmorillonite nanocomposite fatliquoring agent. technical background [0002] Fatliquor is one of the most used leather chemicals in tanning production, and it has an extremely important impact on the performance of the finished leather. It can penetrate into the collagen fibers of the skin to lubricate and plasticize, making the molecular chain segments easy to move, and the finished leather is soft, waterproof, sun-proof, moist and elastic. Functional fatliquor has become the trend of market development. In recent years, fatliquor with filling and waterproof properties have come out one after another, but there are few research reports on fatliquor with flame retardancy, while sofa leather, There is an increasing demand for flame retardancy in automotive cushion leather and the like. Contents of the inventi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C14C9/02
Inventor 吕斌高党鸽马建中洪蕾
Owner SHAANXI UNIV OF SCI & TECH
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