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Cordierite with silicon-titanium oxide grown on its surface and preparation method thereof

A surface growth and cordierite technology, applied in chemical instruments and methods, chemical/physical processes, catalyst supports, etc., can solve the problems of small specific surface area and poor treatment effect of cordierite supports, and achieve increased binding force and specific surface area , the effect of a wide range of application prospects

Active Publication Date: 2016-08-17
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In this method, the pretreatment of honeycomb ceramic cordierite adopts nitric acid immersion treatment, and the treatment effect of this method is relatively poor, and the specific surface area of ​​the obtained cordierite carrier is small

Method used

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  • Cordierite with silicon-titanium oxide grown on its surface and preparation method thereof
  • Cordierite with silicon-titanium oxide grown on its surface and preparation method thereof
  • Cordierite with silicon-titanium oxide grown on its surface and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0022] Put the cut cordierite into the polytetrafluoroethylene lining of the autoclave, add 5% hydrochloric acid solution to the lining to completely immerse the cordierite, seal the autoclave and place it in an oven at 250°C for 2 hours of hydrothermal treatment . After the hydrothermal treatment, the cordierite carrier was washed with distilled water until the washing liquid was neutral, and the distilled water on the surface was blown off with an air compressor, dried at 120°C for 8 hours, and calcined at 550°C for 3 hours to obtain a silicon-titanium oxide content of 2.8wt%. The properties of the product A1 are shown in Table 1.

Embodiment 2

[0024] Same as Example 1, except that 15% nitric acid solution was used instead for hydrothermal treatment at 100°C for 3 hours to obtain product A2 with a silicon-titanium oxide content of 0.5wt%, and its properties are shown in Table 1.

Embodiment 3

[0026] Same as Example 1, except that 20% mixed acid solution of nitric acid and hydrochloric acid (the mass ratio of nitric acid and hydrochloric acid is 1:1) was used for hydrothermal treatment at 150°C for 0.5 hours to obtain a product with a silicon titanium oxide content of 0.8wt%. A3, see Table 1 for properties.

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Abstract

The invention discloses a honeycomb cordierite with a silicon titanium oxide grown on surface of cordierite, the silicon titanium oxide is distributed on the tunnel surface of honeycomb cordierite, by measuring according to mass percentage, content of the silicon titanium oxide is 0.1-3%, and mass ratio of SiO2 to TiO2 in the silicon titanium oxide is 0.8:1-2:1. The preparation method comprises the following steps: performing hydro-thermal treatment on the honeycomb cordierite in an acidic solution, then washing and drying, and roasting to obtain a modified cordierite carrier. According to the method, cordierite strength is kept, specific surface area of the cordierite carrier can be obviously increased simultaneously, treatment process is simple, by taking cordierite as the carrier, coating load capacity is large, and the combination between the coating and the carrier is firm.

Description

technical field [0001] The invention relates to a cordierite carrier with silicon-titanium oxide grown on the surface and a preparation method thereof. Background technique [0002] Compared with general bulk ceramics, monolithic honeycomb cordierite is especially suitable for catalyst supports for various purposes due to its stable performance, low expansion coefficient, high void ratio, low pressure drop and high geometric surface area. Environmental protection, metallurgy, electronics, automobiles and other fields have broad application prospects. Since the surface of the cordierite honeycomb ceramic carrier is relatively smooth, the specific surface area is small (<1m 2 / g), the active ingredient is difficult to uniformly disperse on the surface of the carrier. In order to increase the specific surface area of ​​the carrier, alumina sol with a higher specific surface area is usually coated on the surface of the cordierite to increase the specific surface area of ​​t...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J32/00B01J21/14B01J35/04
Inventor 季洪海王诗语耿晨晨凌凤香王少军
Owner CHINA PETROLEUM & CHEM CORP