A method for leaching gold and silver from manganese-coated gold and silver ore under normal temperature and pressure

A gold-silver, atmospheric pressure technology is applied in the field of beneficiation of manganese-coated gold-silver ore.

Active Publication Date: 2017-02-08
INST OF RESOURCES UTILIZATION & RARE EARTH DEV GUANGDONG ACAD OF SCI +1
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  • Abstract
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  • Application Information

AI Technical Summary

Problems solved by technology

This theoretically shows that the two-mine method must be heated under a higher sulfuric acid concentration to realize the leaching of manganese, so that the wrapped gold and silver are exposed; Jiang Tao et al. ,1995,06:26-29+50-51) proposed to use RH for one-step treatment of silver-manganese ore, which has the advantages of short process, high speed, and low investment; in the leaching process, part of RH acts as a reducing agent, and part of it acts as a reducing agent. With a catalyst, the entire leaching reaction is carried out step by step. The reduction of manganese dioxide can be completed quickly, while the oxidation reaction of silver takes a certain amount of time. Since the intermediate product is easy to volatilize, it is necessary to control the speed of the previous reaction to ensure the synchronization of the two reactions. To ensure the leaching rate of silver, the process condition test shows that RH and H 2 SO 4 When the dosage is 13.2% and 36%, the time is 2 hours, and the liquid-solid ratio is 4:1, the leaching rates of manganese and silver can reach 96% and 79%, respectively. This scheme realizes the simultaneous leaching of manganese and silver without sulfuric acid The dosage is too high, the cost is high, and there are difficulties in production and implementation
[0005] Generally speaking, scientific and technological workers have carried out a lot of research work on manganese-silver ore, and technically realized the pretreatment of manganese-silver ore, and the leaching indicators of manganese and silver are also high. However, due to factors such as complex process and large consumption of chemicals, Existing research results cannot be practically applied to manganese-silver ore for a long time

Method used

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  • A method for leaching gold and silver from manganese-coated gold and silver ore under normal temperature and pressure

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] The original ore is a manganese-silver mine in Yunnan, China.

[0028] S1. Grinding the raw ore to -0.074mm accounts for 80%, adding water to adjust the pulp concentration to 35%;

[0029] S2. Pretreatment: Add 30Kg / t of sulfuric acid to the grinding product according to the amount of ore (for safety, first dilute the concentrated sulfuric acid to dilute sulfuric acid with a mass concentration of 5%), add 8Kg / t according to the amount of ore Reduced iron powder, stirred at normal temperature and pressure for 3 hours to obtain the pretreated raw ore;

[0030] S3. Filtration: filter the pretreated raw ore to obtain manganese-containing filtrate and manganese leaching slag;

[0031] S4. Cyanide leaching of gold and silver from manganese leaching slag: add water to the manganese leaching slag to adjust the pulp concentration to 36%, add sodium hydroxide 500g / t, and lime 6Kg / t to adjust the slurry to a pH value of 10, based on ore weight , add sodium cyanide 1000g / t. Stir...

Embodiment 2

[0034] The original ore is a manganese silver mine in Guangxi, China.

[0035] S1. Raw ore is ground to -0.074mm, accounting for 65%, adding water to adjust the pulp concentration to 30%;

[0036] S2. Pretreatment: add 15Kg / t of sulfuric acid to the grinding product according to the amount of ore (for safety, first dilute the concentrated sulfuric acid to dilute sulfuric acid with a mass concentration of 10%), add 12Kg / t according to the amount of ore Reduced iron powder, stirred at normal temperature and pressure for 4.5 hours to obtain pretreated raw ore;

[0037] S3. Filtration: filter the pretreated raw ore to obtain manganese-containing filtrate and manganese leaching slag;

[0038] S4. Cyanide leaching of gold and silver from manganese leaching slag: add water to the manganese leaching slag to adjust the pulp concentration to 31%, add lime 8Kg / t to adjust the slurry to a pH value of 11, and add sodium cyanide 1300g / t based on the ore weight t. Stir and leach at normal...

Embodiment 3

[0041] The original ore is a manganese-silver mine in Yunnan, China.

[0042] S1. Grinding the raw ore to -0.074mm accounts for 80%, adding water to adjust the pulp concentration to 30%;

[0043] S2. Pretreatment: add 20Kg / t of sulfuric acid to the grinding product according to the amount of ore (for safety, first dilute the concentrated sulfuric acid to dilute sulfuric acid with a mass concentration of 10%), add 8Kg / t according to the amount of ore Reduced iron powder, stirred at normal temperature and pressure for 3 hours to obtain the pretreated raw ore;

[0044] S3. Filtration: filter the pretreated raw ore to obtain manganese-containing filtrate and manganese leaching slag;

[0045] S4. Cyanide leaching of gold and silver from manganese leaching slag: add water to the manganese leaching slag to adjust the pulp concentration to 36%, add sodium hydroxide 500g / t, and lime 6Kg / t to adjust the slurry to a pH value of 10, based on ore weight , add sodium cyanide 1000g / t. Sti...

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Abstract

The invention discloses a method for leaching gold and silver out of kustelite wrapped by manganese under normal pressure and temperature. The method includes the steps that raw ore grinding is performed; pretreatment is performed through sulfuric acid and reduced iron powder; filtering is carried out; and manganese-leaching slag obtained through filtering is subjected to cyanide leaching to obtain the gold and silver. Compared with existing methods for leaching the gold and silver out of the kustelite wrapped by the manganese, the method achieves pretreatment of the kustelite wrapped by the manganese under low acid concentration and normal pressure and temperature, the gold and silver leaching rate is substantially increased, and the method is applicable to the kustelite wrapped by the manganese.

Description

technical field [0001] The invention relates to a beneficiation method for manganese-encapsulated gold and silver ore, more specifically, to a pretreatment and leaching method for manganese-encapsulated gold and silver ore. Background technique [0002] Manganese-silver ore contains high manganese minerals and other oxides, and gold and silver are often dispersed in these minerals in very fine particles, making manganese-silver ore one of the most difficult silver-containing minerals to handle. When cyanide is used for direct leaching, since most of the gold and silver are wrapped, cyanide cannot effectively contact it, so the leaching rate of gold is generally less than 50%, and the leaching rate of silver is even less than 30%. [0003] There are many researches on the chemical leaching of manganese minerals at home and abroad. There are three possible schemes for leaching manganese-silver ores: first leaching manganese and then leaching silver, direct leaching silver (or ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22B11/08C22B7/04C22B3/08
CPCC22B3/08C22B7/006C22B7/04C22B11/04C22B11/042C22B11/08Y02P10/20
Inventor 邱显扬汤玉和邹坚坚胡真汪泰李汉文宋宝旭王成行武鲁庆胡佛明
Owner INST OF RESOURCES UTILIZATION & RARE EARTH DEV GUANGDONG ACAD OF SCI
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