Method for preparing hydrogenation catalyst
A hydrogenation catalyst and hydrogenation activity technology, applied in the direction of molecular sieve catalysts, chemical instruments and methods, physical/chemical process catalysts, etc., can solve the problems of amorphous silicon-aluminum agglomeration, reduction of catalyst specific surface area and pore volume, and influence on catalyst performance, etc. problem, achieve the effect of enhancing binding force, avoiding agglomeration and improving performance
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Embodiment 1
[0036] 250g of solid aluminum chloride was added to 2 liters of distilled water while heating and stirring until dissolved to obtain aluminum chloride solution (a). Concentrated ammonia water is added appropriate amount of distilled water and is diluted into about 10wt% dilute ammonia water (b), 14.4gY type molecular sieve Y-1 (SiO 2 / Al 2 o 3 The molar ratio is 11.0, the unit cell constant is 24.42?, and the relative crystallinity is 95%) use an impregnation solution containing 13g sodium tungstate and 12g nickel nitrate hexahydrate for saturated impregnation, after impregnation, dry at 120°C for 180 minutes, and bake at 500°C 4 hours; 5.6 g of hexadecylamine was dissolved in 120 ml of absolute ethanol, and metal-containing Y molecular sieves were added therein under stirring to form a solution (c). Take 10L of water glass (industrial grade, modulus 3.0) and dilute it in 20L of deionized water to prepare solution (d). Take a plastic tank, add (a) into the tank, stir and he...
Embodiment 2
[0039] 250g of solid aluminum sulfate was added to 2 liters of distilled water while heating and stirring until dissolved to obtain aluminum sulfate solution (a). Concentrated ammonia water is added appropriate amount of distilled water and is diluted into about 10wt% dilute ammonia water (b), 182gY type molecular sieve Y-1 (SiO 2 / Al 2 o 3 The molar ratio is 11.0, the unit cell constant is 24.42?, and the relative crystallinity is 95%). Use an impregnation solution containing 185g sodium tungstate and 163g nickel nitrate hexahydrate for saturated impregnation, dry at 120°C for 180 minutes after impregnation, and bake at 500°C 4 hours; 36.4g of octadecylamine was dissolved in 200ml of absolute ethanol, and metal-containing Y molecular sieves were added, and beaten to form a slurry (c). Take 10L of water glass (industrial grade, modulus 3.0) and dilute it in 20L of deionized water to prepare solution (d). Take a plastic tank, add (a) into the tank, stir and heat to 65°C, ope...
Embodiment 3
[0042] 31.25g of solid aluminum sulfate was added to 2 liters of distilled water while heating and stirring until dissolved to obtain aluminum sulfate solution (a). Prepare the solid sodium metaaluminate to a concentration of 20g Al 2 o 3 / l sodium aluminate solution (b), 191.5g Y-type molecular sieve Y-1 (SiO 2 / Al 2 o 3 The molar ratio is 11.0, the unit cell constant is 24.42?, and the relative crystallinity is 95%) using an impregnation solution containing 51.3g sodium tungstate and 45.2g nickel nitrate hexahydrate for saturated impregnation, after impregnation, dry at 120°C for 180 minutes, 500 Roasting at °C for 4 hours; 19.2 g of dodecylamine was dissolved in 1 L of absolute ethanol, and metal-containing Y molecular sieves were added thereto for beating to obtain slurry (c). Take 10L of water glass (industrial grade, modulus 3.0) and dilute it in 20L of deionized water to prepare solution (d). Take a glue tank, put 2l of deionized water into it, stir and heat it to ...
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