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Composite zinc removing agent for treating wastewater containing zinc

A waste water and total quality technology, applied in the direction of water/sewage treatment, water/sludge/sewage treatment, water pollutants, etc., can solve the problems of high operating costs, large investment, and difficulty in meeting water standards, and achieve low operating costs, The process is simple and the treatment effect is remarkable

Inactive Publication Date: 2012-05-23
CHANGZHOU YAHUAN ENVIRONMENTAL PROTECTION TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This patented technology allows for effective treatments on contaminated waters without causing environmental concerns or requiring expensive equipment such as chemicals that may harm other organisms living nearby.

Problems solved by technology

Technically speaking, this patented technical problem addressed in this patents relates to improving the efficiency of removing various types of contaminants (zinc) during the manufacturing processes for products made with materials containing these substances. Current solutions involve expensive equipment, complex operations, and excessive landfill disposal issues associated with traditional techniques like neutralization-based cleanup systems.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0020] According to the total mass percentage of the composite zinc remover, 20% sodium oxalate, 40% magnesium sulfide, and 40% ferrous sulfate are formulated into a composite zinc remover to treat zinc in a certain pharmaceutical wastewater. The zinc content in wastewater is 100mg / L, during the test, take 15mL of zinc remover and add it to the zinc-containing wastewater, adjust the pH value to 4.5, stir for 15 minutes, and then perform air flotation treatment on the obtained wastewater, and finally remove a layer of residue floating on the surface of the wastewater with a scraper After scraping, zinc was not detected in the effluent.

example 2

[0022] Based on the total mass percentage of the compound zinc remover, 80% potassium oxalate, 10% magnesium sulfide, and 10% aluminum sulfate will be formulated as a compound zinc remover to treat zinc in a certain chemical wastewater. The zinc content in the wastewater is 80mg / L, during the test, take 13mL of zinc remover and add it to the zinc-containing wastewater, adjust the pH value to 5.0, stir for 20 minutes, and then perform air flotation treatment on the obtained wastewater, and finally scrape a layer of residue floating on the surface of the wastewater with a slag scraper Scrape off, the zinc content in the effluent is 0.04mg / L.

example 3

[0024] Based on the total mass percentage of the compound zinc remover, 35% of sodium citrate, 30% of hydroxyethylidene diphosphonate, 15% of sodium sulfide, and 20% of magnesium sulfide are formulated into a compound zinc remover. The zinc content in the wastewater is 70mg / L. During the test, 16mL of zinc remover is added to the zinc-containing wastewater, the pH value is adjusted to 5.3, and stirred for 25 minutes. The obtained wastewater is then subjected to air flotation treatment, and finally the flotation A layer of residue on the surface of the wastewater was scraped off with a slag scraper, and zinc was not detected in the effluent.

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PUM

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Abstract

The invention discloses a composite zinc removing agent for treating wastewater containing zinc, belonging to the field of sewage treatment in environmental protection. The composite zinc removing agent is prepared by compounding organic matters and inorganic matters, wherein the organic matters comprise one or two of sodium citrate, tricalcium citrate, sodium oxalate, potassium oxalate and hydroxyethylidene bisphosphonate, and the inorganic matters comprise two or more of sodium sulfide, magnesium sulfide, ferrous sulfate and aluminum sulfate; in terms of mass ration, the sodium citrate accounts for 20 to 80 percent, the tricalcium citrate accounts for 20 to 80 percent, the sodium oxalate accounts for 20 to 80 percent, the potassium oxalate accounts for 20 to 80 percent, the hydroxyethylidene bisphosphonate accounts for 20 to 80 percent, the sodium sulfide accounts for 10 to 40 percent, the magnesium sulfide accounts for 10 to 40 percent, the ferrous sulfate accounts for 10 to 40 percent, and the aluminum sulfate accounts for 10 to 40 percents; and the composite zinc removing agent prepared according to the proportion is added into the wastewater containing the zinc under the condition that a pH value is between 4.0 and 6.0, the wastewater is stirred for 10 to 30 minutes and is subjected to air flotation treatment, a layer of residue floating on the surface of the wastewater is finally scraped by using a scraping machine, and yielding water can be lower the national discharge standard I. The composite zinc removing agent has the characteristics of simple process flow, lower running cost, no sludge generation, high zinc removing effect and the like.

Description

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Claims

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Application Information

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Owner CHANGZHOU YAHUAN ENVIRONMENTAL PROTECTION TECH
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