Catalyst for producing ethylidene diacetate

A technology of ethylene diacetate and catalyst, applied in physical/chemical process catalyst, metal/metal oxide/metal hydroxide catalyst, organic chemistry and other directions, can solve the problem of low selectivity and yield of ethylene diacetate Low, high selectivity of ethylene diacetate, to achieve the effect of improving yield and selectivity, improving activity and stability

Active Publication Date: 2016-04-13
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] One of the technical problems to be solved by this invention is the problem of low yield and low selectivity of diethylene acetate, and a catalyst used for

Method used

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  • Catalyst for producing ethylidene diacetate
  • Catalyst for producing ethylidene diacetate
  • Catalyst for producing ethylidene diacetate

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] Preparation of catalyst: RhCl containing 6.30gRh, 2.90gB and 3.00gZn 3 ·3H 2 O, ammonium pentaborate ((NH 4 )B 5 o 8 ·8H 2 O) and zinc gluconate (C 12 h 22 o 14 Zn 3 ·3H 2 O) fully mixed and dissolved in pure water to obtain 400ml of impregnation solution, and the specific surface of 1.0L was 165m 2 / g, spherical SiO with a pore volume of 0.95 and a diameter of 5.6mm 2 The carrier was immersed in the above impregnating solution, left to stand for 2 hours and dried at 100° C. to obtain the catalyst. The Rh content of the catalyst was analyzed by ICP-MS to be 6.30 g / L, the B content was 2.90 g / L, and the Zn content was 3.00 g / L.

[0030] Synthesis of diethylene acetate: Add 1.0mol acetic acid, 0.05mol catalyst, 0.10mol methyl iodide and 0.45mol methyl acetate into a 500ml titanium reactor, first use argon to discharge the air in the kettle and then pressurize to 2.0MPa, Then feed carbon monoxide and hydrogen until the pressure is 7.8MPa, increase the stirring ...

Embodiment 2

[0034]Preparation of catalyst: RhCl containing 6.30gRh, 2.90gB and 3.00gCe 3 ·3H 2 O, ammonium pentaborate ((NH 4 )B 5 o 8 ·8H 2 O) and Ce(OAc) 3 ·5H 2 O is fully mixed and dissolved in pure water to obtain 400ml of impregnation solution, and the specific surface of 1.0L is 165m 2 / g, spherical SiO with a pore volume of 0.95 and a diameter of 5.6mm 2 The carrier was immersed in the above impregnating solution, left to stand for 2 hours and dried at 100° C. to obtain the catalyst. The Rh content of the catalyst was analyzed by ICP-MS to be 6.30 g / L, the B content was 2.90 g / L, and the Ce content was 3.00 g / L.

[0035] Synthesis of diethylene acetate: Add 1.0mol acetic acid, 0.05mol catalyst, 0.10mol methyl iodide and 0.45mol methyl acetate into a 500ml titanium reactor, first use argon to discharge the air in the kettle and then pressurize to 2.0MPa, Then feed carbon monoxide and hydrogen until the pressure is 7.8MPa, increase the stirring speed to 1200rpm, while stirr...

Embodiment 3

[0046] The preparation of catalyst: will contain 5.00gRh, contain 1.00gB and contain 1.00gZn triphenylphosphine rhodium chloride (C 54 h 45 ClP 3 Rh), boric acid (H 3 BO 3 ) and zinc citrate Zn 3 (C 6 h 5 o 7 ) 2 2H 2 O is fully mixed and dissolved in acetic acid with a concentration of 10wt%, to obtain 400ml of impregnation solution, and the specific surface of 1.0L is 150m 2 / g, spherical Al with a pore volume of 0.90 and a diameter of 5.6mm 2 o 3 The carrier was immersed in the above impregnating solution, left to stand for 2 hours and dried at 80° C. to obtain the catalyst. The Rh content of the catalyst analyzed by ICP-MS was 5.00 g / L, the B content was 1.00 g / L, and the Zn content was 1.00 g / L.

[0047] Synthesis of diethylene acetate: Add 1.0mol acetic acid, 0.05mol catalyst, 0.10mol methyl iodide and 0.45mol methyl acetate into a 500ml titanium reactor, first use argon to discharge the air in the kettle and then pressurize to 2.0MPa, Then feed carbon monox...

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Abstract

The invention relates to a catalyst for producing ethylidene diacetate. The catalyst is mainly used for solving the problem in the prior art that catalysts for ethylidene diacetate are relatively low in activity and selectivity. Through adopting the technical scheme that the catalyst for ethylidene diacetate adopts SiO2, Al2O3 or a mixture of SiO2 and Al2O3 as a carrier, and active ingredients comprise at least one element selected from platinum family metals, at least one element selected from metalloid elements and at least one metal element selected from IIB and lanthanide series metal elements, the technical problem is better solved, and the catalyst can be applied to the industrial production of vinyl acetate.

Description

technical field [0001] The invention relates to a catalyst used in the production of ethylene diacetate, a preparation method of the catalyst used in the production of ethylene diacetate and a synthesis method of ethylene diacetate. Background technique [0002] Vinyl acetate (vinylacetate, VAC or VAM for short), is a colorless, transparent, flammable liquid at room temperature with a sweet ether fragrance. It is one of the most productive organic chemical raw materials in the world, widely used in the production of polyvinyl acetate (PVAc), polyvinyl alcohol, coatings, pastes, adhesives, vinylon, films, vinyl copolymer resins, acetal resins A series of chemical and chemical fiber products are widely used in various industries. [0003] The production of vinyl acetate adopts ethylene gas-phase method and acetylene gas-phase method both at home and abroad, which belong to the petrochemical process route. Since the rise of C1 chemistry, in the 1980s, the American Halcon (Halc...

Claims

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Application Information

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IPC IPC(8): B01J23/60B01J23/63B01J23/644B01J27/057C07C67/36C07C69/16
Inventor 查晓钟杨运信张丽斌
Owner CHINA PETROLEUM & CHEM CORP
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