Ultraviolet scattering agent and application therefor

A technology of ultraviolet rays and scattering agents, applied in the field of ultraviolet scattering agents, which can solve problems such as damaged gloss, increased concealment, and high specificity, and achieves excellent fluidity and excellent safety effects

Active Publication Date: 2016-06-29
NISSHINBO IND INC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Generally, if the amount of UV absorber is increased, the effect will be improved, but since the UV shielding mechanism is mainly absorption, there is a disadvantage that only UV in a certain wavelength range can be shielded, and there may be problems in durability
In addition, if UV absorbers are used in cosmetics, etc., for people with weak skin, there may be effects on the human body such as rough skin and rashes.
[0005] On the other hand, UV scattering agents made of inorganic particles such as zinc oxide and titanium oxide generally have a high UV scattering effect, but it is difficult to disperse and maintain them in the state of primary particles, and they often exist as aggregates, resulting in concealment. Disadvantages of over-elevation
In addition, there is a disadvantage that glossiness is impaired even if only a small amount is added
[0006] Compared with organic materials, inorganic materials have a large specificity, and when used in films, molded products, etc., they are difficult to be compatible with resins, so there may be disadvantages in terms of light weight, crackability, etc.
In addition, in cosmetics, in order to maintain dispersion, it is sometimes necessary to use a large amount of surfactant, and the use of a large amount of surfactant is not preferable from the viewpoint of preventing rough skin and skin aging.

Method used

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  • Ultraviolet scattering agent and application therefor
  • Ultraviolet scattering agent and application therefor
  • Ultraviolet scattering agent and application therefor

Examples

Experimental program
Comparison scheme
Effect test

Embodiment

[0181] Hereinafter, synthesis examples, examples, and comparative examples are given to describe the present invention more specifically, but the present invention is not limited to the following examples. In addition, the evaluation items in each of the following Examples and Comparative Examples were measured by the following methods.

[0182] (1) Aspect ratio of polymer particles

[0183] Using a scanning electron microscope (S-4800 manufactured by Hitachi High Technologies Co., Ltd.), photographs were taken at a measurable magnification (300 to 30,000 times), and the obtained elliptical or needle-shaped polymer particles were two-dimensionalized (should be It should be noted that, generally, the elliptical or needle-shaped polymer particles are kept in a state where the long axis direction is horizontal.), the major axis (L) and minor axis (D) of each particle are measured, and the aspect ratio (L / D) is calculated. , to calculate the average aspect ratio (P AV ).

[018...

Synthetic example 1

[0189] After dissolving the compounds shown below in each phase in a 2,000 mL flask, the water phase and the oil phase were mixed and charged, and heated and stirred (400 rpm) at an oil bath temperature of 80°C under a nitrogen stream for about 8 hours , A particle solution of polymethyl methacrylate was obtained.

[0190]

[0191] (Polystyrene: manufactured by Sigma Aldrich Co., weight average molecular weight about 45,000)

[0192] Next, the particle solution was washed with methanol-filtered five times using a known suction filter, and vacuum-dried to obtain polymer particles A1.

Synthetic example 2

[0194] Polymer particles A2 of polymethyl methacrylate were obtained in the same manner as in Synthesis Example 1 except that the polystyrene in the oil phase was changed to 12.0 g.

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PUM

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Abstract

Provided is an ultraviolet scattering agent characterized by comprising at least one type of elliptical or needle-like polymer particles (A), wherein (1) the average (LAV) of the major axis (L) in a two-dimensional projection diagram obtained by radiating light from a direction perpendicular to the major-axis direction is 0.1 to 80 microns, (2) the average (DAV) of the minor axis (D) in a two-dimensional projection diagram obtained by radiating light from a direction perpendicular to the major-axis direction is 0.05 to 40 microns, and (3) the average (PAV) of the aspect ratio (L / D) calculated from the major axis (L) and the minor axis (D) is 2 to 30.

Description

technical field [0001] The present invention relates to ultraviolet (UV) scattering agents and their use. Background technique [0002] Polymer particles and inorganic particles having a micron size are used as fillers and objects to be inspected in various fields such as electronic and electrical materials, optical materials, paints, inks, building materials, biological and medical materials, and cosmetics. In recent years, particularly, the development of irregularly shaped microparticles other than spherical ones has been actively carried out, and application development has been increasingly carried out in order to impart various properties such as optical characteristics and texture. The present inventors have also developed elliptical or needle-shaped polymer particles with a high aspect ratio, and have developed particles that are more excellent than conventional spherical particles in various characteristics such as concealment, light scattering, and hand feeling (pa...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K3/00A61K8/81A61Q1/00A61Q17/04C08L101/00C09D5/33D21H17/67
CPCA61Q17/04D21H17/67C08L101/00A61Q1/02A61Q1/10A61Q5/065A61K8/8117A61K8/8152A61K8/027A61K2800/412C09D5/004A61K8/0245A61Q19/00C09D11/03C09D125/06C09D125/14C09D133/12
Inventor 早川和寿松坂惠里奈山田刚毅桥场俊文
Owner NISSHINBO IND INC
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