High-rigidity PP (polypropylene) expanded beads and energy-saving preparation method thereof

A technology of foaming beads and polypropylene, applied in the direction of coating, etc., can solve the problems of unfavorable material recycling, increased post-processing costs, and easy pollution, and achieves difficult peeling, good compatibility, and low steam pressure Effect

Inactive Publication Date: 2016-08-24
WUXI HI TEC ENVIRONMENTAL MATERIAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This patent is to disperse non-crosslinked polypropylene resin particles in a dispersion medium containing organic peroxides to obtain a dispersion (water-based dispersion medium). The amount of organic peroxides in the dispersion is 100 parts by weight of polypropylene resin particles is 0.01-10 parts by weight. Due to the addition of peroxide crosslinking, on the one hand, the application of material recovery is unfavorable, and at the same time, the dispersion of peroxide in water is easy to cause pollution, and the cost of subsequent treatment will increase.

Method used

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  • High-rigidity PP (polypropylene) expanded beads and energy-saving preparation method thereof
  • High-rigidity PP (polypropylene) expanded beads and energy-saving preparation method thereof

Examples

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Effect test

Embodiment 1

[0023] A kind of high rigidity polypropylene foamed bead, comprise each component of following percentage by weight: High rigidity polypropylene 42 parts, the polypropylene of low molding pressure 58 parts, auxiliary agent 0.3 part; Wherein said high rigidity polypropylene is fusing point Polypropylene with a flexural modulus greater than 1.2MPa at a temperature greater than 140°C; the polypropylene with a low molding pressure is a polypropylene with a melting point less than 135°C. The melt index of rigid polypropylene and low molding pressure polypropylene blend is 5g / 10min.

[0024] Step 1: Mix high-rigidity polypropylene, polypropylene with low molding pressure and additives according to the weight ratio through an extruder, extrude, and draw wire, and then use pelletizing equipment to pelletize to form a modified polypropylene Microparticles, wherein the high-rigidity polypropylene is polypropylene with a melting point greater than 140°C, and the low-molding-pressure poly...

Embodiment 2

[0028] A kind of high-rigidity polypropylene foam beads, including the following components in weight percentage: 95 parts of high-rigidity polypropylene, 5 parts of polypropylene with low molding pressure, 2 parts of auxiliary agent; wherein the high-rigidity polypropylene is melting point Polypropylene with a flexural modulus greater than 1.2 MPa above 140°C; the polypropylene with low molding pressure is polypropylene with a melting point less than 130°C, and the melt index of the mixture of rigid polypropylene and polypropylene with low molding pressure is 15g / 10min .

[0029] Step 1: Mix high-rigidity polypropylene, polypropylene with low molding pressure and additives according to the weight ratio through an extruder, extrude, and draw wire, and then use pelletizing equipment to pelletize to form a modified polypropylene Microparticles, wherein the high-rigidity polypropylene is polypropylene with a melting point greater than 140°C, and the low-molding-pressure polypropy...

Embodiment 3

[0033] A kind of high rigidity polypropylene foamed bead, comprise each component of following percentage by weight: High rigidity polypropylene 70 parts, the polypropylene of low molding pressure 32 parts, auxiliary agent 1.2 parts; Wherein said high rigidity polypropylene is fusing point Polypropylene with a flexural modulus greater than 1.5 MPa at a temperature greater than 150°C; the polypropylene with a low molding pressure is a polypropylene with a melting point less than 130°C. High rigid polypropylene is propylene-butylene copolymerized polypropylene; low molding pressure polypropylene is ethylene-propylene-butylene terpolymerized polypropylene; the melt index of rigid polypropylene and low molding pressure polypropylene mixture is 8g / 10min.

[0034] Step 1: Mix high-rigidity polypropylene, polypropylene with low molding pressure and additives according to the weight ratio through an extruder, extrude, and draw wire, and then use pelletizing equipment to pelletize to fo...

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Abstract

The invention discloses high-rigidity PP (polypropylene) expanded beads. A formula of the high-rigidity PP expanded beads comprises the following components in parts by weight: 42 to 95 parts of high-rigidity PP, 5 to 58 parts of low-molding-pressure PP and 0.3 to 2 parts of assistant; the high-rigidity PP is PP with a melting point of over 140 DEG C and a bending modulus of over 1.2MPa; the low-molding-pressure PP is PP with a melting point of lower than 135 DEG C. according to the high-rigidity PP expanded beads disclosed by the invention, in the production process, two extruders are adopted to carry out double-layer co-extrusion, a middle core layer is formed by the high-rigidity PP, and a skin layer is formed by the low-molding-pressure PP; on one hand, high rigidity of the high-rigidity PP of the middle core layer cannot be damaged, so that the finally prepared PP expanded beads have high rigidity; on the other hand, both the middle center layer and the skin layer adopt PP (polypropylene) materials and have good compatibility, so that incompatibility between the PP material and a PS (Poly Styrene) material or the PP material and a PE material (Poly Ethylene) cannot be generated, the formed product is difficult to strip off, and in the forming process, a required steam pressure is low and only a forming pressure of 1.4 to 2.4kPa is required.

Description

technical field [0001] The invention relates to polypropylene foam beads, in particular to a high-rigidity polypropylene foam beads and an energy-saving preparation method thereof. Background technique [0002] In the prior art, high-rigidity polypropylene foamed beads (EPP) occupy a dominant position in the market. In various polypropylene foamed beads products, the higher the rigidity of EPP, the lower the consumption of EPP, which can The products of polypropylene foamed bead products tend to be lightweight; in the invention patent of CN103509203B, the invention patent of a kind of reinforced polypropylene foamed beads discloses a method with high strength (bending strength increased by 20 %), high-impact EPP beads (impact index performance increased by 10%), this patent has improved the rigidity of polypropylene foam beads to a certain extent, but in this patent, it is only easy to crystallize and high The melting point of two polypropylene resins is simply blended. The...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/14C08L23/16B29B9/06B29B9/16C08J9/16
CPCC08L23/14B29B9/06B29B9/16B29B2009/166C08J9/16C08J2323/14C08J2423/14C08L2203/14C08L2205/025
Inventor 曾佳刘缓缓黄芸朱民
Owner WUXI HI TEC ENVIRONMENTAL MATERIAL CO LTD
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