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Method for preparing hydrogenation catalyst

A hydrogenation catalyst and hydrogenation activity technology, applied in the direction of molecular sieve catalysts, chemical instruments and methods, physical/chemical process catalysts, etc., can solve the problems of amorphous silicon-aluminum agglomeration, reduction of catalyst specific surface area and pore volume, and influence on catalyst performance, etc. problem, achieve the effect of enhancing binding force, avoiding agglomeration and improving performance

Active Publication Date: 2014-05-21
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, the carrier material is prepared by directly adding molecular sieves in the process of forming amorphous silica-alumina. In this way, amorphous silica-alumina is prone to agglomeration, and it is also easy to enter the pores of the other party or block the pores of molecular sieves, which affects the amorphous silica-alumina. The distribution on the molecular sieve, the poor connectivity between the molecular sieve and the amorphous silica-alumina channel, reduces the specific surface area and pore volume of the catalyst, and the distribution of active metals is not easy to control, which makes the hydrogenation function of the catalyst mismatch with the cracking function, affecting the catalyst performance

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] 250g of solid aluminum chloride was added to 2 liters of distilled water while heating and stirring until dissolved to obtain aluminum chloride solution (a). Concentrated ammonia water is added appropriate amount of distilled water and is diluted into about 10wt% dilute ammonia water (b), 14.4gY type molecular sieve Y-1 (SiO 2 / Al 2 o 3 The molar ratio is 11.0, the unit cell constant is 24.42?, and the relative crystallinity is 95%) use an impregnation solution containing 13g sodium tungstate and 12g nickel nitrate hexahydrate for saturated impregnation, after impregnation, dry at 120°C for 180 minutes, and bake at 500°C 4 hours; 5.6 g of hexadecylamine was dissolved in 120 ml of absolute ethanol, and metal-containing Y molecular sieves were added therein under stirring to form a solution (c). Take 10L of water glass (industrial grade, modulus 3.0) and dilute it in 20L of deionized water to prepare solution (d). Take a plastic tank, add (a) into the tank, stir and he...

Embodiment 2

[0039] 250g of solid aluminum sulfate was added to 2 liters of distilled water while heating and stirring until dissolved to obtain aluminum sulfate solution (a). Concentrated ammonia water is added appropriate amount of distilled water and is diluted into about 10wt% dilute ammonia water (b), 182gY type molecular sieve Y-1 (SiO 2 / Al 2 o 3 The molar ratio is 11.0, the unit cell constant is 24.42?, and the relative crystallinity is 95%). Use an impregnation solution containing 185g sodium tungstate and 163g nickel nitrate hexahydrate for saturated impregnation, dry at 120°C for 180 minutes after impregnation, and bake at 500°C 4 hours; 36.4g of octadecylamine was dissolved in 200ml of absolute ethanol, and metal-containing Y molecular sieves were added, and beaten to form a slurry (c). Take 10L of water glass (industrial grade, modulus 3.0) and dilute it in 20L of deionized water to prepare solution (d). Take a plastic tank, add (a) into the tank, stir and heat to 65°C, ope...

Embodiment 3

[0042] 31.25g of solid aluminum sulfate was added to 2 liters of distilled water while heating and stirring until dissolved to obtain aluminum sulfate solution (a). Prepare the solid sodium metaaluminate to a concentration of 20g Al 2 o 3 / l sodium aluminate solution (b), 191.5g Y-type molecular sieve Y-1 (SiO 2 / Al 2 o 3 The molar ratio is 11.0, the unit cell constant is 24.42?, and the relative crystallinity is 95%) using an impregnation solution containing 51.3g sodium tungstate and 45.2g nickel nitrate hexahydrate for saturated impregnation, after impregnation, dry at 120°C for 180 minutes, 500 Roasting at °C for 4 hours; 19.2 g of dodecylamine was dissolved in 1 L of absolute ethanol, and metal-containing Y molecular sieves were added thereto for beating to obtain slurry (c). Take 10L of water glass (industrial grade, modulus 3.0) and dilute it in 20L of deionized water to prepare solution (d). Take a glue tank, put 2l of deionized water into it, stir and heat it to ...

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PUM

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Abstract

The invention discloses a method for preparing a hydrogenation catalyst. The method comprises the following steps: adding a mixture of molecular sieves containing hydrogenation active metal components and organic amines in the amorphous silica-alumina gel forming process; carrying out aging after amorphous silica-alumina gel forming is completed and then carrying out filtration, washing and drying; then carrying out forming, drying and roasting, thus obtaining the hydrogenation catalyst. By adopting the method, the molecular sieves and amorphous silica-alumina can be organically combined together with good combination degree and dispersion degree, agglomeration and even blockage of the molecular sieves and amorphous silica-alumina can be avoided, and meanwhile, the hydrogenation and cracking functions of the catalyst can be effectively adjusted and the usability of the catalyst can be improved. The catalyst prepared by the method is suitable for the shallow cracking and deep hydrogenation processes.

Description

technical field [0001] The invention relates to a method for preparing a hydrogenation catalyst, in particular to a method for preparing a hydrogenation catalyst containing molecular sieves and amorphous silicon-alumina. Background technique [0002] Hydrocracking technology is one of the important means for the secondary processing of crude oil and the lightening of heavy oil. Because of its strong adaptability to raw materials, flexible production operations and product solutions, and good product quality, it has become an important way to produce high-quality light clean oil products and solve the source of chemical raw materials. [0003] Hydrocracking catalysts are generally dual-functional catalysts, and their cracking activity and hydrogenation activity are respectively provided by the acidic component and hydrogenation active component in the catalyst. [0004] The acidic component of the catalyst is generally provided by molecular sieves contained in the catalyst a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J29/16B01J29/78C10G47/20
Inventor 蒋广安张晔郑庆华刘雪玲李宝忠王继锋
Owner CHINA PETROLEUM & CHEM CORP
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