aerosol formulations for copd
A dosage and co-solvent technology, applied in the field of aerosol pharmaceutical solution formulations, can solve the problems of unpublished evidence of glycopyrronium chloride preparation, difficulty in grinding and the like
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[0028] The present invention also relates to a process for the preparation of a pharmaceutical composition comprising adding 1M HCl to a solution of glycopyrronium chloride in HFA propellant and co-solvent, wherein the amount of 1M HCl added is between 0.05-0.4 μg / μl of the final solution.
[0029] The pharmaceutical composition of the present invention may also contain other additional pharmaceutically active ingredients for separate, sequential or simultaneous use. Optional additional pharmaceutical actives of the composition include any pharmaceutically active ingredient known in the art to be useful in the prophylaxis or treatment of respiratory diseases and symptoms thereof. Examples of such active ingredients are: beta-2-agonists such as formoterol, salbutamol, fenoterol, camoterol (TA 2005), indacaterol, miviterol, vilanterol ( GSK 642444), Terbutaline, Salmeterol, Bitoterol and Oxinaline, all their single stereoisomeric forms or their mixtures and their salts; corticos...
Embodiment
[0074] Stability of glycopyrronium chloride during storage
[0075] Solution formulations were prepared using the compositions shown in Table 1.
[0076] Table 1
[0077]
[0078] Acid-containing samples were prepared by adding 1 M HCl in an amount corresponding to 0.222 μg / μl solution.
[0079] This solution was poured into inverted storage tanks under different conditions: 5°; 25°C / 60%RH; 30°C / 75%RH. The samples were analyzed for glycopyrronium chloride content by chromatography after 1, 2 and 3 months of storage.
[0080] The results show the stabilizing effect of adding acid to glycopyrronium chloride solution formulations.
[0081] The formulation was found to maintain a constant content in the presence of 1M HCl, but was highly dependent on storage time and temperature if no acid was used. See Table 2 below when the formulations were stored with or without acid for 3 months at 25°C / 60% relative humidity.
[0082] Table 2
[0083] active ingredient
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