Long-acting insecticide compounded with volatiles of Ligonia chinensis and alkaloid of iron bar hammer and preparation method thereof
A technology of volatile matter and iron rod hammer, which is applied in the field of biological long-acting insecticides and their preparation, can solve the problems that the stability of the application effect cannot be guaranteed, affect the development and application of large areas, and unfavorably protect the active ingredients, etc., and achieve the effect of prevention and control Significantly, improve the physical and chemical stability, and improve the effect of insecticidal toxicity
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Embodiment 1-6
[0028] Example 1-6. The distribution ratio of each component of the clathrate volatile matter clathrate is shown in Table 1. Table 2, the preparation method is as follows:
[0029] (1) The preparation method of the volatile matter of Ligularia chinensis: firstly, the fresh whole grass of Ligularia luteus is killed at 112°C for 12 minutes, and then dried naturally in the shade at 28°C; then weigh the dried or fresh product, crush , put the pulverized material and 86% methanol at 1:1 (volume ratio) together in a closed glass container, soak at room temperature for 60h, extract at 42°C, 95Hz ultrasonic wave for 0.9h, filter, and collect the filtrate. A total of 3 extractions were performed in the same way, and all filtrates were combined. Collect fractions from the filtrate under reduced pressure at 62°C and 0.65MPa, mix the obtained fractions, and then recover methanol under reduced pressure at 42°C and 0.65MPa to obtain a dark brown oily liquid with a unique smell of Ligmus ch...
Embodiment 7
[0036] Embodiment 7. Long-acting insecticide compounded with the volatile matter of Ligularia chinensis and the alkaloid of the scorpion, the formula is the same as in Example 5, and the preparation method is as follows:
[0037] (1) The preparation method of the volatile matter of Ligularia chinensis: Firstly, the fresh whole grass of Ligularia sylvestris was killed at 110°C for 10 minutes, then dried naturally in the shade at 25°C, and then the dried or fresh product was weighed and pulverized , put the pulverized material and 85% methanol at 1:1 (volume ratio) together in a closed glass container, soak at room temperature for 48h, 40°C, 90Hz ultrasonic extraction for 0.8h, filter, and collect the filtrate. A total of 3 extractions were performed in the same way, and all filtrates were combined. Collect fractions from the filtrate under reduced pressure at 60°C and 0.6 MPa, mix the obtained fractions, and recover methanol under reduced pressure at 40°C and 0.6 MPa to obtain ...
Embodiment 8
[0042] Example 8. The long-acting insecticide compounded with the volatiles of Ligularia fruticosa and the alkaloids of the iron bar hammer, the formula is the same as in Example 5, and the preparation method is as follows:
[0043] (1) The preparation method of the volatile matter of Ligularia chinensis: firstly, the fresh whole Ligularia sylvestris is killed at a high temperature of 115°C for 15 minutes, and then dried naturally in the shade at a temperature of 30°C; Grass, then weigh the dry or fresh product, crush it, put the crushed product and 88% methanol at a ratio of 1:1 (volume ratio), and place it in a closed glass container, soak it at room temperature for 72 hours, and extract it by ultrasonic wave at 43 °C and 100 Hz for 1.0 h , filtered, and the filtrate was collected. A total of 4 extractions were performed in the same method, and all filtrates were combined. Collect fractions from the filtrate under reduced pressure at 65°C and 0.7MPa, mix the obtained fracti...
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