Aqua regia corrosion inhibitor and preparation method thereof

A technology of corrosion inhibitor and acidified corrosion inhibitor, which is applied in earth-moving drilling, wellbore/well components, etc., can solve the problems of steel plate or component pitting, high economic cost, metal corrosion and other problems, achieve low corrosion rate, inhibit Local corrosion, good acid solubility

Inactive Publication Date: 2012-06-13
HUAZHONG UNIV OF SCI & TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

But, because aqua regia has strong corrosivity to metal, and various corrosion inhibitors on the market all can't solve the corrosion problem of aqua regia, so when carrying out pickling with aqua regia, its concentration is often prepared very low, makes Aqua regia cannot play its due effect. Even so, dilute aqua regia will still cause corrosion to the metal, causing pitting on the steel plate or components after pickling, which affects the appearance; It is injected separately with hydrochloric acid, so that the injected powder nitric acid and hydrochloric acid are mixed at the bottom of the well to form aqua regia. This is not only economically expensive, but also the nitric acid and hydrochloric acid cannot be mixed well under the formation to form aqua regia, making the acidizing effect far inferior to direct Acidification with aqua regia

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0010] Example 1 Preparation of aqua regia corrosion inhibitor for high concentration aqua regia pickling

[0011] Add 30 parts by weight of dimethylformamide, 25 parts by weight of propynyl alcohol, and 6 parts by weight of potassium iodide in the stirring tank. After stirring and dissolving, add 6 parts by weight of sodium thiocyanate. After stirring and dissolving, add 5 parts by weight of octylphenol polyoxyethylene ether and 28 parts by weight of 7801 acidification corrosion inhibitor were stirred evenly to obtain a clear and transparent aqua regia corrosion inhibitor.

Embodiment 2

[0012] Example 2 Using the aqua regia corrosion inhibitor prepared in Example 1 for high-concentration aqua regia pickling

[0013] Fill a jar with 15% HCl+10% HNO 3 Aqueous aqua regia, and put the jar filled with aqua regia in a constant temperature water bath to keep the aqua regia inside at 35°C. Add the aqua regia corrosion inhibitor that embodiment 1 prepares in the aqueous regia solution, make the mass concentration of the aqua regia corrosion inhibitor in the solution be 0.2%, it can be observed that the solution after adding the aqua regia corrosion inhibitor remains clear and transparent, the A3 steel The piece (size 76×13×1.5mm) was cleaned with alcohol and acetone, dried naturally and weighed, then soaked in the aqua regia solution added with aqua regia corrosion inhibitor. After 2 hours, the A3 steel piece was taken out, and the steel piece could be found The surface is bright, without local corrosion, and the corrosion rate of the A3 steel sheet obtained by dry w...

Embodiment 3

[0014] Example 3 Preparation of Aqua Regia Corrosion Inhibitor for Acidification of Aqua Regia

[0015] Add 20 parts by weight of dimethylformamide, 26 parts by weight of propynyl alcohol, and 8 parts by weight of potassium iodide in the stirring tank. After stirring and dissolving, add 6 parts by weight of sodium thiocyanate. After stirring and dissolving, add 5 parts by weight of nonylphenol polyoxyethylene ether and 35 parts by weight of 7801 acidification corrosion inhibitor were stirred evenly to obtain a clear and transparent aqua regia corrosion inhibitor.

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PUM

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Abstract

The invention provides an aqua regia corrosion inhibitor and a preparation method thereof. The aqua regia corrosion inhibitor provided by the invention is prepared from the following components in parts by weight: 25-35 parts of 7801 acidification corrosion inhibitor, 20-30 parts of dimethyl formamide, 15-25 parts of alkynol, 5-10 parts of iodide, 3-6 parts of surfactant and 4-7 parts of thiocyanide. The aqua regia corrosion inhibitor has the advantages of low consumption, obvious corrosion inhibition effect and favorable acid solubility; and the acid liquor with the aqua regia corrosion inhibitor is kept clear and transparent, and does not stratify or precipitate. The aqua regia corrosion inhibitor provided by the invention also has the advantages of simple preparation technique, accessible raw materials and favorable solubility in aqua regia, and can be used for acid washing and acidification of aqua regia; and the aqua regia corrosion inhibitor can ensure very low and uniform corrosion speed of metal, and effectively inhibit local corrosion.

Description

technical field [0001] The invention relates to a corrosion inhibitor used for acid washing with aqua regia and acidifying aqua regia in medium and low temperature oil and gas wells. Background technique [0002] Because aqua regia has strong corrosion and oxidation properties, it has wide application prospects in metal pickling and acidizing of oil and gas wells. For example, in pickling, aqua regia can quickly dissolve the thick and dense scale and oil stains on the surface, which greatly improves the efficiency of pickling operations; and in acidizing oil and gas wells, aqua regia can effectively remove organic plugging in oil layers , reduce the viscosity of heavy oil, increase the permeability of the formation, and increase the recovery factor. However, since aqua regia has strong corrosiveness to metals, and various corrosion inhibitors on the market cannot solve the corrosion problem of aqua regia, when pickling with aqua regia, its concentration is often prepared ve...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K8/54
Inventor 陈振宇陈鹏程金帮能
Owner HUAZHONG UNIV OF SCI & TECH
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