Adhesive film, adhesive composition for the film, and optical element comprising the film
A technology of adhesive film and composition, applied in the direction of film/sheet adhesive, adhesive type, ester copolymer adhesive, etc., can solve the problems of conversion signal failure, serious failure, etc.
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preparation example 1
[0113] Preparation example 1: (meth)acrylic acid copolymer 1 containing carbonate group and aromatic group
[0114] 90 g of aromatic group-containing polyol carbonate was charged into a 2L four-necked flask, and heated to 60°C. Then, 0.5 g of dibutyltin dilaurate diluted in toluene at a ratio of 10% was added to the flask. The resultant was cooled to 50° C., and then 6 g of 2-methacryloyl chloride and 6 g of 2-methacryloyloxyethyl isocyanate (MOI) were added thereto. The resultant was kept at 50°C for 7 hours. After confirming by IR that no NCO group of MOI was observed, the resultant was cooled to 40°C. Preparation of (meth)acrylate polymers containing carbonate groups and aromatic groups represented by general formula 1A:
[0115] [Formula 1A]
[0116]
[0117] Among them, a is 4.
preparation example 2
[0118] Preparation example 2: (meth)acrylic acid copolymer 2 containing carbonate group and aromatic group
[0119] 90 g of aromatic group-containing polyol carbonate was charged into a 2L four-necked flask, and heated to 60°C. Then, 0.5 g of dibutyltin dilaurate diluted in toluene at a ratio of 10% was added to the flask. 11 g of 3-isocyanatopropyltriethoxysilane were added and the temperature was maintained at 60° C. for 3 hours. After confirming by IR that no NCO group of MOI was observed, the resultant was cooled to 50° C., and then 6 g of 2-methacryloyloxyethyl isocyanate (MOI) was added. The resultant was kept at 50°C for 7 hours. After confirming by IR that no NCO group of MOI was observed, the resultant was cooled to 40°C. Preparation of (meth)acrylate copolymers containing carbonate groups, aromatic groups and silyl groups represented by general formula 1B:
[0120] [Formula 1B]
[0121]
[0122] Among them, a is 4.
[0123] The details of the components used...
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