A kind of anti-corrosion passivation liquid and its preparation method and application and a kind of hot-dip metal material

A technology for hot-dip metal plating and passivation solution, applied in the field of anti-corrosion passivation solution and hot-dip metal material, can solve problems such as poor corrosion resistance of protective film, and achieve the effects of excellent storage resistance and excellent corrosion resistance.

Inactive Publication Date: 2016-08-03
PANZHIHUA IRON & STEEL RES INST OF PANGANG GROUP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The purpose of the invention is to overcome the poor corrosion resistance defect of the protective film formed by the existing anti-corrosion passivation solution, and provide a kind of anti-corrosion passivation solution capable of forming a better protective film with corrosion resistance

Method used

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  • A kind of anti-corrosion passivation liquid and its preparation method and application and a kind of hot-dip metal material

Examples

Experimental program
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preparation example Construction

[0013] The invention provides a method for preparing an anti-corrosion passivation solution, which comprises mixing water, a silane coupling agent, a water-soluble silicate, a silicon oxide filler and a water-soluble film-forming resin in sequence; the silane coupling The agent includes a first silane coupling agent and a second silane coupling agent, and the first silane coupling agent is R-Si(OCH 3 ) 3 , R-Si(OC 2 h 5 ) 3 , R-SiCH 3 (OCH 3 ) 2 and R-SiCH 3 (OC 2 h 5 ) 2 At least one of, and each R is independently selected from NH 2 (CH 2 ) 2 NH(CH 2 ) 3 -, NH 2 (CH 2 ) 2 NHCH 2 CH(CH 3 )CH 2 -, HO(CH 2 ) 2 NH(CH 2 ) 2 NH(CH 2 ) 3 - or NH 2 (CH 2 ) 2 NH(CH 2 ) 2 NH(CH 2 ) 3 -; The second silane coupling agent is HS (CH 2 ) 3 Si(OCH 3 ) 3 、HS(CH 2 ) 3 Si(OC 2 h 5 ) 3 、HS(CH 2 ) 3 SiCH 3 (OCH 3 ) 2 and HS(CH 2 ) 3 SiCH 3 (OC 2 h 5 ) 2 at least one of the

[0014] Wherein, in detail, the method includes: (1) uniformly mixing...

Embodiment 1

[0051] Mix 28 parts by weight of water and 1.6 parts by weight of silane coupling agent (composed of the first silane coupling agent and the second silane coupling agent) at a stirring speed of 1500 rpm to obtain uniform liquid A, Among them, the first silane coupling agent is NH 2 (CH 2 ) 2 NH(CH 2 ) 3 Si(OCH 3 ) 3 , purchased from Hubei Debang Chemical New Material Co., Ltd., brand DB-792, the second silane coupling agent is HS (CH 2 ) 3 Si(OCH 3 ) 3 , purchased from Hubei Debang Chemical New Material Co., Ltd., brand DB-590, the weight ratio of the first silane coupling agent and the second silane coupling agent is 1:0.5.

[0052] Mix all the uniform liquid A and 1 part by weight of water-soluble silicate (sodium metasilicate pentahydrate, purchased from Qingdao Darun Chemical Co., Ltd.) at a stirring speed of 1500 rpm until uniform to obtain uniform liquid B .

[0053] All the homogeneous liquid B and 0.72 parts by weight of silica filler (nano silica sol, purch...

Embodiment 2

[0066] Mix 25 parts by weight of water and 1.4 parts by weight of silane coupling agent (composed of the first silane coupling agent and the second silane coupling agent) at a stirring speed of 1500 rpm to obtain a homogeneous liquid A, Among them, the first silane coupling agent is NH 2 (CH 2 ) 2 NH(CH 2 ) 3 Si(OC 2 h 5 ) 3 , purchased from Hubei Debang Chemical New Material Co., Ltd., brand DB-793, the second silane coupling agent is HS (CH 2 ) 3 Si(OC 2 h 5 ) 3 , purchased from Hubei Debang Chemical New Material Co., Ltd., brand DB-580, the weight ratio of the first silane coupling agent and the second silane coupling agent is 1:0.4.

[0067] All of the uniform liquid A and 1 part by weight of water-soluble silicate (potassium silicate, purchased from Baoding Runfeng Industrial Co., Ltd.) were mixed until uniform at a stirring speed of 1500 rpm to obtain a uniform liquid B.

[0068] Mix all the homogeneous liquid B and 0.6 parts by weight of silica filler (nano-...

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Abstract

The invention provides a preparation method of an anticorrosion passivation solution, which comprises uniformly mixing water, a silane coupling agent, a water-soluble silicate, a silicon oxide filler and a water-soluble film-forming resin in sequence. The present invention also provides the anti-corrosion passivation solution prepared according to the above-mentioned preparation method and the application of the above-mentioned anti-corrosion passivation solution in the preparation of metal materials. The present invention also provides a hot-dip metal material, which includes a hot-dip metal substrate and a coating attached to the hot-dip metal substrate, the coating is the above-mentioned anti-corrosion passivation liquid solidified product. The protective film formed by the anti-corrosion passivation solution provided by the invention has excellent corrosion resistance. In addition, the anti-corrosion passivation solution provided by the invention has excellent storage resistance, and can be stored at room temperature for 180 days after preparation without obvious change in properties and performance decline.

Description

technical field [0001] The invention relates to the field of metal protection, in particular to a preparation method of an anti-corrosion passivation solution, an anti-corrosion passivation solution obtained by the preparation method, uses of the anti-corrosion passivation solution and a hot-dip metal material. Background technique [0002] Hot-dip metal materials, including hot-dip galvanized metal materials and hot-dip galvanized metal materials, in order to prevent corrosion, a layer of anti-corrosion passivation solution will be coated on the surface of the hot-dip metal materials to form a protective film. Therefore, the performance of the anti-corrosion passivation solution is very important for the anti-corrosion of hot-dip metal materials. [0003] For example, CN101608306A discloses a passivation solution, which also belongs to an anti-corrosion passivation solution, and is characterized in that the passivation solution is an aqueous solution containing water-solubl...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D167/00C09D125/14C09D163/00C09D175/04C09D133/04C09D133/00C09D127/12C09D7/12C09D5/08
Inventor 许哲锋李纪仁李南黄平生李光跃
Owner PANZHIHUA IRON & STEEL RES INST OF PANGANG GROUP
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