Multi-gray scale photomask, manufacturing method of multi-gray scale photomask and pattern transfer method
A multi-grayscale and photomask technology, which is applied to microlithography exposure equipment, photoplate-making process on patterned surface, and originals for photomechanical processing, etc., can solve the problem of insufficient shading and impermeable penetration Issues such as light phase cancellation effect
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[0038] Below, refer to figure 1 and figure 2 One embodiment of the present invention will be described. figure 1 It is a flowchart showing the manufacturing process of the multi-tone photomask 100 of this embodiment, figure 2 It is a plan view of the multi-tone photomask 100 of this embodiment.
[0039] (1) Composition of multi-grayscale photomask
[0040] Such as figure 1 of (d), figure 2 As shown, the multi-grayscale photomask 100 includes: a transparent substrate 10; a prescribed pattern for transfer, which includes an optical film 30 formed on the transparent substrate 10 (in this embodiment, a film having a prescribed transmittance). strong light-shielding film), the light-shielding portion 101 , the semi-transparent portion 103 , and the light-transmitting portion 102 are formed by patterning.
[0041] The transparent substrate 10 is made of, for example, quartz (SiO 2 ) glass, containing SiO 2 、Al 2 o 3 , B 2 o 3 , RO (R is an alkaline earth metal), R 2 ...
Embodiment
[0088] As an example of the present invention, the following shape was obtained by optical simulation (simulation), that is, using a figure 2 (a) The multi-tone photomask 100 of the illustrated transfer pattern, that is, the multi-tone photomask 100 in which the fine transmission pattern 30a is formed approximately in the center of the width of the light-shielding portion 101, is formed on the object to be processed. The positive resist film is exposed to light and developed to form the shape of the resist pattern.
[0089] For the multi-tone photomask 100 used here, a multi-tone photomask whose transmittance of the optical film 30 is 5% (for the line representing the wavelength i) is used. In addition, for the amount of phase shift, a film of 180 degrees for the i-line (157.3 degrees for the g-line, and 167.4 degrees for the h-line) was used. As the applied exposure conditions, conditions of an exposure machine for LCD are applied, and broadband light including i-line, h-li...
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