RF tag and method for producing same
A label and prepreg technology, used in printed circuit manufacturing, chemical instruments and methods, printed circuits, etc., and can solve problems such as misoperation of electronic equipment
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Embodiment
[0080] Embodiments will be further specifically described below by citing synthesis examples, examples and comparative examples. First, the evaluation method of the RF tags used in each example will be described.
[0081] 【Environmental Resistance Evaluation】
[0082] The judgment of environmental resistance is carried out through heat cycle test and high temperature and high humidity resistance. The form of the sample used for evaluation is as follows.
[0083] RF tag: length 90mm, width 50mm and thickness 4mm.
[0084] Antenna circuit 10: length 90mm and width 40mm.
[0085] Metal foil M: length 90mm and width 55mm.
[0086] 【Heat cycle resistance】
[0087] The thermal cycle resistance was judged by putting the RF tag sample into the thermal cycle resistance evaluation device. The number of cycles when delamination was observed by visual inspection of the RF tag, and the rate of change from the initial value of the resistance value between antenna circuits and the resi...
Synthetic example 1
[0094] Synthetic example 1 manufacture of graft copolymer
[0095] After adding 8500 g of pure water to a stainless steel autoclave with an internal volume of 20 liters, 750 g of a 1% by mass aqueous solution of polyvinyl alcohol was dissolved as a suspending agent. 3500 g of polypropylene described below was added thereto, and stirred and dispersed. Separately, 10.0 g of benzoyl peroxide as a radical polymerization initiator and 37.5 g of tert-butylperoxymethacryloyloxyethyl carbonate as a radical copolymerizable organic peroxide were dissolved in 1080 g of monofunctional Styrene as an aromatic vinyl monomer and 300 g of divinylbenzene as a bifunctional aromatic vinyl monomer were charged into the autoclave and stirred.
[0096] Then the temperature of the autoclave was raised to 85-95°C and stirred for 2 hours to impregnate divinylbenzene and styrene containing benzoyl peroxide and tert-butyl peroxymethacryloyloxyethyl carbonate. into polypropylene. Then lower the tempera...
Synthetic example 2~14
[0103] Synthesis example 2~14, the manufacture of graft copolymer
[0104] Using the same method as that shown in Synthesis Example 1, aromatic vinyl monomers were graft-polymerized to various main chain structures to obtain graft copolymers of Synthesis Examples 2 to 14. Their composition is shown in Table 1.
[0105]
[0106] The abbreviations in Table 1 are as follows.
[0107] PP: Polypropylene (trade name "SunAllomer-PM671A", manufactured by SunAllomer Co., Ltd., MFR: 7g / (10min))
[0108] St: Styrene
[0109] DVB: divinylbenzene
[0110] TPX: poly(4-methyl-1-pentene) (trade name "TPX RT18", manufactured by Mitsui Chemicals Co., Ltd., MFR: 26 g / (10 min))
[0111] TOPAS6013: Ethylene-norbornene copolymer (trade name "TOPAS 6013", manufactured by Polyplastics Co., Ltd., MFR: 14g / 10min)
[0112] TOPAS6015: ethylene-norbornene copolymer (trade name "TOPAS 6015", manufactured by Polyplastics Co., Ltd., MFR: 4 g / 10min)
[0113] PPE: polyphenylene ether (trade name "lupi...
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