Slow-release high-efficiency polycarboxylate water reducer and preparation method thereof

A polycarboxylic acid, slow-release technology, applied to concrete admixtures, slow-release high-efficiency polycarboxylate water reducers, the preparation of said polycarboxylate water reducers, and the field of polycarboxylate water reducers can solve the problem of Issues such as no guidance plan are given to achieve high water reduction efficiency, prevent agglomeration, and effective electrostatic adsorption

Active Publication Date: 2015-11-11
SHIJIAZHUANG CHANGAN YUCAI BUILDING MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The above technologies have not given specific guidance on how to make the polycarboxylate superplasticizer have slow release and higher water reducing efficiency

Method used

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  • Slow-release high-efficiency polycarboxylate water reducer and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] Example 1: The slow-release high-efficiency polycarboxylate water reducer is made of the following mass ratio (weight ratio) of raw materials: 6.7 parts of acrylic acid, 1.8 parts of maleic anhydride, polyoxyethylene ether macromonomer 38.7 parts, 4.6 parts of polymer template agent, 1.8 parts of sodium hydroxide, 59.5 parts of deionized water, 0.6 part of peroxide initiator, and 0.5 part of chain transfer agent. The above-mentioned polyoxyethylene ether macromonomer is a combination of isobutenol polyoxyethylene ether HPEG-2400 and isopentenol polyoxyethylene ether TPEG-2400. In 38.7 parts of polyoxyethylene ether macromonomer, isobutenol Polyoxyethylene ether HPEG-2400 accounts for 20 parts, isopentenol polyoxyethylene ether TPEG-2400 accounts for 18.7 parts; the above polymer template is a combination of poly N-vinylpyrrolidone and polyallylamine. In 4.6 parts of polymer templates, poly-N-vinylpyrrolidone accounts for 3 parts, and polyallylamine accounts for 1.6 part...

Embodiment 2

[0020] Example 2: The slow-release high-efficiency polycarboxylate superplasticizer is made of the following mass ratio (weight ratio) of raw materials: 1.5 parts of acrylic acid, 0.5 parts of maleic anhydride, polyoxyethylene ether macromonomer 30.5 parts, 2.5 parts of polymer template, 1.4 parts of sodium hydroxide, 55.3 parts of deionized water, 0.4 parts of peroxide initiator, and 0.2 parts of chain transfer agent.

[0021] The above-mentioned polyoxyethylene ether macromonomer is one or a combination of isobutenol polyoxyethylene ether HPEG-2400, isobutenol polyoxyethylene ether HPEG-3000, isopentenol polyoxyethylene ether TPEG-2400 (the mass ratio can be arbitrary when combined). In this embodiment, the polyoxyethylene ether macromonomer is selected from the combination of isobutenyl alcohol polyoxyethylene ether HPEG-2400 and isobutenyl alcohol polyoxyethylene ether HPEG-3000. In 30.5 parts of polyoxyethylene ether macromonomer, isobutylene Alcohol polyoxyethylene ethe...

Embodiment 3

[0023] Example 3: The slow-release high-efficiency polycarboxylate superplasticizer is made of the following mass ratio (weight ratio): 4.1 parts of acrylic acid, 1.1 parts of maleic anhydride, polyoxyethylene ether macromonomer 34.6 parts, 3.5 parts of polymer template, 1.6 parts of sodium hydroxide, 57.4 parts of deionized water, 0.5 parts of peroxide initiator, and 0.35 parts of chain transfer agent.

[0024] The above-mentioned polyoxyethylene ether macromonomer is one or a combination of isobutenol polyoxyethylene ether HPEG-2400, isobutenol polyoxyethylene ether HPEG-3000, isopentenol polyoxyethylene ether TPEG-2400 (the mass ratio can be arbitrary when combined). In this embodiment, the polyoxyethylene ether macromonomer is selected from isopentenol polyoxyethylene ether TPEG-2400. The above-mentioned polymer template agent is one or a combination of polycarboxylic acid, poly-N-vinylpyrrolidone, poly-2-vinylpyridine, and polyallylamine (the mass ratio of the combinatio...

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Abstract

The invention discloses a slow release type efficient polycarboxylic acid water reducer and a preparation method thereof. The slow release type efficient polycarboxylic acid water reducer is composed of the following materials: acrylic acid, maleic anhydride, polyoxyethylene ether macromonomer, a macromolecule template agent, sodium hydroxide, deionized water, a peroxide initiator and a chain transfer agent. The preparation method comprises the following steps: adding sodium hydroxide and deionized water into a stirring kettle to prepare a sodium hydroxide solution; dropping acrylic acid into the sodium hydroxide solution by using a peristaltic pump to obtain a reaction liquid A; adding the peroxide initiator and deionized water into a material barrel to obtain a dissolving solution B; adding the chain transfer agent and deionized water into a material barrel to obtain a dissolving solution C; adding the polyoxyethylene ether macromonomer, maleic anhydride and the macromolecule template agent into a reaction kettle, and sucking out deionized water to obtain a reaction liquid D; adding the reaction liquid A, the dissolving liquid B and the dissolving liquid C into the reaction liquid D by using a peristaltic pump to obtain the slow release type efficient polycarboxylic acid water reducer. The water reducer provided by the invention has slow release property, relatively high water reducing efficiency, and good water reducing performance and slump loss resistant property.

Description

technical field [0001] The invention relates to a concrete admixture, in particular to a polycarboxylate water reducer, belonging to the technical field of building materials, in particular to a slow-release high-efficiency polycarboxylate water reducer. The invention also relates to a preparation method of the polycarboxylate water reducer. Background technique [0002] Concrete water reducer is an admixture that can reduce the amount of mixing water and improve the strength of concrete under the condition that the workability of concrete and the amount of cement remain unchanged. Concrete water reducer hinders or destroys the flocculation structure of cement particles through the action of surfactant, complexation, electrostatic repulsion or three-dimensional repulsion, so as to save the amount of cement while ensuring the workability and strength of concrete. At present, the commonly used water reducing agents on the market include lignosulfonic acids, polycyclic aromati...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B24/32C08F283/06C08F220/06C08F222/06C08F2/38
Inventor 倪涛王进春刘昭洋苏荣汪咏梅叶子万甜明
Owner SHIJIAZHUANG CHANGAN YUCAI BUILDING MATERIALS
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