Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Thermal excitation delayed fluorescence main material based on phosphonic aryl derivatives, preparation method and application thereof

A technology of aryl derivatives and delayed fluorescence, which is applied in the fields of luminescent materials, chemical instruments and methods, semiconductor/solid-state device manufacturing, etc. Effects of Injecting Transport Capabilities, Inhibiting Interactions

Active Publication Date: 2017-06-13
HEILONGJIANG UNIV
View PDF4 Cites 8 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The present invention aims to solve the technical problem that existing planar thermally excited delayed fluorescent dye molecules are prone to quenching, resulting in low device efficiency, and provides a thermally excited delayed fluorescent host material based on phosphine heteroaryl derivatives and its preparation method and application

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Thermal excitation delayed fluorescence main material based on phosphonic aryl derivatives, preparation method and application thereof
  • Thermal excitation delayed fluorescence main material based on phosphonic aryl derivatives, preparation method and application thereof
  • Thermal excitation delayed fluorescence main material based on phosphonic aryl derivatives, preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

specific Embodiment approach 1

[0059] Embodiment 1: The structural formula of the thermally excited delayed fluorescence host material based on phosphine heteroaryl derivatives in this embodiment is denoted as DPDPA; or denoted as DPDPSA; or Where X=S or O, Y=S or O, when X=Y=S, it is recorded as DPDPS 2 A; when X=S, Y=O, it is recorded as DPDPSOA; when X=Y=O, it is recorded as DPDPO 2 A; or denoted as DPDPP; or denoted as DPDPSP; or Where X=S or O, Y=S or O, when X=Y=S, it is recorded as DPDPS 2 P; when X=S, Y=O, it is recorded as DPDPSOP; when X=Y=O, it is recorded as DPDPO 2 p.

specific Embodiment approach 2

[0060] Specific embodiment two: The preparation method of the thermally excited delayed fluorescence host material based on phosphine heteroaryl derivatives described in specific embodiment one is as follows:

[0061] Add o-dibromoaryl compound, phenylphosphine dichloride, and n-butyllithium into tetrahydrofuran (THF) at a molar ratio of 1:(1~1.5):(2~4), under argon protection Under the condition of -60~-85℃, react for 1~3 hours, then pour into water, extract with dichloromethane to obtain the organic layer, dry the organic layer liquid, directly purify or vulcanize / and oxidize After further purification, a thermally excited delayed fluorescence host material based on phosphine heteroaryl derivatives is obtained; wherein the o-dibromoaryl compound is o-dibromobenzene or 2,3-dibromonaphthalene.

specific Embodiment approach 3

[0062] Specific embodiment three: the difference between this embodiment and specific embodiment two is that the vulcanization process is: adding sulfur powder to the organic layer liquid, stirring and reacting at a temperature of 15-30°C for 0.5-2 hours, Complete vulcanization. Others are the same as in the second embodiment.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
Thicknessaaaaaaaaaa
Thicknessaaaaaaaaaa
Thicknessaaaaaaaaaa
Login to View More

Abstract

The invention provides a thermal excitation delayed fluorescence main material based on phosphonic aryl derivatives, a preparation method and an application thereof and relates to the thermal excitation delayed fluorescence main material, the preparation method and the application thereof. The invention aims to solve the technical problem of low device efficiency caused by the easiness in quenching of the molecules of the present planar thermal excitation delayed fluorescence dye. The structural formula of the thermal excitation delayed fluorescence main material provided by the invention is as follows. The preparation method comprises the following steps: adding an o-dibromo aryl compound, dichlorophenyl phosphine and n-butyllithium into tetrahydrofuran; uniformly mixing and then reacting under argon protection; pouring into water; extracting with dichloromethane, thereby acquiring an organic layer; after drying, directly purifying or vulcanizing / and oxidizing and then re-purifying, thereby acquiring the thermal excitation delayed fluorescence main material based on phosphonic aryl derivatives, wherein the o-dibromo aryl compound is o-dibromo-benzene or 2,3-dibromo naphthalene. The thermal excitation delayed fluorescence main material based on phosphonic aryl derivatives is applied to a thermal excitation delayed fluorescence electrofluorescence device.

Description

technical field [0001] The invention relates to a heat-excited delayed fluorescent host material and a preparation method and application thereof. Background technique [0002] Due to its low starting voltage and high luminous efficiency, organic light-emitting diodes have attracted extensive research. As the third-generation flat-panel display and lighting technology, organic light-emitting diodes generally use phosphorescent dyes to construct phosphorescent electroluminescence. , but because the construction of phosphorescent dyes is often accompanied by the presence of noble metals, this increases the cost of preparation and is not environmentally friendly. Therefore, there is an urgent need for other types of dyes to replace phosphorescent dyes. Recently, thermally excited delayed fluorescence technology, known as the third generation of organic electroluminescent technology, has made great research progress. Thermally excited delayed fluorescent dyes can jump from thei...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): C07F9/6568C09K11/06H01L51/50H01L51/54
CPCC09K11/06C07F9/65683C07F9/65685C09K2211/1096H10K85/657H10K50/121H10K50/11H10K2101/10
Inventor 许辉杨鹤韩春苗
Owner HEILONGJIANG UNIV
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com