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Pesticide wastewater dephosphorizing agent

A technology for pesticide wastewater and phosphorus removal agent, which is applied in water/sewage treatment, adsorbed water/sewage treatment, oxidized water/sewage treatment, etc., can solve the problems of low phosphorus removal efficiency, difficult preparation, and large dosage, etc. Achieve the effect of improving the treatment effect, reducing the total phosphorus content and producing less sludge

Active Publication Date: 2014-10-15
临安天川环保科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, some domestic and foreign incineration methods are used to treat high-concentration organophosphorus pesticide wastewater, but this method has high cost, high energy consumption, and is prone to produce secondary pollutants such as waste residue and waste gas, causing environmental hazards, and it is difficult for the effluent to reach the national level. standard
In addition, there are also chemical methods, such as single dosing of metal salts to remove phosphorus, but the disadvantage is that the cost of chemicals is significantly higher than that of biological phosphorus removal systems that rarely add chemicals, and the amount of sludge produced is significantly greater than that of treatment systems that do not add chemicals. It may cause the existing sludge treatment system to be overloaded, and the sludge treatment and disposal costs will increase accordingly, and the dewatering performance of the generated sludge is not as good as that of conventional water treatment plants without chemicals
[0004] For the treatment of pesticide wastewater, at present, there are many domestic patents, but most of them focus on inorganic phosphorus pesticide wastewater
Most of the existing organic phosphorus pesticide wastewater phosphorus removal agents are difficult to prepare, the dosage is large, and the phosphorus removal efficiency is not high, and they are mostly used to treat low-concentration wastewater

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] Mix 67g of ferrous sulfate, 27g of aluminum sulfate, 3g of hydrogen peroxide, and 3g of sodium hypochlorite evenly to obtain 100g of compound agent; dissolve 25g of the above compound agent in 250g of deionized water, then add 0.5g of polyacrylamide flocculant, stir to dissolve evenly Obtain 275.5g pesticide wastewater phosphorus removal agent after complete.

[0022] Take 1000mL of organophosphorus pesticide wastewater from a company in Zhejiang Province, dilute the total phosphorus to 125mg / L, adjust the pH to about 3-4, add 30ml of the pesticide wastewater phosphorus removal agent prepared in Example 1, stir at room temperature for 30min, and then use NaOH to adjust the pH to 6 or so, let it stand for 30 minutes, the results show that the phosphorus content in the effluent is less than 1mg / L, and the removal rate of phosphorus is 99.51%.

Embodiment 2

[0024] Mix 67g of ferrous sulfate, 27g of aluminum sulfate, 3g of hydrogen peroxide, and 3g of sodium hypochlorite evenly to obtain 100g of compound agent; dissolve 25g of the above compound agent in 250g of deionized water, then add 0.5g of polyacrylamide flocculant, stir to dissolve evenly Obtain 275.5g pesticide wastewater phosphorus removal agent after complete.

[0025] Take 1000mL of organophosphorus pesticide wastewater from a company in Zhejiang Province, dilute the total phosphorus to 103mg / L or more, adjust the pH to about 3-4, add 30ml of the pesticide wastewater phosphorus removal agent prepared in Example 2, stir at room temperature for 40min, and then adjust the pH with NaOH When it reached 7 or so, let it stand for 30 minutes. The results showed that the phosphorus content in the effluent was less than 1mg / L, and the removal rate of phosphorus was 99.13%.

Embodiment 3

[0027] Mix 70g of polyferric sulfate, 22g of aluminum sulfate, 5g of hydrogen peroxide, and 3g of sodium hypochlorite evenly to obtain 100g of compound agent; dissolve 25g of the above compound agent in 250g of deionized water, then add 1.0g of polyacrylamide flocculant, stir to dissolve evenly Obtain 276g pesticide wastewater phosphorus removal agent after complete.

[0028] Take 1000mL of organophosphorus pesticide wastewater from a company in Zhejiang Province, dilute the total phosphorus to 115mg / L, adjust the pH to about 3-4, add 30ml of the pesticide wastewater phosphorus removal agent prepared in Example 3, stir at room temperature for 30min, and then use NaOH to adjust the pH to 9 or so, let it stand for 30 minutes, the results show that the phosphorus content in the effluent is less than 0.5mg / L, and the removal rate of phosphorus is 99.61%.

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PUM

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Abstract

The invention discloses a pesticide wastewater dephosphorizing agent which is a mixture. The mixture comprises a compound medicament, a flocculating agent and a water aqua according to the weight ratio of 25 : (0.5-1.5) : 250. According to the production process, raw materials and the like of the phosphorus containing pesticide, the characteristic of wastewater and the form of phosphate are analyzed, optimal pharmacy prescription is screened aiming at the nature difference of inorganic phosphorus and organic phosphorus, and ferric salt, aluminium salt, hydrogen peroxide, hydrogen peroxide and polyacrylamide are adopted to form the compound medicament integrating an efficient complexing agent, an oxidizing agent, an adsorbing agent and the flocculating agent as a whole, and the total phosphorus content of pesticide wastewater is greatly reduced. The pesticide wastewater dephosphorizing agent has the characteristics that the investment cost is lower, the operating cost is saved, and the generated sludge quantity is less, the effluent of the organic phosphorus pesticide wastewater treated through the dephosphorizing agent can reach the standard request of being lower than 1 mg/L, and the pesticide wastewater dephosphorizing agent has important significance on stable operation of pesticide industry production.

Description

technical field [0001] The invention belongs to the field of pesticide wastewater treatment, in particular to a pesticide wastewater phosphorus removal agent. Background technique [0002] In recent years, my country's pesticide industry has developed rapidly, and its annual production capacity has reached more than 1.5 million tons. The total output ranks first in the world, and it is a major pesticide exporter. Shandong, Jiangsu, and Zhejiang are the top three pesticide production areas in my country. Through the prevention and control of pesticides, 54 million tons of grain losses have been recovered every year across the country. As a substitute for organochlorine pesticides, organophosphorus pesticides are currently widely used at home and abroad because of their high efficiency, broad spectrum, and low residue. They are currently the most widely used pesticides. The national "Twelfth Five-Year Plan" pointed out that it is necessary to implement major demonstration pr...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F1/56C02F1/72C02F1/76C02F1/28C02F1/00
Inventor 陈建军孙蔓陈雪丹
Owner 临安天川环保科技有限公司
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