A kind of rare earth permanent magnet made from mixed rare earth of Baiyun Obo co-associated raw ore and its preparation method

A technology of rare earth permanent magnets and mixed rare earths, which is applied in the fields of magnetic objects, magnetic materials, inductors/transformers/magnets, etc., can solve problems such as failure to consider the co-occurrence characteristics of rare earth elements, unbalanced use of rare earth resources, and ecological environment pollution. Achieve the effects of reducing rare earth separation steps and separation requirements, improving grain boundary phases, and reducing sintering temperature and time

Active Publication Date: 2017-07-04
INNER MONGOLIA UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Traditional rare earth permanent magnets consume a large amount of low-abundance, resource-scarce praseodymium, neodymium, samarium, dysprosium, and terbium rare earth elements, while high-abundance lanthanum and cerium elements have not been effectively utilized and have a large backlog, resulting in unbalanced utilization of rare earth resources
Moreover, the original process did not consider the co-occurrence characteristics of rare earth elements, excessively pursued the purity of raw materials, and caused serious ecological environmental pollution and waste of resources in the process of rare earth mining-selection-separation purification-smelting

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0036] A kind of method that prepares rare earth permanent magnet material with powder metallurgy technology, wherein MMMFeB is in (PrNd) x MM 1-x -The weight percentage of Fe-B and Re-Fe-B mixture is given by table 1, (PrNd) x MM 1-x - MM accounts for 70% of the total rare earth in Fe-B, where La / Re, Ce / Re, and MM / Re respectively represent the percentage of La in the total rare earth in the magnet, the percentage of Ce in the total rare earth in the magnet, and the percentage of MM in the magnet. Total percentage of rare earths in the magnet.

[0037] The method comprises the steps of:

[0038] (1) Raw material treatment: carry out surface treatment on the raw material, and remove the surface oxide layer of the prepared raw material by mechanical or chemical methods, wherein the raw material includes mixed rare earth MM associated with Baiyan Obo co-existing ore;

[0039] (2) Ingredients: Mix the raw materials processed in step (1) according to a certain proportion to pre...

example 2

[0049] A method of manufacturing mixed rare earth permanent magnet materials by hot pressing and hot deformation process, wherein MMMeB is in (PrNd) x MM 1-x -The weight percentage of Fe-B and Re-Fe-B mixture is given by table 1, (PrNd) x MM 1-x - MM accounts for 70% of the total rare earth in Fe-B, where La / Re, Ce / Re, and MM / Re respectively represent the percentage of La in the total rare earth in the magnet, the percentage of Ce in the total rare earth in the magnet, and the percentage of MM in the magnet. Total percentage of rare earths in the magnet.

[0050] The method comprises the steps of:

[0051] (1) Ingredients: prepare main alloy raw materials and auxiliary alloy raw materials according to the main alloy and auxiliary alloy respectively, the main alloy (PrNd) x (MM) 1-x -Fe-B is calculated by weight percentage: (Pr, Nd, MM): 29%, Fe: 69.95%, B: 1.05%, wherein, MM is Baiyan Obo co-associated raw ore mixed rare earth; auxiliary alloy ReNdFe is calculated by weig...

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Abstract

The present invention relates to a rare earth permanent magnet made of mixed rare earth from Baiyun Obo co-associated raw ore and a preparation method thereof. The composition of the rare earth permanent magnet is shown in the following formula: (PrNd)x(MM)y(Fe1-aAa)zB , 2≤x+y≤2.5, 11≤z≤14, MM is Baiyan Obo co-associated raw ore mixed rare earth. The rare earth permanent magnet can be realized by powder metallurgy process, rapid quenching-hot pressing and heat deformation process. The present invention proposes to develop a new type of resource-saving rare earth permanent magnet by using the mixed rare earth of Baiyun Obo raw ore to replace the traditional rare earth permanent magnet, which has the advantages of low price and reduced environmental pollution. The scope of application of ferrite and SmCo rare earth permanent magnets is blank.

Description

technical field [0001] The invention belongs to the technical field of rare earth permanent magnet materials, and relates to a rare earth permanent magnet made of mixed rare earths associated with raw ore in Baiyun Obo and a preparation method thereof, in particular to a mixed rare earth-praseodymium neodymium-iron-boron double hard magnetic alloy magnet and its Preparation. Background technique [0002] Rare earth permanent magnet materials are indispensable materials in the fields of national security, information, energy, and environmental protection. China is the largest producer of rare earth permanent magnet materials. According to industry analysis related reports, the market penetration rate of medium and low-grade NdFeB permanent magnets in traditional applications (speakers, magnetic separation, permanent magnet motors, VCM, MRI, etc.) has reached more than 50%, and the demand is in a period of stable growth, with an annual growth rate of 5%. %-10% or so. China i...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01F1/053H01F1/057H01F41/02B22F3/16
Inventor 张雪峰马强李柱柏刘艳丽李永峰慕利娟赵倩赵增茹王高峰
Owner INNER MONGOLIA UNIV OF SCI & TECH
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