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Herbicide containing glyphosate and dicamba and preparation method thereof

A herbicide and glyphosate technology, applied in the field of pesticides, can solve problems such as the inability to accurately grasp the ratio of glyphosate and dicamba, the inability of pesticides to achieve control effects, and the inability to achieve accurate quantification, so as to reduce drying costs, The effect of reducing the yield and requiring less equipment

Inactive Publication Date: 2015-04-01
SHANDONG WEIFANG RAINBOW CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] First of all, the simple tank mixing method cannot accurately grasp the ratio of glyphosate and dicamba, and for the compound use of the two pesticides, the difference in the ratio will cause significant differences in the efficacy
This may cause the mixed pesticide to not achieve the best control effect
[0007] Secondly, in most cases, the tank mixing method does not add additives, even if it is added, it cannot be accurately quantified, and the type and amount of additives also play a vital role in the efficacy of pesticides
[0008] Moreover, since both glyphosate and dicamba are acidic substances and are not easily soluble in water, simply mixing the two in a tank is likely to greatly reduce the efficacy of the drug due to precipitation
Although there is currently a method of salting the two to improve solubility, the salt-forming process is mostly carried out in a solvent and then crystallized again to obtain the salt, which causes the loss of the product
Moreover, salting glyphosate and dicamba before mixing also increases the complexity of the operation

Method used

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  • Herbicide containing glyphosate and dicamba and preparation method thereof
  • Herbicide containing glyphosate and dicamba and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0053] Preparation of Example 1 Glyphosate 60% and Dicamba 20% Sodium Salt Soluble Granules

[0054] With 631g glyphosate (95%) and 204g dicamba (98%), 17g sodium sulfate and 393g sodium bicarbonate, drop in the kneader, after mixing uniformly, be warming up to 50 ℃ under normal pressure, react 40min, add 50g cattle Esteramine polyoxyethylene ether is used to prepare kneading materials, and after granulation, drying and sieving, 998.4 g of glyphosate 60% and dicamba 20% sodium salt soluble granules are obtained, with a yield of 99.84%.

Embodiment 2

[0055] Embodiment 2 Preparation of glyphosate 60% and dicamba 20% potassium salt soluble granules

[0056] Put 618g of glyphosate (97%), 204g of dicamba (98%) and 467g of potassium bicarbonate into a kneader, after mixing evenly, react for 60min at 45°C under normal pressure, add 50g of alkyl glucoside to obtain The kneaded material was granulated, dried and sieved to obtain 1000.8 g of glyphosate 60% and dicamba 20% potassium salt soluble granules with a yield of 100.08%.

Embodiment 3

[0057] Embodiment 3 Preparation of glyphosate 60% and dicamba 20% ammonium salt soluble granules

[0058] Put 631g of glyphosate (95%) and 204g of dicamba (98%), 40g of ammonium sulfate and 369g of ammonium bicarbonate into a kneader, after mixing evenly, react for 50min at 55°C under normal pressure, and add 50g of tallow Amine polyoxyethylene ether and alkyl glucoside mixture, obtained kneading material, after granulation, drying, sieving, 999.8g of glyphosate 60% and dicamba 20% ammonium salt soluble granules were obtained, yield 99.98%.

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Abstract

The invention relates to the technical field of a pesticide and particularly relates to a herbicide containing glyphosate and dicamba and a preparation method thereof. The herbicide is prepared from the following raw materials in parts by weight: 40-65 parts of glyphosate, 15-25 parts of dicamba, 27-48 parts of alkaline substances, 2-5 parts of a surface active agent and 0-5 parts of inorganic filler. Verified by experiments, when the mass ratio of the glyphosate to the dicamba is 3 to 1, the optimal synergistic effect can be generated; by selection of proper surface active agent and proper used amount, the pesticide effect is obviously improved; verified by experiments, N-polyoxyethylated-N-tallow-alkylamine or alkyl polyglucoside is selected as the surface active agent, and when the weight part of N-polyoxyethylated-N-tallow-alkylamine or alkyl polyglucoside is 5, the obvious synergistic effect can be achieved, the foaming property is not more than 20mL, and the dissolution of a preparation cannot be influenced; and in addition, the invention also provides a preparation method of the herbicide. In preparation, a solid-solid synthesis process is adopted, the production efficiency is improved, the production cost is saved and the energy consumption is reduced.

Description

technical field [0001] The invention relates to the technical field of pesticides, in particular to a herbicide containing glyphosate and dicamba and a preparation method thereof. Background technique [0002] Glyphosate is a non-selective, non-residual herbicide that kills perennial root weeds and is widely used in rubber, mulberry, tea, orchards and sugarcane fields. Glyphosate was initially used in rubber gardens to control thatch and other weeds, which can make rubber tapping one year earlier and increase the production of old rubber trees. It is now gradually being used in forestry, orchards, mulberry gardens, tea gardens, rice-wheat, rice and rapeseed rotations, etc. place. Various weeds have different sensitivity to glyphosate, so the dosage is also different. For example, annual weeds such as barnyardgrass, green foxtail, goosegrass, crabgrass, and cattail, the dosage is calculated as 6~10.5g / 100m; the dosage of psyllium, chrysanthemum, and commelina is 11.4~15g / 10...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): A01N57/20A01N25/30A01N25/14A01P13/00A01N37/40
Inventor 孙国庆侯永生陈帅吴勇
Owner SHANDONG WEIFANG RAINBOW CHEM
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