Application of cross-linked chitosan porous microspheres in cigarette filter tips
A technology of cross-linked chitosan and porous microspheres, applied in application, smoke oil filter, tobacco and other directions, can solve the problem of weak adsorption capacity of gas phase and semi-volatile components, difficult to meet the requirements of filter rod forming process, and inability to directly apply filter Rod processing and other issues, to achieve good cigarette harm reduction effect, good biocompatibility and safety, and high specific surface area.
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Embodiment 1
[0022] Set the specific surface area to 300m 2 / g, the particle size distribution range of microspheres is 10~15μm, the pore size of micropores is 5~20nm, and the natural accumulation volume is 0.6cm 3 / g cross-linked chitosan porous microspheres are evenly sprinkled in the paper filter element, the addition amount is 30mg / piece, and the prepared filter rod is applied to cigarettes in the form of a composite filter rod. The amount of crotonaldehyde released in mainstream smoke was 43.5%. The paper filter rod loaded with cross-linked chitosan porous microspheres has no negative impact on the sensory quality of cigarettes, and at the same time can increase the penetration of cigarette aroma and improve smoking comfort.
Embodiment 2
[0024] Set the specific surface area to 35m 2 / g, the microsphere particle size distribution range is 400~500μm, the micropore diameter is 80~100nm, and the natural accumulation volume is 3.0cm 3 / g of cross-linked chitosan porous microspheres is added to the cavity of the ternary cavity filter stick by vacuum feeding, and the addition amount is 90 mg / piece, and the prepared ternary composite filter stick is applied to cigarettes, tobacco Gas detection, reducing the release of crotonaldehyde in mainstream smoke by 38.6% year-on-year. The cross-linked chitosan porous microsphere ternary composite filter stick has no negative impact on the sensory quality of cigarettes, and at the same time can increase the penetration of cigarette aroma and improve smoking comfort.
Embodiment 3
[0026] The specific surface area is 242m 2 / g, the microsphere particle size distribution range is 30~80μm, the micropore diameter is 20~40nm, and the natural accumulation volume is 0.8cm 3 / g of cross-linked chitosan porous microspheres is evenly sprinkled on the tow, and the addition amount is 40mg / branch. The cross-linked chitosan microsphere composite filter rod is applied to cigarettes. The amount of crotonaldehyde released in mainstream smoke was 31.5%. The cross-linked chitosan porous microsphere composite filter rod has no negative impact on the sensory quality of cigarettes, and at the same time can increase the penetration of cigarette aroma and improve smoking comfort.
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