Low-temperature rapidly cured acrylic ester modified epoxy resin joint sealant used in road and bridge
A fast-curing, acrylate technology, used in modified epoxy resin adhesives, adhesive additives, non-polymer adhesive additives, etc., can solve the problems of prolonged curing time, affecting the normal traffic of bridges, and water resistance. , to achieve the effect of preventing secondary fatigue cracking, excellent low temperature permeability, and excellent adhesion performance
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Embodiment 1
[0032] Raw material preparation:
[0033] 1) Graft-polymerized epoxy resin and acrylic acid (ester) copolymer: Take 40 parts of bisphenol F diglycidyl ether (BPF), 5 parts of methyl methacrylate, 5 parts of ethyl methacrylate, methacrylic acid After 10 parts were mixed, 0.2% by mass of BPO promoter was added, and the reaction was carried out for 6.5-7h under a protective gas atmosphere and an oil bath temperature of 90°C, subject to the end of the reaction exotherm, to prepare a graft-polymerized ring Oxygen resin and acrylic copolymer, ready to use.
[0034] 2) Acrylic monomer: Take 15 parts of methyl methacrylate, 10 parts of ethyl methacrylate, 12 parts of styrene, 8 parts of lauryl methacrylate, 6 parts of acetoacetate ethyl methacrylate (AAEM), γ - 2 parts of methacryloxypropyltrimethoxysilane, 1 part of N-methylolacrylamide, 1 part of N-butylmethyl (meth)acrylamide, 1 part of 2-hydroxyethyl acrylate, acrylic acid 1 part of 2-hydroxypropyl methacrylate, 1 part of 2-hydr...
Embodiment 2
[0042] Raw material preparation:
[0043] 1) Graft-polymerized epoxy resin and acrylic acid (ester) copolymer: Take 30 parts of bisphenol F diglycidyl ether (BPF), 15 parts of methyl methacrylate, 11 parts of ethyl methacrylate, methacrylic acid After mixing the 6 parts, add 0.2% by mass of the BPO accelerator, and react for 6.5-7 hours under the protective gas atmosphere and the temperature of the oil bath at 90°C. Subject to the end of the reaction exotherm, the graft-polymerized ring Oxygen resin and acrylic copolymer, ready to use.
[0044] 2) Acrylic monomer: Take 5 parts of methyl methacrylate, 3 parts of ethyl methacrylate, 3 parts of styrene, 12 parts of lauryl methacrylate, 5 parts of acetoacetate ethyl methacrylate (AAEM), γ - 1 part of methacryloxypropyltrimethoxysilane, 1 part of N-methylolacrylamide, 1 part of diacetone acrylamide (DAAM), 1 part of 2-hydroxyethyl acrylate, 2- 1 part of hydroxypropyl ester, 1 part of 2-hydroxyethyl methacrylate, and 1 part of 2-h...
Embodiment 3
[0052] Raw material preparation:
[0053] 1) Graft-polymerized epoxy resin and acrylic acid (ester) copolymer: Take 45 parts of bisphenol F diglycidyl ether (BPF), 22 parts of methyl methacrylate, 10 parts of ethyl methacrylate, methacrylic acid After mixing 8 parts of styrene and 4 parts of styrene, 0.5% by mass of BPO promoter was added, and the reaction was carried out for 7.5 hours under a protective gas atmosphere and at a temperature of 90°C in an oil bath. Branch polymerized epoxy resin and acrylic copolymer, ready to use.
[0054] 2) Acrylic monomer: Take 5 parts of methyl methacrylate, 3 parts of ethyl methacrylate, 3 parts of styrene, 12 parts of lauryl methacrylate, 5 parts of acetoacetate ethyl methacrylate (AAEM), γ - 1 part of methacryloxypropyltrimethoxysilane, 1 part of N-methylolacrylamide, 1 part of diacetone acrylamide (DAAM), 1 part of 2-hydroxyethyl acrylate, 2- 1 part of hydroxypropyl ester, 1 part of 2-hydroxyethyl methacrylate, 1 part of 2-hydroxyprop...
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