A kind of fdy fiber with surface cracking and preparation method thereof
A fiber and speed technology, applied in the field of FDY fiber and its preparation, can solve problems such as insufficient
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Embodiment 1
[0037] A kind of preparation method of the FDY fiber of surface cracking, comprises the preparation method of low crystallization rate polyester and the preparation method of sheath-core composite fiber:
[0038] 1) The preparation method of the low crystallization rate polyester is divided into two steps of esterification reaction and polycondensation reaction:
[0039] Described esterification reaction:
[0040] Using terephthalic acid, ethylene glycol, isophthalic acid and 1,4-cyclohexanediol as raw materials, the molar ratio of terephthalic acid: ethylene glycol: isophthalic acid: 1,4-cyclohexanediol =100:120:0.5:0.5, make a homogeneous slurry and carry out the esterification reaction; the esterification reaction is carried out in a nitrogen atmosphere, the pressure is controlled at 0.4MPa, the temperature is controlled at 250°C, and the distilled amount of esterified water reaches the theoretical value 90% is the end point of the esterification reaction.
[0041] Descri...
Embodiment 2
[0048] A kind of preparation method of the FDY fiber of surface cracking, comprises the preparation method of low crystallization rate polyester and the preparation method of sheath-core composite fiber:
[0049] 1) The preparation method of the low crystallization rate polyester is divided into two steps of esterification reaction and polycondensation reaction:
[0050] Described esterification reaction:
[0051] Using terephthalic acid, ethylene glycol, isophthalic acid and 1,4-cyclohexanediol as raw materials, the molar ratio of terephthalic acid: ethylene glycol: isophthalic acid: 1,4-cyclohexanediol =100:120:1:2, make a uniform slurry and carry out the esterification reaction; the esterification reaction is pressurized in a nitrogen atmosphere, the pressure is controlled at 0.3MPa, the temperature is controlled at 245°C, and the amount of esterified water distilled reaches the theoretical 90% of the value is the end point of the esterification reaction.
[0052] Describ...
Embodiment 3
[0059] A kind of preparation method of the FDY fiber of surface cracking, comprises the preparation method of low crystallization rate polyester and the preparation method of sheath-core composite fiber:
[0060] 1) The preparation method of the low crystallization rate polyester is divided into two steps of esterification reaction and polycondensation reaction:
[0061] Described esterification reaction:
[0062] Using terephthalic acid, ethylene glycol, isophthalic acid and 1,4-cyclohexanediol as raw materials, the molar ratio of terephthalic acid: ethylene glycol: isophthalic acid: 1,4-cyclohexanediol =100:120:3:5, make a homogeneous slurry and carry out the esterification reaction; the esterification reaction is carried out in a nitrogen atmosphere, the pressure is controlled at 0.4MPa, the temperature is controlled at 230°C, and the distilled amount of esterified water reaches the theoretical value 90% is the end point of the esterification reaction.
[0063] Described ...
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