Preparation method of hydrogenation catalyst
A hydrogenation catalyst, hydrogenation activity technology, applied in molecular sieve catalysts, chemical instruments and methods, physical/chemical process catalysts, etc. Problems such as poor penetration of aluminum channels to achieve the effect of improving performance
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Embodiment 1
[0037] Add 800 g of solid aluminum chloride into 3.5 liters of distilled water while heating and stirring until dissolved to obtain solution (a). Concentrated ammonia water is added appropriate amount of distilled water and is diluted into about 10wt% dilute ammonia water (b), 42gY type molecular sieve Y-1 (SiO 2 / Al 2 o 3 The molar ratio is 11.0, the unit cell constant is 24.42?, and the relative crystallinity is 95%). Use an impregnation solution containing 18g sodium tungstate and 16g nickel nitrate hexahydrate for saturated impregnation, dry at 120°C for 180 minutes after impregnation, and bake at 500°C 4 hours; 16g of octadecylamine was dissolved in 350ml of absolute ethanol to form a solution (c). While stirring, add metal-containing Y molecular sieve to (c) and stir for 1 hour, filter, and dry the filter cake at 100° C. for 4 hours to obtain (d). Take a plastic tank, add (a) into the tank, stir and heat to 60°C, open the valve of the container containing (b), and add...
Embodiment 2
[0040] 800g of solid aluminum sulfate was added to 3.5 liters of distilled water while heating and stirring until dissolved to obtain aluminum sulfate solution (a). Concentrated ammonia water is added appropriate amount of distilled water and is diluted into about 10wt% dilute ammonia water (b), 195gY type molecular sieve Y-1 (SiO 2 / Al 2 o 3 The molar ratio is 11.0, the unit cell constant is 24.42?, and the relative crystallinity is 95%) use an impregnation solution containing 233g sodium tungstate and 205g nickel nitrate hexahydrate for saturated impregnation, after impregnation, dry at 120°C for 180 minutes, and bake at 500°C 4 hours; 39 g of hexadecylamine was dissolved in 1 L of ethanol to form solution (c). Under stirring, add metal-containing molecular sieves to (c), stir for 1 hour, filter, and dry the filter cake at 110°C for 12 hours to obtain (d). Take a plastic tank, add (a) into the tank, stir and heat to 60°C, open the valve of the container containing (b), an...
Embodiment 3
[0043] 730g of solid aluminum sulfate was added to 1.5 liters of distilled water while heating and stirring until dissolved to obtain aluminum sulfate solution (a). Prepare the solid sodium metaaluminate to a concentration of 20gAl 2 o 3 / l sodium aluminate solution (b), 1848g Y-type molecular sieve Y-1 (SiO 2 / Al 2 o 3 The molar ratio is 11.0, the unit cell constant is 24.42?, and the relative crystallinity is 95%) use an impregnation solution containing 636g sodium tungstate and 560g nickel nitrate hexahydrate for saturated impregnation, after impregnation, dry at 120°C for 180 minutes, and bake at 500°C 4 hours; 185 g of decylamine was dissolved in 2.5 L of ethanol to form solution (c). In the state of stirring, add the metal-modified molecular sieve into (c), and stir for 1 hour to obtain (d). Take a glue tank, put 1L of deionized water into it, stir and heat it to 60°C, open the valves of the containers containing (a), (b) and (d) at the same time, control the pH of ...
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