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Low-temperature rapidly cured acrylic ester modified epoxy resin joint sealant used in road and bridge

A fast-curing, acrylate technology, used in modified epoxy resin adhesives, adhesive additives, non-polymer adhesive additives, etc., can solve the problems of prolonged curing time, affecting the normal traffic of bridges, and water resistance. , to achieve the effect of preventing secondary fatigue cracking, excellent low temperature permeability, and excellent adhesion performance

Active Publication Date: 2014-12-24
JIANGSU TRANSPORTATION RES INST CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Chinese patent CN10192146A provides a crack repair agent, including two mixtures of A and B, the A mixture includes epoxy resin, toughening agent, epoxy reactive diluent, and the B mixture includes modified amine curing agent, accelerator and organic silicon Oxyalkylene coupling agent, although its overall performance is superior to traditional asphalt joint filling materials, but it has defects such as high brittleness, poor toughness, water resistance, and acid resistance.
The resin has the advantages of high bonding strength, good toughness, low viscosity, good wettability, and curing at room temperature. However, even at room temperature, the curing time is as long as 3-5 hours. The curing time will be extended, which will seriously affect the construction efficiency. If the traffic is closed for a long time, it will affect the normal traffic of the bridge, and in severe cases, it will affect the traffic safety.

Method used

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  • Low-temperature rapidly cured acrylic ester modified epoxy resin joint sealant used in road and bridge
  • Low-temperature rapidly cured acrylic ester modified epoxy resin joint sealant used in road and bridge
  • Low-temperature rapidly cured acrylic ester modified epoxy resin joint sealant used in road and bridge

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] Raw material preparation:

[0033] 1) Graft-polymerized epoxy resin and acrylic acid (ester) copolymer: Take 40 parts of bisphenol F diglycidyl ether (BPF), 5 parts of methyl methacrylate, 5 parts of ethyl methacrylate, methacrylic acid After 10 parts were mixed, 0.2% by mass of BPO promoter was added, and the reaction was carried out for 6.5-7h under a protective gas atmosphere and an oil bath temperature of 90°C, subject to the end of the reaction exotherm, to prepare a graft-polymerized ring Oxygen resin and acrylic copolymer, ready to use.

[0034] 2) Acrylic monomer: Take 15 parts of methyl methacrylate, 10 parts of ethyl methacrylate, 12 parts of styrene, 8 parts of lauryl methacrylate, 6 parts of acetoacetate ethyl methacrylate (AAEM), γ - 2 parts of methacryloxypropyltrimethoxysilane, 1 part of N-methylolacrylamide, 1 part of N-butylmethyl (meth)acrylamide, 1 part of 2-hydroxyethyl acrylate, acrylic acid 1 part of 2-hydroxypropyl methacrylate, 1 part of 2-hydr...

Embodiment 2

[0042] Raw material preparation:

[0043] 1) Graft-polymerized epoxy resin and acrylic acid (ester) copolymer: Take 30 parts of bisphenol F diglycidyl ether (BPF), 15 parts of methyl methacrylate, 11 parts of ethyl methacrylate, methacrylic acid After mixing the 6 parts, add 0.2% by mass of the BPO accelerator, and react for 6.5-7 hours under the protective gas atmosphere and the temperature of the oil bath at 90°C. Subject to the end of the reaction exotherm, the graft-polymerized ring Oxygen resin and acrylic copolymer, ready to use.

[0044] 2) Acrylic monomer: Take 5 parts of methyl methacrylate, 3 parts of ethyl methacrylate, 3 parts of styrene, 12 parts of lauryl methacrylate, 5 parts of acetoacetate ethyl methacrylate (AAEM), γ - 1 part of methacryloxypropyltrimethoxysilane, 1 part of N-methylolacrylamide, 1 part of diacetone acrylamide (DAAM), 1 part of 2-hydroxyethyl acrylate, 2- 1 part of hydroxypropyl ester, 1 part of 2-hydroxyethyl methacrylate, and 1 part of 2-h...

Embodiment 3

[0052] Raw material preparation:

[0053] 1) Graft-polymerized epoxy resin and acrylic acid (ester) copolymer: Take 45 parts of bisphenol F diglycidyl ether (BPF), 22 parts of methyl methacrylate, 10 parts of ethyl methacrylate, methacrylic acid After mixing 8 parts of styrene and 4 parts of styrene, 0.5% by mass of BPO promoter was added, and the reaction was carried out for 7.5 hours under a protective gas atmosphere and at a temperature of 90°C in an oil bath. Branch polymerized epoxy resin and acrylic copolymer, ready to use.

[0054] 2) Acrylic monomer: Take 5 parts of methyl methacrylate, 3 parts of ethyl methacrylate, 3 parts of styrene, 12 parts of lauryl methacrylate, 5 parts of acetoacetate ethyl methacrylate (AAEM), γ - 1 part of methacryloxypropyltrimethoxysilane, 1 part of N-methylolacrylamide, 1 part of diacetone acrylamide (DAAM), 1 part of 2-hydroxyethyl acrylate, 2- 1 part of hydroxypropyl ester, 1 part of 2-hydroxyethyl methacrylate, 1 part of 2-hydroxyprop...

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Abstract

The invention discloses a low-temperature rapidly cured acrylic ester modified epoxy resin joint sealant used in roads and bridges. The joint sealant comprises a component A and a component B, wherein the component A comprises 55 parts of bisphenol F diglycidyl ether, 10-12 parts of graft polymerized epoxy resin and acrylic copolymer and 33-60 parts of an acrylic monomer; the component B comprises 5-15 parts of modified 1,3-cyclohexanediamine and 30-45 parts of modified hexamethylenediamine; the joint sealant is prepared by respectively stirring and mixing the component A and the component B, mixing the two components in the mass ratio of 100:(90-100), uniformly stirring, adding 1-5 parts by mass of an accelerant diacyl organic peroxide into the mixed liquid, and further stirring. The joint sealant disclosed by the invention is high in binding strength, has the characteristic of excellent aging resistance, low flexibility, low viscosity, high interface binding force, secondary fatigue cracking resistance and the like, and can be used in joint sealing construction all year around.

Description

technical field [0001] The invention relates to materials for preventive maintenance of resin asphalt and epoxy asphalt mixture pavement layers, and asphalt pavement rapid filling and repairing materials, in particular to a low-temperature rapid curing acrylate modified epoxy resin joint glue for road bridges. Background technique [0002] As thermosetting resin materials, resin asphalt RA and epoxy asphalt EA have strong anti-rutting and anti-fatigue damage capabilities. It was reported that epoxy resin modified asphalt was synthesized and put into engineering application. Since the first introduction of epoxy asphalt pavement technology in Nanjing Second Bridge in 2001, by the end of 2013, the total area of ​​domestic epoxy asphalt pavement has reached more than 1 million m2. However, due to the high-temperature and heavy-duty use environment in China and the overall low construction level of steel bridge deck pavement in China, domestic epoxy asphalt pavement often begin...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J163/10C09J11/04C09J11/06C08F283/10C08F220/14C08F220/18C08F212/08C08F220/28C08F220/68C08F220/54
Inventor 于迪尔曹荣吉吴春颖刘伟张辉朱雷纵瑾瑜
Owner JIANGSU TRANSPORTATION RES INST CO LTD
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