Preparation method and product of high-efficiency leaching and adsorbing material for Cd contaminated soil and wastes

A technology of polluted soil and adsorption materials, applied in the field of environmental engineering, can solve the problems of high cost of leaching and repair, single adsorption of heavy metals, and inability to remove heavy metals from soil, etc., and achieve the effect of rapid and efficient leaching and high adsorption capacity

Inactive Publication Date: 2017-05-31
TIANJIN TIANRUN YIKANG ENVIRONMENTAL PROTECTION TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, there are many remediation methods for soil heavy metal pollutants, generally including physical remediation, chemical remediation and biological remediation, but most remediation methods cannot achieve ideal results
[0003] Although the soil heavy metal chemical remediation method can achieve the purpose of temporary remediation, it cannot remove the heavy metals in the soil, and the chemical materials used are likely to cause soil compaction and other changes in physical and chemical properties; while the soil heavy metal bioremediation method is mainly for planting high enrichment Plants, this method has a long repair period and cannot achieve the purpose of rapid restoration, thus affecting the use of land; soil heavy metal physical restoration methods include leaching, guest soil, soil replacement and other methods. From the perspective of economy and efficiency, the leaching method For a more ideal repair method
However, the commonly used soil leaching adsorption materials have disadvantages such as high price, low adsorption capacity, and single adsorption of heavy metals, resulting in low soil leaching efficiency and high leaching repair costs.

Method used

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  • Preparation method and product of high-efficiency leaching and adsorbing material for Cd contaminated soil and wastes

Examples

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preparation example Construction

[0022] A method for preparing an efficient leaching adsorption material for Cd-contaminated soil and waste, the steps are:

[0023] (1) Attapulgite clay is dispersed in cetyltrimethylammonium bromide aqueous solution to form attapulgite clay suspension;

[0024] (2) Add ethanol to the attapulgite clay suspension, let it stand for a while to form a mixed solution;

[0025] (3) The mixed solution is placed in a disperser and stirred to become an attapulgite clay colloid;

[0026] (4) Add mercaptopropyltrimethoxysilane to the attapulgite clay colloid, and stir to form a mercapto-modified attapulgite clay gel;

[0027] (5) Air-dry the mercapto-modified attapulgite clay gel, and grind to obtain mercapto-modified attapulgite clay particles.

[0028] In the step (1), the concentration of the cetyltrimethylammonium bromide aqueous solution is 0.5%-2%, and the weight ratio of the cetyltrimethylammonium bromide aqueous solution to the attapulgite clay is 2-4:1.

[0029] The weight ra...

Embodiment 1

[0035] A method for preparing an efficient leaching adsorption material for Cd-contaminated soil and waste, the steps are:

[0036] (1) 450 parts of attapulgite clay are dispersed in 1800 parts of cetyltrimethylammonium bromide aqueous solution (concentration 0.5%) to form attapulgite clay suspension;

[0037] (2) Add 16.1 parts of ethanol to the attapulgite clay suspension, and let it stand for 20 hours to form a mixed solution;

[0038] (3) The mixed solution is placed in a disperser and stirred at a speed of 1500 rpm for 15 minutes to become an attapulgite clay colloid;

[0039] (4) Add 20.5 parts of mercaptopropyltrimethoxysilane to the attapulgite clay colloid under stirring conditions of 500 rpm, and stir for 17 minutes at a speed of 1500 rpm to form a mercapto-modified attapulgite clay gel;

[0040] (5) Air-dry the attapulgite clay gel at 20° C., and grind to obtain mercapto-modified attapulgite clay particles.

Embodiment 2

[0042] A method for preparing an efficient leaching adsorption material for Cd-contaminated soil and waste, the steps are:

[0043] (1) 450 parts of attapulgite clay are dispersed in 1700 parts of cetyltrimethylammonium bromide aqueous solution (concentration 0.7%) to form attapulgite clay suspension;

[0044] (2) Add 17 parts of ethanol to the attapulgite clay suspension, let it stand for 22 hours to form a mixed solution;

[0045] (3) The mixed solution is placed in a disperser and stirred at a speed of 1600 rpm for 14 minutes to become an attapulgite clay colloid;

[0046] (4) Add 22 parts of mercaptopropyltrimethoxysilane to the attapulgite clay colloid at a stirring condition of 700 rpm, and stir at a speed of 1600 rpm for 16 minutes to form a mercapto-modified attapulgite clay gel;

[0047] (5) Air-dry the attapulgite clay gel at 24° C., and grind to obtain mercapto-modified attapulgite clay particles.

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Abstract

The invention provides a preparation method of a high-efficiency leaching and adsorbing material for Cd contaminated soil and wastes and also discloses the high-efficiency leaching and adsorbing material prepared by the preparation method. The material has quicker and higher adsorption capacity for heavy metal Cd; besides, the material is low in price and easily-obtained and facilitates wide application of a leaching remediation method for heavy metal contaminated soil; meanwhile, sulfydryl (-HS) in sulfhydryl modified attapulgite clay serving as an adsorbing material can generate a stronger complexing action with heavy metal ions, and heavy metal is not easy to dissolute, so that the sulfhydryl modified attapulgite clay has important significance on repeated leaching and adsorbing; in addition, a pH value, obtained by measuring, of the sulfhydryl modified attapulgite clay is neutral and is relatively-stable, so the sulfhydryl modified attapulgite clay has no influence on leacheate or soil and better facilitates quick and efficient leaching.

Description

technical field [0001] The invention belongs to the technical field of environmental engineering, and in particular relates to a preparation method and product of an efficient leaching adsorption material for Cd-contaminated soil and waste. Background technique [0002] With the development of economy and the increase of population, environmental pollution has become a major problem that threatens the ecological balance and human health, especially the pollution of heavy metal Cd. At present, there are many remediation methods for soil heavy metal pollutants, generally including physical remediation, chemical remediation and biological remediation, but most remediation methods cannot achieve ideal results. [0003] Although the soil heavy metal chemical remediation method can achieve the purpose of temporary remediation, it cannot remove the heavy metals in the soil, and the chemical materials used are likely to cause soil compaction and other changes in physical and chemica...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J20/22B01J20/30B09C1/00B09C1/02
CPCB01J20/22B01J20/12B09C1/00B09C1/02
Inventor 于洋宋志廷
Owner TIANJIN TIANRUN YIKANG ENVIRONMENTAL PROTECTION TECH CO LTD
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