Fluidization calcium-based thermal-chemical high temperature energy storing/releasing system and working method thereof

A fluidization and thermochemical technology, applied in heat storage equipment, energy storage, indirect heat exchangers, etc., can solve problems such as burns to eyes, skin and mucous membranes of respiratory organs, high cost of energy storage systems, and expensive metal nickel. Achieve the effects of low price, large heat transfer area and fast reaction rate

Inactive Publication Date: 2016-07-06
SOUTH CHINA UNIV OF TECH
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Problems solved by technology

However, its energy storage temperature is only 150°C to 300°C, and the price of metal nickel in its energy storage material is relatively expensive, which may lead to a higher cost of its energy storage system; the application number is 201510116256.3 "New Amino Thermochemical Energy Storage System" Chinese invention patent, which proposes to use the thermochemical reversible reaction of amino groups for energy storage
Ammonia

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  • Fluidization calcium-based thermal-chemical high temperature energy storing/releasing system and working method thereof

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Embodiment Construction

[0027] In order to make the purpose and technical solution of the present invention clearer, the present invention will be further described in detail with reference to the accompanying drawings.

[0028] The system uses calcium-based thermochemical high-temperature reversible reaction CaO(s)+H 2 O(g)?Ca(OH) 2 (s)?H=-109kJ / mol, storage and release of energy through mutual conversion between solar energy, thermal energy and chemical energy. The system mainly includes an energy input unit, an energy storage unit, and an energy output unit, which are mainly divided into an energy storage process and an energy release process. During energy storage, calcium hydroxide undergoes an endothermic decomposition reaction under fluidized conditions, and the absorbed heat It is stored in the reaction product calcium oxide in the form of chemical energy; when the energy is released, calcium oxide and water vapor undergo an exothermic reaction under fluidized conditions, and the released he...

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Abstract

The invention discloses a fluidization calcium-based thermal-chemical high temperature energy storing/releasing system and a working method thereof. The system is characterized in that the storing and releasing of energy are performed by means of a calcium-based thermal-chemical high-temperature reversible reaction through mutual transformation among solar energy, thermal energy and chemical energy. The system mainly comprises an energy input unit, an energy storing unit and an energy output unit. During storing of energy, calcium hydroxide is subjected to an endothermic decomposition reaction under a fluidization condition, and absorbed energy is stored in calcium oxide as a reaction product in a chemical energy form; during releasing of the energy, the calcium oxide and water vapor are subjected to an exothermic reaction under the fluidization condition, and released heat heats water to generate high-temperature high-pressure steam, so that a steam turbine is driven to generate power. The fluidization calcium-based thermal-chemical high temperature energy storing/releasing system has the characteristics of high unit mass energy-storing density, high energy quality, low energy-storing lost, no pollution and the like, can be modularly combined according to energy-storing capacity, and can be applied to fields such as large-scale solar thermal generation and peak-load regulation.

Description

technical field [0001] The invention relates to the technical field of energy storage, in particular to a thermochemical high-temperature energy storage system that uses calcium-based reversible reactions to store energy from solar energy or power grid valley electricity. Background technique [0002] With the rapid development of the economy, the supply of energy is becoming more and more difficult to meet the demand. In today's world, traditional fossil energy (coal, oil, natural gas, etc.) still dominates. Moreover, the combustion of fossil energy will produce a large amount of greenhouse gases and other toxic and harmful gases and dust, which has brought a series of environmental pollution problems. Therefore, the development and utilization of renewable clean energy has received widespread attention. Solar energy is a widely distributed, clean and environmentally friendly energy. Efficient use of solar energy can alleviate today's energy problems and environmental pol...

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Application Information

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IPC IPC(8): F28D20/00
CPCF28D20/003Y02E60/14Y02E70/30
Inventor 龙新峰赖永鑫张丽桦廖珊珊唐永铨
Owner SOUTH CHINA UNIV OF TECH
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