Composite non-electrolyte additive for improving high-temperature safety performance of battery

A high-temperature performance, non-aqueous electrolyte technology, applied in the direction of secondary batteries, secondary battery repair/maintenance, circuits, etc., can solve problems such as out-of-control batteries, flammability, explosions, etc., to meet the needs of high safety, guarantee Safety, the effect of improving safety

Inactive Publication Date: 2012-07-04
SHANGHAI INST OF SPACE POWER SOURCES
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the electrolyte commonly used in lithium-ion batteries has a low flash point and is flammable, which has become a safety hazard during the use of lithium-ion batteries.
Lithium-ion secondary batteries emit a lot of heat when they are overcharged and discharged, short-circuited, and high-current for a long time. These heats become a safety hazard for flammable electrolytes, which can cause catastrophic thermal breakdown (thermal runaway) or even battery explosion.

Method used

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  • Composite non-electrolyte additive for improving high-temperature safety performance of battery
  • Composite non-electrolyte additive for improving high-temperature safety performance of battery

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] The composition of the non-aqueous electrolyte: EMC / EC / PC=55:40:5 (weight ratio), solute LiPF 6 , the concentration is 1mol / L. In 100 parts by weight of non-aqueous electrolyte, add 3 parts of PS, 0.4 parts of PPACA. Composition of universal additives. Then 1.0 parts of FEC, 1.0 parts of DTFEC, 1.0 parts of DMMEMP, 1.0 parts of TFP were added thereto.

[0025] The electrolytes of Comparative Examples 1-5 and Example 1 were respectively used to manufacture 284864 batteries with a minimum capacity of 800mAh to investigate the effects of electrolyte additives on the firing performance and cycle performance of the batteries.

[0026] Charging conditions: 0.5C constant current charging to 4.2V, constant voltage charging to 20mAh.

[0027] Sleep: 10 minutes

[0028] Discharge system: 0.5C constant current discharge to 3.0V.

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Abstract

The invention discloses a composite nonaqueous electrolyte additive for improving the high-temperature safety performance of a battery. The safety and flame retardancy of the battery in a high-temperature state can be effectively improved, and the electrolyte is prevented from combusting and exploding due to battery overheating. The non-electrolyte additive for improving the high-temperature safety performance of the battery consists of fluorinated carbonic ester and alkyl phosphate. The non-electrolyte additive is an additive capable of effectively improving the safety of the battery in the high-temperature state; and the safety of the battery in the high-temperature state is effectively guaranteed, the electrical property of the battery is not influenced, and a requirement of customers on the high safety of the battery can be well met. The non-electrolyte additive can be applied to the conventional lithium ion batteries and lithium battery systems.

Description

technical field [0001] The invention relates to a nonaqueous electrolyte composite additive, in particular to a composite nonaqueous electrolyte additive which can effectively improve the safety performance of batteries under high temperature conditions. Background technique [0002] As an important component of ion conduction in lithium batteries, non-aqueous electrolytes are basically stable in composition, mainly including EC, DMC, PC, EMC, DEC, etc. With the continuous expansion of the lithium-ion battery market, safety issues have become constraints for lithium-ion batteries. An important factor in the development of batteries, especially in the fields of electric vehicles and large-scale energy storage, puts forward higher and newer requirements for the safety of batteries. However, the electrolyte commonly used in lithium-ion batteries has a low flash point and is flammable, which has become a safety hazard during the use of lithium-ion batteries. Lithium-ion seconda...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M10/42H01M10/0567
CPCY02E60/12Y02E60/10
Inventor 张邦玲戴扬高蕾王可解晶莹
Owner SHANGHAI INST OF SPACE POWER SOURCES
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