Aluminum hydroxide dry glue containing silicon and boron and preparation method thereof
A technology of aluminum hydroxide and dry glue, which is applied in the direction of chemical instruments and methods, catalyst carriers, chemical/physical processes, etc., can solve the problem of small increase in pore volume and specific surface area, reduced catalyst activity and service life, and difficult to play Problems such as the role of silicon and boron additives, etc., to achieve the effect of suitable pore structure and acidity, improved dispersion, and large pore volume
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Embodiment 1
[0028] will contain Al 2 o 3 5g / 100mL AlCl 3 Solution 2000mL with NH 3 10g / 100mL of ammonia water was added dropwise to the gelling reaction tank stirred at 60°C, the pH value was maintained at 7.6, the reaction contact time was 40min, and aging was carried out at a temperature of 70°C and a pH value of 8.0. The aging time was 1h. The product was filtered, and then washed with deionized water with a solid-to-liquid volume ratio of 1:20 at a washing temperature of 80°C for three times, and the obtained filter cake was dried at 120°C for 3 hours.
Embodiment 2
[0030] After the gelation of Example 1, dropwise add the SiO-containing 2 2g / 100mL simethicone oil 100mL, aged at 70°C for 80min, then added 2 o 3 3g / 100mL organic compound solution 100mL, the boron-containing organic compound solution is prepared by dissolving boric acid in water, and the molar ratio of boric acid to mannitol is 1:1, and the others are the same as in Example 1.
Embodiment 3
[0032] After the gelation of Example 1, dropwise add the SiO-containing 2 2g / 100mL methyl silicone oil 100mL, aging at 70°C for 80min, then add B 2 o 3100mL of 3g / 100mL organic compound solution, the boron-containing organic compound solution is prepared by dissolving boric acid in water, and the molar ratio of boric acid to ethylene glycol is 1.0:1.5, and then aging at 70°C for 80min, and the other is the same example 1.
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