Continuous cooling crystallizer

A technology of cooling crystallization and crystallization tank, which is applied in the direction of solution crystallization, etc., can solve the problems of easy scaling, wear and tear, and large heat transfer coefficient of external heat exchangers, and achieve the effects of stable operation, difficult scaling, and simple equipment structure

Inactive Publication Date: 2012-05-02
ZHEJIANG HUAYI ENG DESIGN
4 Cites 14 Cited by

AI-Extracted Technical Summary

Problems solved by technology

The heat transfer coefficient is large and the heat transfer area is variable, but a suitable circulating pump must be selecte...
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Abstract

The invention discloses a continuous cooling crystallizer, comprising a crystallization tank and a heat exchanger in the crystallization tank, wherein, the heat exchanger comprises a top-enclosed heat exchange cylinder, a heat exchange pipe fixed in the heat exchange cylinder, a cooling medium inlet pipe and a cooling medium outlet pipe; a hollow shaft vertically passing through the top surface of the crystallization tank and a driving mechanism driving the hollow shaft to rotate are arranged above the crystallization tank, the top end of the hollow shaft is connected with a three-channel rotary joint, the bottom end of the hollow shaft is connected with the enclosed end of the heat exchange cylinder; a material pipe which has a top end communicated with one channel of the three-channel rotary joint and a bottom end passing through the heat exchange cylinder is arranged in the hollow shaft, one ends of the cooling medium inlet pipe and the cooling medium outlet pipe are respectively communicated with the inlet end and outlet end of the heat exchange pipe, and the other ends of the cooling medium inlet pipe and the cooling medium outlet pipe are respectively communicated with the rest two channels of the three-channel rotary joint. The continuous cooling crystallizer is used in a cooled shell-and-tube heat exchanger and arranged in the crystallization tank, rotates at a certain speed when working, and the cooling process and stirring process are combined as a whole, thus the crystallization efficiency is greatly increased.

Application Domain

Solution crystallization

Technology Topic

Cooling mediumPlate heat exchanger +2

Image

  • Continuous cooling crystallizer
  • Continuous cooling crystallizer
  • Continuous cooling crystallizer

Examples

  • Effect test(2)

Test Example

[0025] Application example 1
[0026] The coumarin-63-(2-benzothiazolyl)-7-diethylaminocoumarin acetone solution at a temperature of 50℃ enters from the inlet of the rotary joint 14 at 1.5t/h and passes through the shaft hole of the hollow shaft 10 The material pipe 18 in the middle enters the tube side of the heat exchanger, and enters the crystallization tank 1 through the heat exchange cylinder 2. Through the observation mirror 7, when the liquid level of the crystallization tank 1 reaches half the height of the cylinder of the crystallization tank 1, open the bottom valve of the crystallization tank 1 and the solution enters the centrifuge 22. At the same time, adjust the material inlet valve to ensure a stable liquid level.
[0027] After stabilization, start the motor 13 and drive the hollow shaft 10 and the entire heat exchanger to rotate at 100 rpm through the transmission chain 11, open the cooling medium valve, and the chilled water enters through the cooling medium inlet of the three-way rotary joint 14 and passes through a three-way rotary joint. After the passage, it enters the cooling medium inlet pipe 5, then enters the shell side from the bottom of the heat exchanger, and returns to the cooling medium outlet pipe 4 from the upper part of the heat exchanger, and enters the cooling medium recoverer 21 through the passage of the three-way rotary joint 14.
[0028] Observe the temperature at the outlet of the crystallization tank 1, adjust the flow of the cooling medium, the outlet temperature reaches 15°C, and stabilizes, the solution passes through the heat exchanger, the temperature drops rapidly, and becomes a supersaturated solution at the outlet of the heat exchanger, coumarin-63-( 2-benzothiazolyl)-7-diethylaminocoumarin crystals precipitate out of the solution, and the layer drops to the bottom of the crystallization tank 1 due to gravity. The crystals and the solution enter the centrifuge 22 through the bottom valve for separation, resulting in a uniform and pure particle size Crystal.
[0029] Compared with the conventional K3000L glass-lined kettle crystallizer with stirring, the continuous crystallization process has significantly improved crystallization efficiency. Using kettle type crystallizer, processing 3m 3 The solution needs 4 to 5 hours, and the crystallization can be completed in only 2 hours by adopting the present invention, and the amount of crystals is about 10% more than the conventional crystallizer.

Test Example

[0030] Application example 2
[0031] The methanol solution of sodium phenylpyruvate with a temperature of 45℃ enters from the material inlet of the three-way rotary joint 14 at a temperature of 1.5t/h, enters the tube side of the heat exchanger through the material tube 18, and enters the crystallization tank 1 through the heat exchange tube. Observe the sight glass 7, when the liquid level of the crystallization tank 1 reaches one third of the height of the cylinder part of the crystallization tank 1, the valve at the bottom of the crystallization tank 1 is opened, and the solution enters the centrifuge 22.
[0032] After the liquid level is stable, start the motor 13 and drive the hollow shaft 10 and the entire heat exchanger to rotate at 85 rpm through the transmission chain 11, open the cooling medium valve, and the frozen brine enters through the cooling medium inlet 13 of the three-way rotary joint 14 and passes through one of them After the passage, it enters the cooling medium inlet pipe 4, then enters the shell side from the bottom of the heat exchanger, and returns the cooling medium outlet pipe 4 from the upper part of the heat exchanger, and enters the cooling medium recoverer 21 through another passage of the rotary joint 14.
[0033] Observe the temperature at the outlet of crystallization tank 1 and adjust the flow of cooling medium. The outlet temperature reaches 8°C and stabilizes. The solution passes through the heat exchanger and the temperature drops rapidly. Sodium phenylpyruvate crystals precipitate out of the solution, and the layer drops to the crystallization tank due to gravity At the bottom, the crystals and the solution enter the centrifuge 22 through the bottom valve for separation to obtain crystals with uniform and pure particle size.
[0034] Compared with the conventional K5000L glass-lined kettle type crystallizer (with jacket) with stirring, the continuous crystallization process of the present invention has significantly improved crystallization efficiency. Using kettle crystallizer, processing 5m 3 The solution needs 5-6h, and it takes about 3.5h to complete the crystallization using this patent, and the amount of crystals is about 8% more than the conventional crystallizer.

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Description & Claims & Application Information

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