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Method for preparing decoloration coal activated carbon

A coal-based activated carbon and decolorization technology, which is applied in the field of preparation of decolorized coal-based activated carbon, can solve the problems of low caramel decolorization rate and environmental pollution, and achieve the effects of improving pore structure, good wear resistance and improving adsorption capacity

Active Publication Date: 2011-04-27
山西华青环保股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the caramel decolorization rate of the coal-based activated carbon prepared by this method is not high, and adhesives are used in the molding process, causing additional pollution to the environment

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] Select Datong weakly caking coal with ash content of 2.4% by weight and volatile content of 32% by weight, Shaanxi weakly caking coal with ash content of 3.2% by weight and volatile content of 29% by weight, and fat coal, and crush the above-mentioned raw coal into seed coal of 6-9 mm , dried until the moisture content is less than 8%, and the ingredients are prepared according to the following ratio: Datong weakly caking coal 70kg, Shaanxi weakly caking coal 22kg, fat coal 8kg; crushed, passed through a 200-mesh sieve, and added 1kg of light magnesium oxide powder with an activity greater than 60 , mixed evenly; use the domestic WZ-500 dry roller briquetting machine (Hebei Xinji Jieda Equipment Co., Ltd.) to dry the powder into blocks; under anaerobic conditions, the temperature was raised to 300 at a heating rate of 3°C / min. °C pre-carbonization, followed by further carbonization at 450 °C for 300 minutes; two-stage activation, first activated at 800 °C for 2 hours in ...

Embodiment 2

[0033] Dosing according to the following proportions: 60kg of Datong weakly caking coal, 30kg of Shaanxi weakly caking coal, 10kg of fat coal; pulverize, pass through a 200-mesh sieve, add 2kg of light magnesium oxide powder with an activity greater than 60, and mix evenly; use domestic WZ-500 The dry roller briquetting machine dry-presses the powder into blocks; under anaerobic conditions, the temperature is raised to 300°C at a heating rate of 3°C / min for pre-carbonization, and then further carbonized at 450°C for 270 minutes; two-stage activation is adopted, first Activate at 800°C for 1 hour in a water vapor atmosphere, then activate at 900°C for 12 hours in a mixed atmosphere composed of 15% water vapor and 85% flue gas by volume; use 20% sulfuric acid aqueous solution at room temperature Soak the activated product and wash with water.

[0034] According to the same standards as in Example 1, various properties were tested, and the results are summarized in Table 1.

Embodiment 3

[0036] Dosing according to the following ratio: Datong weakly caking coal 72kg, Shaanxi weakly caking coal 18kg, fat coal 10kg; pulverize, pass through a 200-mesh sieve, add 3kg of light magnesium oxide powder with an activity greater than 60, and mix evenly; use domestic WZ-500 The dry roller briquetting machine dry-presses the powder into blocks; under anaerobic conditions, the temperature is raised to 300°C at a heating rate of 4°C / min for pre-carbonization, and then further carbonized at 500°C for 240 minutes; two-stage activation is adopted, first Activate at 800°C for 1 hour in a water vapor atmosphere, then activate at 800°C for 10 hours in a mixed atmosphere composed of 20% by volume water vapor and 80% by volume of flue gas; use 20% sulfuric acid aqueous solution at room temperature Soak the activated product and wash with water.

[0037] According to the same standards as in Example 1, various properties were tested, and the results are summarized in Table 1.

[003...

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PUM

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Abstract

The invention provides a method for preparing decoloration coal activated carbon, which adopts the technology of mixing and matching high activity magnesium oxide and different coals, and controls the atmosphere, the temperature and the time of subsection activation; therefore, the coal activated carbon which has high caramel decoloration rate, high molasses valve, high strength and high wear resistance can be obtained under the condition that adhesive is not used, and the environment is seldom influenced.

Description

technical field [0001] The invention relates to a method for preparing decolorized coal-based activated carbon, in particular to a method for preparing coal-based activated carbon with high caramel decolorization rate, high molasses value, high strength and high wear resistance. Background technique [0002] The raw materials for producing decolorized activated carbon in the prior art generally use woody materials or other biomass raw materials, and the activation methods used are generally chemical activation or chemical-physical activation. CN1425607A and CN1456499A disclose the method that utilizes acid hydrolysis lignin to prepare high decolorization granular activated carbon, through the operation of adding acid pretreatment, hardening, activation, the decolorization of methylene blue prepared is more than 270mg / g, and iodine adsorption value is more than 1285mg / g, and Granular activated carbon whose method A caramel decolorization rate is above 120%. CN1511784A disclo...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C01B31/08
Inventor 李磊常宝华李贵义贺守印杨培梧
Owner 山西华青环保股份有限公司