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Stable aqueous composite compositions

A technology of water-based composition and complex, which is applied in the direction of devices and coatings for coating liquid on the surface, and can solve problems such as reduced efficiency

Active Publication Date: 2015-02-25
ROHM & HAAS CO
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

When forming and drying the TiO 2 When too close, TiO 2 Will be less effective as a hiding pigment

Method used

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  • Stable aqueous composite compositions
  • Stable aqueous composite compositions
  • Stable aqueous composite compositions

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0061] Example 1. Preparation of composite particles below the critical composite ratio

[0062] Preparation of the absorbent emulsion polymer a.

[0063] A stage 1 monomer emulsion was prepared by mixing the following ingredients: 150 grams deionized water, 12.6 grams (30% effective) of anionic surfactant A, 292.3 grams BA, 205.1 grams MMA, 2.52 grams ALMA and 4.03 grams MAA. The monomer emulsion of stage 2 was prepared by mixing the following components: 275 grams of deionized water, 17.4 grams (30% effective) of anionic surfactant A, 403.7 grams of BA, 220.9 grams of MMA, 5.6 grams of MAA, 59.9 grams of PEM and 12.0 grams of UMA.

[0064]A 5 L four necked round bottom flask equipped with a paddle stirrer was fitted with a thermocouple, nitrogen inlet and reflux condenser on the reactor. 1000 grams of deionized water and 50.0 grams (30% effective) of Anionic Surfactant A were added to the flask and stirring was started. The contents of the flask were heated to 84°C unde...

Embodiment 2

[0070] Example 2. Preparation of a stable aqueous complex composition

[0071] Preparation of the absorbent emulsion polymer b.

[0072] A primary monomer emulsion was prepared by mixing the following components: 555 grams deionized water, 68.7 grams (30% active) of anionic surfactant A, 939.6 grams BA, 748.2 grams MMA and 3.48 grams MAA. Stage 1 monomer emulsion was prepared by transferring 772 grams of the primary monomer emulsion to a separate container and then adding 40.0 grams of PEM diluted with 30 grams of deionized water. A stage 2 monomer emulsion was prepared by transferring 719 grams of the primary monomer to a separate container. A stage 3 monomer emulsion was prepared by adding 17.4 grams of UMA to the remaining primary monomer emulsion. A 5 L four necked round bottom flask equipped with a paddle stirrer was fitted with a thermocouple, nitrogen inlet and reflux condenser on the reactor. To the flask was added 900 grams of deionized water, 3.9 grams (30% effe...

Embodiment 3

[0085] Example 3. The complex prepared under certain PVC and volume solid conditions can obtain acceptable viscosity

[0086] Preparation of absorbent emulsion polymer d.

[0087] A stage 1 monomer emulsion was prepared by mixing the following components: 136.2 grams deionized water, 20.2 grams (30% active) of anionic surfactant A, 235.4 grams BA, 187.4 grams MMA, 0.9 grams MAA and 36.8 grams PEM. A stage 2 monomer emulsion was prepared by mixing the following ingredients: 154.5 grams deionized water, 22.9 grams (30% active) of anionic surfactant A, 267.0 grams BA, 212.6 grams MMA and 1.0 grams MAA. The monomer emulsion of stage 3 was prepared by mixing the following components: 209.3 grams of deionized water, 31.0 grams (30% effective) of anionic surfactant A, 361.6 grams of BA, 287.9 ​​grams of MMA, 16.0 grams of a 50% aqueous solution of UMA and 1.3 grams of MAA. A 5-liter four-necked round bottom flask equipped with a paddle stirrer was equipped with a thermocouple, ni...

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Abstract

This invention provides a method for forming a stable aqueous composition including composite particles by admixing TiO2 particles and adsorbing emulsion polymer particles at or below the critical composite ratio to an equilibrated viscosity range of from 200 cps to 4000 cps. Also provided is a method for forming a stable aqueous composition including composite particles by admixing TiO2 particles and adsorbing emulsion polymer particles at a mixing intensity of greater than 2 hp / kgal. A method for providing a coating including composite particles is also included.

Description

technical field [0001] The present invention relates to a process for the preparation of a stable aqueous composition comprising composite particles comprising adding TiO 2 The particles are mixed with absorbent emulsion polymer particles to an equilibrium viscosity in the range of 200-4000 centipoise. The present invention also relates to a method for forming a stable aqueous composition comprising composite particles, the method comprising: mixing TiO 2 The particles are mixed with absorbent emulsion polymer particles. The invention also provides methods for providing coatings. Background technique [0002] Titanium dioxide (TiO 2 ) is an expensive component of many paints. When forming and drying the TiO 2 When too close, TiO 2 Efficiency as a hiding pigment will be reduced. It has been revealed that through the use of adsorbent emulsion polymers, it is possible to improve and strengthen the TiO 2 spacing and the resulting efficiency. Contains central TiO with a ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D133/08C09D7/12B05D7/24
CPCC08K3/22B05D1/00C09D201/00
Inventor J·C·博林A·G·克拉夫琴科J·W·胡克三世J·J·莫雷蒂M·H·基弗J·N·瓦那
Owner ROHM & HAAS CO