A positive temperature coefficient thermistor and its preparation method

A positive temperature coefficient and thermistor technology, applied to resistors with positive temperature coefficients, etc., can solve the problems of PTC strength and output power decay too fast, the electrical properties of positive temperature coefficient materials change, and the stability of PTC effect is poor. Achieve good repeatability, eliminate NTC effect and improve electrical conductivity

Inactive Publication Date: 2016-06-15
ZHENGZHOU UNIVERSITY OF LIGHT INDUSTRY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The positive temperature coefficient polymer composite material filled with carbon black has the characteristics of adjustable electrical conductivity in a wide range, easy molding, and low cost; but the existing problems are high room temperature resistivity and poor stability of the PTC effect, resulting in PTC strength. And the output power attenuation is too fast, the leakage current is large after protection, etc.
However, the positive temperature coefficient polymer composite material with metal particles as conductive fillers, because the metal particles are always rigid particles during the phase transition process of PTC temperature rise, does not undergo phase transition, resulting in a more serious negative temperature resistance effect during the continuous temperature rise process ( NTC); the appearance of NTC phenomenon not only irreversibly changes the electrical properties of the positive temperature coefficient material, but also causes the material to fail due to high temperature during the use of the material, or even catch fire

Method used

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  • A positive temperature coefficient thermistor and its preparation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] Add 80 parts by weight of high-density polyethylene and 30 parts by weight of polypropylene into the internal mixer, stir and mix for 8 minutes at a speed of 30 rpm and a temperature of 175°C; then add 2.5 parts of crosslinking agent triallyl isocyanurate Ester, 1.5 parts by weight of antioxidant and 2.5 parts by weight of lubricant, continue to mix for 3 minutes to obtain a mixture; respectively use 4,0.5,0.5 parts by weight of coupling agent to 16 parts by weight of titanium diboride, 4 parts by weight of carbon fiber and 4 parts by weight of multi-walled carbon nanotubes are subjected to surface treatment, then the treated conductive filler is added to the above mixture, the rotating speed is increased to 80rpm, and then the mixture is continued for 3 minutes to obtain the mixture; the above mixture is extruded with a twin-screw After machine extrusion and granulation, the positive temperature coefficient polymer composite material pellets are obtained; then the above...

Embodiment 2

[0045] Add 70 parts by weight of high-density polyethylene and 35 parts by weight of polypropylene into the internal mixer, stir and mix for 6 minutes at a speed of 35 rpm and a temperature of 180°C; then add 2 crosslinking agents trimethylolpropane triacrylic acid Ester, 1.5 parts by weight of antioxidant and 3 parts by weight of lubricant, continue to mix for 5 minutes to obtain a mixture; respectively use 5,0.5,0.5 parts by weight of coupling agent for 25 parts by weight of titanium diboride, 2.5 parts by weight of carbon fiber and 2.5 parts by weight Surface treatment of multi-walled carbon nanotubes in parts by weight, then adding the treated conductive filler to the above mixture, increasing the rotating speed to 70rpm, and then continuing to mix for 3 minutes to obtain the mixture; After extrusion and granulation, the positive temperature coefficient polymer composite material pellets are obtained; and then the above pellets are molded to obtain a positive temperature co...

Embodiment 3

[0048] Add 75 parts by weight of high-density polyethylene and 25 parts by weight of polypropylene into the internal mixer, stir and mix for 10 minutes at a speed of 40 rpm and a temperature of 170 °C; then add 3 crosslinking agents trimethylolpropane triacrylic acid Esters, 2 parts by weight of antioxidant and 2 parts by weight of lubricant, continue to mix for 5 minutes to obtain a mixture; respectively use 3.5, 0.6, 0.4 parts by weight of coupling agent for 15 parts by weight of titanium diboride, 3 parts by weight of carbon fiber and 2 parts by weight of Surface treatment of multi-walled carbon nanotubes in parts by weight, then adding the treated conductive filler to the above mixture, increasing the rotating speed to 70rpm, and then continuing to mix for 3 minutes to obtain the mixture; After extrusion and granulation, the positive temperature coefficient polymer composite material pellets are obtained; and then the above pellets are molded to obtain a positive temperatur...

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Abstract

The invention provides a positive temperature coefficient thermistor made from a polymer composite material containing a specific positive temperature coefficient and a preparation method of the positive temperature coefficient thermistor. The thermistor comprises a first electric conductor, the polymer composite material with the positive temperature coefficient and a second electric conductor, wherein the polymer composite material and the second electric conductor are sequentially attached to the first electric conductor. The positive temperature coefficient thermistor is characterized in that the polymer composite material with the positive temperature coefficient is prepared from the following components in parts by weight: 70-85 parts of high-density polyethylene, 25-40 parts of polypropylene, 20-35 parts of conductive filler, 4-6 parts of a coupling agent, 2-3 parts of a crosslinking agent, 1-2 parts of an anti-oxidant and 2-3 parts of a lubricating agent. The preparation method of the positive temperature coefficient thermistor comprises the following steps: putting the polymer composite material with the positive temperature coefficient between the two electric conductors, and molding into a three-layer composite core; then irradiating the composite core by an irradiation X ray, carrying out thermal treatment, and welding conducting electrodes to the two electric conductors. The positive temperature coefficient thermistor is a brand new thermistor and contains the polymer composite material with the specific positive temperature coefficient, so that the positive temperature coefficient thermistor has the characteristics of low room temperature inner resistance, high PTC intensity, good stability and the like.

Description

technical field [0001] The invention relates to a positive temperature coefficient thermistor and a preparation method thereof, in particular to a positive temperature coefficient thermistor comprising a positive temperature coefficient polymer composite material and a preparation method thereof. Background technique [0002] At present, positive temperature coefficient thermistors include positive temperature coefficient thermistors for degaussing, positive temperature coefficient thermistors for motor starting, positive temperature coefficient thermistors for overcurrent protection, positive temperature coefficient thermistors for heating, Chip positive temperature coefficient thermistor. [0003] PTC thermistors containing PTC polymer composites are a major class of PTC thermistors, and their performance is mainly affected by the PTC properties of the PTC polymer composites they contain. For thermistor composite materials, it is generally desired to have as low as possib...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01C7/02C08L23/06C08L23/12C08K13/04C08K3/38C08K7/06C08K3/04C08K7/24
Inventor 方洁曹卫锋段现星陈鹏闫红岩张培邓玮
Owner ZHENGZHOU UNIVERSITY OF LIGHT INDUSTRY
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