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Curable solid ink compositions

A technology of solid ink and composition, applied in the direction of ink, photosensitive materials for optomechanical equipment, instruments, etc., can solve the problems of crystalline wax usage restriction printing method, poor ink performance, poor light fastness, etc.

Inactive Publication Date: 2015-03-25
XEROX CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] However, the use of crystalline waxes limits the printing methods used for conventional solid inks
For example, keep the print head at a temperature higher than 120°C during the printing process, which can cause some problems
At these high temperatures, dyes molecularly dissolved in the ink vehicle are often susceptible to undesired effects leading to poor ink performance, such as: photo-oxidation by light (resulting in poor lightfastness); thermal degradation (e.g. When the ink is heated to a temperature above 120°C, the fluorescent dye loses its fluorescence); the dye diffuses from the ink into paper or other substrates (resulting in poor image quality and print-through); the dye penetrates into other solvents in contact with the image (resulting in poor water / solvent fastness)

Method used

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  • Curable solid ink compositions
  • Curable solid ink compositions
  • Curable solid ink compositions

Examples

Experimental program
Comparison scheme
Effect test

Embodiment

[0113] Process A for the Preparation of Ethoxylated Octylphenol Derivative A ("Derivative A")

[0114] Add pre-melted 70g IGEPALCA210 (M W =261) and 80.0g Unilin 425 (OH#95.3, M W =589) mixture. The flask was placed in a 140°C oil bath with a thermometer, then heated and stirred. After approximately 5 minutes, 30 g of IPDI (MW=222) was added, followed by three drops of Fascat 4202 catalyst. An exotherm was observed. After about 1.5 hours, obtain the IR spectrum of reaction product, do not find isocyanate peak (about 2230em -1 ). Pour the contents into aluminum cans to cool and solidify.

[0115] Process B for the preparation of ethoxylated octylphenol derivatives B ("derivatives B")

[0116]Add pre-melted 29.9g IGEPALCA210 (OH#214.92, M W =261) and 67.9g Unilin 425 (OH#95.3, M W =589) mixture. The flask was placed in a 140°C oil bath with a thermometer and heated / stirred. After about 5 minutes, add 30g dicyclohexylmethane-4,4'-diisocyanate (H 12 MDI, M W = 262...

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Abstract

A curable solid ink composition including a curable component, a non-curable component including an ethoxylated octylphenol derivative, a photoinitiator, and a colorant. The curable solid ink composition has a viscosity in the range of less than 10 cPs at 90° C., a shrinkage value of less than 3%, and a superior curing rate compared to existing curable solid ink compositions. The ethoxylated octylphenol derivatives may be prepared by reacting an ethoxylated octylphenol, a linear alcohol, and diisocyanates or polyisocyanates.

Description

technical field [0001] The present invention generally relates to a curable solid ink composition containing ethoxylated octylphenol derivatives and a method for preparing the same, the curable solid ink exhibits better performance than conventional solid phase change inks and curable solid inks Excellent cure rate, cold shrinkage, hardness and scratch resistance. Background technique [0002] Printing inks are often formulated according to the stringent performance requirements required by the target market application, as well as the desired properties. Whether for office printing or production printing, it is desirable to have a specific ink that produces a strong, long-lasting image under stressful conditions. [0003] In a typical piezoelectric inkjet printing device design, the image is applied by ejecting suitably colored ink during four to six rotations (incremental motion) of the substrate (image receiving member or intermediate transfer member) relative to the ink...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D11/101
CPCC09D11/32C09D11/324C09D11/38C09D11/101G03F7/004G03F7/0042G03F7/0045
Inventor M·P·布莱顿M·N·克雷蒂安J·H·班宁S·V·德雷派尔I·达菲C·A·瓦格纳
Owner XEROX CORP