In order to overcome the problems of
crystal blockage and insufficient conversion rate in the existing
chlorine dioxide preparation scheme, the invention provides composite
chlorine dioxide gas preparation equipment which comprises a front reactor and a main reactor, the front reactor is provided with a front reaction cavity, and the front reaction cavity is used for accommodating a reaction solution of a
sodium chlorate solution and
hydrochloric acid, so that separated
sodium chlorate crystals are deposited in the reaction solution and are subjected to reaction
digestion; and the main reactor is used for receiving the gas-liquid mixture without
crystal precipitates, which is guided out by the front reactor, so as to continue the reaction. Meanwhile, the invention also discloses a preparation method of the composite
chlorine dioxide gas. The composite
chlorine dioxide gas preparation equipment provided by the invention thoroughly solves the problem that
crystal precipitates are deposited in filler gaps of the main reactor and block the main reactor, greatly improves the
utilization rate of raw materials, breaks through the
bottleneck of low conversion rate (less than or equal to 50%) of the existing equipment, and achieves the final conversion rate of 90% or above.