50results about How to "Achieve leaching" patented technology

The invention belongs to the field of metallurgical chemical industry, and particularly relates to a method for leaching nickel and molybdenum from an amorphous nickel-molybdenum sulfide mineral by oxidative conversion. According to the technical scheme, the method comprises the following steps: mixing the amorphous nickel-molybdenum sulfide mineral which is finely ground with water to prepare pulp; adding the pulp into a pressure kettle, introducing industrial oxygen, and performing temperature rising reaction under the pressure of 0.8-2.0 MPa and at the temperature of 110-200 DEG C; converting the nickel and the molybdenum into sulfates, dissolving the sulfates into a solution, and filtering the pulp to obtain a leachate containing nickel sulfate and molybdenum sulfate acyl. The characteristics of large specific surface area and high activity of the amorphous nickel-molybdenum sulfide mineral are fully utilized; under the condition that acid is not added, colloidal sulfide is directly converted into sulfuric acid and sulfate in an oxidative manner, so that the nickel and the molybdenum can be leached, the process flow is short, conventional roasting is not needed, harmful smoke pollution is avoided, the process is clean, the consumption of reagents is low, and the leaching rate of metal is high.

The invention discloses an acidophilic iron-oxidizing composite microbial agent which comprises the following communities: a ferroplasma acidiphilum-containing strain, an acidithiobacillus ferrivorans-containing strain, an acidithiobacillus ferrooxidans-containing strain, a leptospirillum ferriphilum-containing strain and a sulfobacillus acidophilus-containing strain, wherein a preparation method of the composite microbial agent comprises the following steps: the aforementioned five strains are placed in a specific basic iron salt/nutrient-containing culture medium, and are subjected to the temperature gradient compounding culture, tolerance mixed-heavy-metal gradient pressure type domestication, temperature cycling gradient type domestication, ferrous oxidation activity improvement and tolerance high-iron domestication, so as to obtain the acidophilic iron-oxidizing composite microbial agent. According to the invention, the acidophilic iron-oxidizing composite microbial agent is simple in formulation, economical, adaptable, versatile and efficient, and can be used for the efficient extraction of heavy metals in electroplating sludge.

The invention discloses a nickel oxide ore acid leaching solution two-step iron removal method. The method comprises the following steps: adding garnierite ore pulp into a nickel oxide ore acid leaching solution, stirring and reacting until the dissolution is completed and the pH value of the solution is more than or equal to 1.6, performing liquid-solid separation, raising the temperature of obtained liquid to 130-170 DEG C, stirring and reacting for 1-3 hours, performing liquid-solid separation, and drying a solid to obtain a hematite product; adding the garnierite ore pulp into the collected liquid for the second time, stirring and reacting until the dissolution is completed and the pH value of the solution is about 2, performing liquid-solid separation, and adding magnesium oxide and an oxidizing agent into the obtained liquid, or only adding the oxidizing agent; stirring and reacting for 0.5-4 hours, performing liquid-solid separation, and drying the solid to obtain a goethite product. By adopting the method disclosed by the invention, complete iron removal can be achieved under a relatively mild condition; hematite and goethite which can be directly sold can be obtained; meanwhile, residual acid in the acid leaching solution and acid released in the iron deposition process are recycled; loss of nickel, cobalt, aluminum and magnesium in the leaching solution can not be generated.

The invention belongs to the field of metallurgy of steel and iron and processing of mineral resources and specifically relates to a method for extracting high-quality iron powder and borax from paigeite. The method provided by the invention comprises the following steps: (1) mixing boron-containing iron concentrate, solid Na2CO3 and coal together to obtain a mixture; (2) roasting the mixture under a reducing atmosphere at the temperature of 950-1150 DEG C to obtain a roasted product; (3) crushing and grinding the roasted product and then, leaching, washing and filtering ore slurry to obtain an alkaline filtrate and an iron-containing filter cake; (4) performing desilication, CO2 carbonization, filtration and crystallization on the alkaline filtrate to obtain qualified borax and simultaneously realize recycling of reaction medium Na2CO3; (5) performing magnetic separation, grinding and secondary magnetic separation on the obtained filter cake to obtain high-quality reducing iron powder (TFe is more than 98.5%) which can be used as an iron-based raw material for powder metallurgy. According to the method provided by the invention, by adding a large amount of Na2CO3, the leaching of boron minerals is simultaneously realized during iron reduction, the process flow is shortened and the energy consumption is reduced.

The invention discloses a method for separating and purifying tellurium from cuprous telluride slag through vacuum distillation. The method comprises the following steps of S1, placing the cuprous telluride slag in a vacuum distillation furnace, and performing vacuum distillation at the vacuum degree of 10-150 Pa to obtain selenium slag and copper-tellurium slag, wherein the vacuum distillation temperature is 390 DEG C-470 DEG C, and the time is 1-4 h; and S2, placing the copper-tellurium slag obtained in the S1 in the vacuum distillation furnace, and performing vacuum distillation at the vacuum degree of 10-150 Pa again to obtain refined tellurium products and copper-silver slag, where the secondary vacuum distillation temperature is 890 DEG C-950 DEG C, and the time is 1-4 h. According to the method, the problems of low direct recovery, long process flow and the like in the current cuprous telluride slag treatment process can be solved, and the short-process and high-value recovery of valuable elements in the cuprous telluride slag is achieved.

This invention discloses a novel method for extracting nickel from nickel sulfide concentrate. The method overcomes the problems of long extraction time, low nickel recovery rate and serious pollution faced by the traditional methods. The method comprises: (1) placing nickel sulfide concentrate and pyrolusite at a certain weight ratio into a reactor; (2) adding certain volume and concentration of H2SO4 solution at a certain temperature, and reacting. Nickel sulfide concentrate is leached to form nickel sulfate, and manganese dioxide is leached to form manganese sulfate. The method has such advantages as short reaction time and high nickel recovery rate. The method can choose nickel sulfide concentrate and pyrolusite at different weight ratios, and adopt different parameters and temperatures to realize multiple reactions.

The invention discloses a method of preparing high-purity nickel sulfate from electrolytic manganese sulfide slag. The method comprises the following steps of (1) crushing and sieving; (2) oxidizing and leaching; (3) calcium removal; (4) manganese removal; (5) synchronous extraction of cobalt and nickel: taking a solution rich in cobalt, nickel and magnesium, and adding a third organic extractant formed by mixing saponified neodecanoic acid with sulfonated kerosene for extraction to obtain an organic phase rich in the cobalt and the nickel and a magnesium-contained aqueous phase; (6) cobalt removal: taking the organic phase rich in the cobalt and the nickel, adding dilute sulfuric acid for reverse extraction to obtain a cobalt-nickel sulfuric acid solution and a neodecanoic acid organic phase, separating out the cobalt-nickel sulfuric acid solution, and adding a fourth organic extractant formed by mixing saponified P507-Cyanex301 with sulfonated kerosene for extraction to obtain a cobalt-rich organic phase and a nickel sulfate solution; and (7) preparation of the high-purity nickel sulfate. The method has the advantages that the method is simple and feasible, leaching of nickel sulfate can be realized, and production of hydrogen sulfide gas, use of an iron precipitation process and a method of removing calcium and magnesium ions with precipitation of fluorine ions can be avoided.

The invention relates to the field of beneficiation and metallurgy with a function of comprehensively recovering valuable components such as vanadium, aluminum, potassium and silicon from the vanadium-containing siliceous shale as a raw material. The process comprises steps as follows: the low-grade vanadium-containing siliceous shale is taken as the raw material, firstly, the vanadium-containingsiliceous shale is desiliconized with a flotation method, vanadium ore concentrate is uniformly mixed with excessive limestone and sodium carbonate, a mixture is subjected to high-temperature roastingin a rotary kiln, and products such as potassium aluminate, potassium ferrite, calcium metavanadate, calcium orthosilicate, carbon dioxide and the like are obtained; the sintered products are dissolved in a dilute alkaline solution, after a dissolution solution is desiliconized and purified, carbon dioxide gas produced by the rotary kiln is introduced into a closed container for carbonization reaction, Al(OH)3 precipitates are separated out, a dealumination solution is subjected to hydrolytic precipitation under the acidic condition, coarse vanadium is obtained and dissolved with alkali, ammonium chloride is added, ammonium metavanadate is obtained, a final solution is a potassium-rich and sodium-rich solution and evaporated step by step, and potash and soda are obtained. According to theinvention, the problem of environmental pollution produced by stockpiling of stone coal leaching residues is solved completely.

The invention discloses a method for selectively leaching zinc in zinc ferrite-containing waste residues through mechanical activation and directional reduction. According to the method, zinc ferrite lattices in the waste residues are subjected to distortion and defects through mechanical activation, the zinc ferrite is directionally reduced into ZnO which is easy to dissolve in acid and Fe3O4 which is not easy to dissolve in acid, the zinc enters a solution, and the iron is left in the residues. By means of the method, zinc leaching is selectively achieved, hazardous waste is reduced, the zinc smelting time is shortened, the zinc smelting cost is reduced, Zn < 2 + > is leached to the maximum extent under the low acid concentration, iron is left in the residues in the form of ferroferric oxide, and therefore the problem of jarosite slag in the zinc hydrometallurgy process is solved from the source.

The invention discloses a method for leaching gold and silver out of kustelite wrapped by manganese under normal pressure and temperature. The method includes the steps that raw ore grinding is performed; pretreatment is performed through sulfuric acid and reduced iron powder; filtering is carried out; and manganese-leaching slag obtained through filtering is subjected to cyanide leaching to obtain the gold and silver. Compared with existing methods for leaching the gold and silver out of the kustelite wrapped by the manganese, the method achieves pretreatment of the kustelite wrapped by the manganese under low acid concentration and normal pressure and temperature, the gold and silver leaching rate is substantially increased, and the method is applicable to the kustelite wrapped by the manganese.

The invention relates to a leaching-purifying method for rare earth concentrate, and belongs to the field of non-ferrous metallurgy. According to the method, a leaching process is adjusted, and a two-stage reverse feeding countercurrent process is adopted, namely, in first-stage leaching, rare earth concentrate slurry is used as a base solution, and a leaching agent is added into the base solution, so that low-impurity rare earth leaching liquid is obtained; in second-stage leaching, first-stage leaching residues serve as raw materials, after a certain number of seed crystals are added, a leaching agent hydrochloric acid is added into the first-stage leaching residues, so that the leaching residues low in rare earth content and an acid leaching solution high in impurity content are obtained, and the acid leaching solution is returned to the first-stage leaching for use; and by means of the leaching process, separation of impurities can be achieved, and rare earth resources can be fully utilized. The method has the advantages of being simple in process, low in cost, high in impurity removal rate, high in rare earth recovery rate and the like, and has good industrial application prospects.

A high-efficiency coupling, polygeneration and low-nitrogen coal gangue activation process includes the following process steps: A. a coal gangue raw material is subjected to wide preheating to obtainfirst coal gangue having a water content of less than 0.8%; B. the first coal gangue is subjected to field effect low nitrogen roasting to obtain a first activated powder product and a high temperature flue gas; C. the high temperature flue gas is subjected to residual heat coupling adjustment to obtain a second activated powder product, a low temperature flue gas recycled to the step A to participate in the wide preheating and low temperature air recycled to the step B to participate in the field effect low nitrogen roasting. The process adopts the combination of mechanical, high temperatureand chemical three activation modes, the activation effect almost reaches the limit, the activation is no longer a single roasting process, the thermal energy in the flue gas is fully utilized, and the coupling adjustment form is designed, the material itself is preheated for drying, combustion air is preheated, and external heat is supplied.

The invention relates to a leaching method of zinc sulfide concentrates, and belongs to the field of wet metallurgy. Water, an oxidizing agent, the zinc sulfide concentrates, additives and a dispersing agent are added in a high-temperature and high-pressure reaction kettle to obtain a reaction system; under the condition of tightness, the reaction system in the high-temperature and high-pressure reaction kettle is heated and pressurized to reach a supercritical state, is reacted by 10-60 min to obtain a reaction product system, and is cooled to reach the room temperature; the solid/liquid-phase separation is performed to obtain zinc-contained leaching liquid and iron-contained oxide leaching slag; the additives are sulfur-contained additives or nitrogen-contained additives; the temperaturein the supercritical state is 380-500 DEG C; and the pressure is 22.5-40 Mpa. The zinc sulfide concentrates are leached by using supercritical water; and high zinc leaching rate and the deposition ofsuch metal as iron, copper and manganese can be realized at the same time.

The invention discloses a method of preparing high-purity cobalt sulfate from electrolytic manganese sulfide slag. The method comprises the following steps of (1) crushing and sieving; (2) oxidizing and leaching; (3) calcium removal; (4) manganese removal; (5) synchronous extraction of cobalt and nickel; (6) cobalt recovery: taking a cobalt-nickel rich organic phase, adding dilute sulfuric acid for reverse extraction to obtain a cobalt-nickel sulfuric acid solution and a neodecanoic acid organic phase, separating out the cobalt-nickel sulfuric acid solution, adding a fourth organic extracting agent formed by mixing saponified P507-Cyanex301 with sulfonated kerosene for extraction to obtain a cobalt-rich organic phase and a nickel sulfate solution, separating out the cobalt-rich organic phase, and adding sulfuric acid for reverse extraction to obtain a high-purity cobalt sulfate-rich solution and a P507-Cyanex301 organic phase; and (7) preparation of the high-purity cobalt sulfate. The method has the advantages that the method is simple and feasible, leaching of cobalt sulfate can be achieved, and production of hydrogen sulfide gas, use of an iron precipitation process and a method of removing calcium and magnesium ions through fluorine ion precipitation can be avoided.

The invention discloses a method for leaching and separating bismuth from blast furnace gas dust or/and mud. The method comprises the following steps: firstly, stirring and leaching blast furnace gas dust or/and mud according to a solid-liquid mass ratio of 1: (1-20) by using an oxalic acid-based eutectic solvent as a leaching agent to obtain a leachate and reaction residues; adjusting the pH value of the leachate by using a NaOH solution, uniformly stirring, standing to form zinc oxalate precipitate, carrying out solid-liquid separation to obtain precipitate and hydrolysate, washing and drying the precipitate to obtain a zinc oxalate byproduct, irradiating the hydrolysate by using an ultraviolet light source to enable an iron element in the hydrolysate to generate light-induced reduction reaction to form ferric oxalate precipitate, and filtering to obtain a ferric oxalate byproduct, wherein the filtrate is a high-purity bismuth-containing solution. According to the method, the high-purity bismuth-containing solution can be selectively separated from the blast furnace gas dust or/and mud so as to be used for producing a bismuth-containing compound with a high additional value, the process is simple, the leaching separation selectivity of the bismuth element is high, and the recycled product and the byproduct are good in economical efficiency.

The invention belongs to the field of national scarce resource recycling, and discloses a method for recycling indium in a waste liquid crystal display. The method for recycling the indium in the waste liquid crystal display comprises the following steps of (1) crushing the waste liquid crystal display into glass powder, and carrying out high-temperature leaching reaction in an acidic ionic liquidsystem; (2) carrying out solid-liquid separation on the reaction product obtained in the step (1), cooling and layering a leaching agent, and extracting to obtain an ion liquid organic phase containing the indium; and (3) reacting the ion liquid organic phase containing the indium obtained in the step (2) and an oxalic acid solution, fully vibrating, centrifugally layering to obtain an indium-containing oxalic acid solution on the upper layer and ionic liquid on the lower layer, and separating to obtain an oxalic acid-containing solution. According to the method for recycling the indium in the waste liquid crystal display provided by the invention, an acid leaching and extracting integration process is effectively realized, a process flow is simplified, the indium leaching separation efficiency is high, and the environment pollution is reduced; and meanwhile, the ionic liquid can be recycled, so that the usage amount of a chemical agent is reduced, and a new method is provided for waste treatment and recycle.

The invention discloses a waste storage battery dismantling processing technology which comprises the following steps: soaking a waste storage battery in sodium hydroxide aqueous solution, dischargingfor 1-2 h, then, fixing and dismantling the discharged waste storage battery shell to obtain an anode electrode grid plate, anode mud and a cathode electrode grid plate, processing the anode electrode grid plate, anode mud and the cathode electrode grid plate separately, and under the alkaline condition, taking 10% aqueous hydrogen peroxide solution as a strong oxidant to recycle arsenic and leadelements in anode mud under the pressurizing and warming condition. The waste storage battery dismantling processing technology does not belong to the wet process and the pyrogenic process of traditional lead anode mud treatment, avoid arsenic secondary pollution, and solves the technical problem about arsenic secondary pollution existing in the wet process and the pyrogenic process of traditional lead anode mud treatment when the storage battery anode mud contains multiple valuable metals including lead, bismuth, copper, arsenic and precious metal.

The invention belongs to the technical field of rare earth secondary resource recovery and recycling, and provides a method for recovering rare earth elements in rare earth molten salt electrolytic slag through a sub-molten salt method, which comprises the following steps: S1, treating the rare earth molten salt electrolytic slag through the sub-molten salt method to obtain an alkaline solution and reaction slag; s2, the reaction residues are subjected to acid leaching, and a leaching solution is obtained; s3, performing impurity removal and precipitation on the leachate to obtain rare earth salt precipitation; and S4, roasting the rare earth salt precipitate to obtain the rare earth oxide. Aiming at the technical problems existing in the chemical recovery process of the rare earth elements in the rare earth molten salt electrolytic slag, the rare earth elements in the rare earth molten salt electrolytic slag are recovered by the sub-molten salt method by utilizing the high chemical reactivity of the sub-molten salt medium, and the method has the advantages of high operability, simple process, low cost, low reaction temperature, no secondary pollution and the like; and efficient recycling of rare earth elements in the rare earth molten salt electrolytic slag is achieved.