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Bipolar polymer blue light host material, preparation method and applications thereof

A blue-light main material and polymer technology, which is applied in the direction of luminescent materials, chemical instruments and methods, semiconductor/solid-state device manufacturing, etc., can solve the problems of low luminous efficiency, achieve low raw material prices, reduce manufacturing costs, and excellent film-forming performance Effect

Inactive Publication Date: 2015-04-15
OCEANS KING LIGHTING SCI&TECH CO LTD +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the luminous efficiency of this phosphorescent material is low

Method used

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  • Bipolar polymer blue light host material, preparation method and applications thereof
  • Bipolar polymer blue light host material, preparation method and applications thereof
  • Bipolar polymer blue light host material, preparation method and applications thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] Example 1: The bipolar polymer blue light host material of this example, that is, poly{3,8-diyl-4,7-diphenyl-1,10-phenanthroline-co-2,7-di Base-3,6-bis(diphenylphosphineoxy)-9-n-hexyl-9H-carbazole} (P1) (where R is n-hexyl, n=47), its structural formula is as follows:

[0028]

[0029] The preparation steps of above-mentioned polymer are as follows:

[0030] The reaction formula is as follows:

[0031]

[0032] Under the protection of argon, 3,8-dibromo-4,7-diphenyl-1,10-phenanthroline (99 mg, 0.2 mmol), 2,7-dibromo-3,6-bis(di Phenylphosphineoxy)-9-n-hexyl-9H-carbazole (162mg, 0.2mmol) was added into a flask containing 10ml of toluene solvent, and after fully dissolving, potassium carbonate (2mL, 2mol / L) solution was added into the flask, Vacuumize to remove oxygen and fill with argon, then add bistriphenylphosphinepalladium dichloride (5.6mg, 0.008mmol); heat the flask to 100°C for Suzuki coupling reaction for 48h. Subsequently, the polymerization reaction was...

Embodiment 2

[0035] Example 2: The bipolar polymer blue light host material of this example, that is, poly{3,8-diyl-4,7-diphenyl-1,10-phenanthroline-co-2,7-di -3,6-di(diphenylphosphineoxy)-9-n-eicosyl-9H-carbazole} (P2) (where R is n-eicosyl, n=100), its structural formula is as follows :

[0036]

[0037] The preparation steps of above-mentioned polymer are as follows:

[0038] The reaction formula is as follows:

[0039]

[0040] Under the protection of mixed gas of nitrogen and argon, 3,8-dibromo-4,7-diphenyl-1,10-phenanthroline (147mg, 0.3mmol), 2,7-dibromo-3,6- Add bis(diphenylphosphineoxy)-9-n-eicosyl-9H-carbazole (302mg, 0.3mmol) and 15mL tetrahydrofuran into a 50mL two-necked bottle, and after fully dissolving, inject a mixture of nitrogen and argon After exhausting the air for about 20 minutes, tetrakistriphenylphosphine palladium (4mg, 0.003mmol) was added into it, and after fully dissolved, sodium bicarbonate (3mL, 2mol / L) solution was added. Then, the mixed gas of nit...

Embodiment 3

[0042] Example 3: The bipolar polymer blue light host material of this example, that is, poly{3,8-diyl-4,7-diphenyl-1,10-phenanthroline-co-2,7-di Base-3,6-bis(diphenylphosphineoxy)-9-methyl-9H-carbazole}(P3) (where R is methyl, n=79), its structural formula is as follows:

[0043]

[0044] The preparation steps of above-mentioned polymer are as follows:

[0045] The reaction formula is as follows:

[0046]

[0047] Under nitrogen protection, 3,8-dibromo-4,7-diphenyl-1,10-phenanthroline (147mg, 0.3mmol), 2,7-dibromo-3,6-bis(diphenyl Phosphinoxy)-9-methyl-9H-carbazole (244mg, 0.33mmol), palladium acetate (3.5mg, 0.015mmol) and tri(o-methylphenyl)phosphine (21mg, 0.06mmol) were added to a 12mL In the flask of N,N-dimethylformamide, add potassium carbonate (3mL, 2mol / L) solution after fully dissolving, then pass nitrogen into the flask and exhaust the air for about 30min; heat the flask to 130°C for Suzuki coupling Reaction 12h. Subsequently, stop the polymerization reacti...

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Abstract

The invention belongs to the field of organic electroluminescent materials, and discloses a bipolar polymer blue light host material, a preparation method and applications thereof. The structural formula of the host material is shown in the description, wherein in the formula, the R represents a C1-C20 alkyl group, and the n represents an integer in a range of 15 to 100. In the provided bipolar polymer blue light host material, the diphenyl phosphine oxide contains an electron-absorbing structure P=O, which is a good electron transmission unit; the carbazole is an important electroluminescent material, and has an excellent hole transmission performance, and the nitrogen atom of carbazole can be modified by an alkyl group so as to improve the solubility and film-forming performance of copolymerized carbazole. Phenanthroline has a big planar rigid structure, and phosphine oxide-carbazole can be introduced into the main chain of the phenanthroline polymer so as to improve the luminescent efficiency of organic electroluminescent devices.

Description

technical field [0001] The invention relates to the field of organic electroluminescent materials, in particular to a bipolar polymer blue light host material and its preparation method and application. Background technique [0002] Since 1987, C.W.Tang et al. of Kodak reported for the first time that Alq 3 Since the double-layer device structure of light-emitting materials, organic electroluminescence has received great attention. Organic electroluminescence can be divided into fluorescence and phosphorescence electroluminescence. According to the spin quantum statistical theory, the formation probability ratio of singlet excitons and triplet excitons is 1:3, that is, singlet excitons only account for 25% of the "electron-hole pairs". Therefore, the fluorescence from the radiative transition of singlet excitons only accounts for 25% of the total input energy, while the electroluminescence of phosphorescent materials can utilize the energy of all excitons, so it has greate...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G61/12C09K11/06H01L51/54
Inventor 周明杰张振华王平黄辉
Owner OCEANS KING LIGHTING SCI&TECH CO LTD
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