The invention relates to a
ceramic ultrafiltration membrane composite oxidation adsorption
wastewater treatment method, which comprises that
wastewater to be treated sequentially passes through a
ceramic ultrafiltration membrane
filtration unit, an oxidation reaction unit and an adsorption purification unit. Wherein the average pore size of the
ceramic ultrafiltration membrane is 10-50nm, the
transmembrane pressure difference is 0.15-0.4 MPa, the
membrane surface flow velocity is 1.5-4.5 m / s, and efficient
solid-liquid separation is realized; the ultrafiltration
produced water enters an oxidation reaction unit and is subjected to
catalytic oxidation with
ozone and / or
hydrogen peroxide under the action of a supported catalyst, and the dosage of the
ozone is 40-100 mg / L; the oxidized
effluent is deeply purified through a modified
activated carbon adsorption column, and the empty
bed flow rate is 10-18 BV / h. The oxidation unit and the adsorption unit can be further integrated to form a series integrated reaction column. The
system has the functions of concentrated solution circulating oxidation, gas-water combined
backwashing, chemical enhanced cleaning and on-line monitoring and
automatic control. The method can effectively remove
refractory organic matters and
heavy metals, is stable in operation, is excellent in
effluent quality, and is suitable for advanced treatment of high-concentration industrial
wastewater.