Trace element water-soluble composite fertilizer in fulvic acid and preparation method thereof
A medium-trace element, water-soluble technology, applied in urea compound fertilizer, ammonium orthophosphate fertilizer, alkaline orthophosphate fertilizer, etc., can solve problems such as low nutrient utilization rate, unreasonable fertilizer ratio, and soil fertility decline , to achieve the effect of reducing nutrient loss, improving fertilizer utilization rate and improving fertility
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Embodiment 1
[0028] A water-soluble compound fertilizer with trace elements in fulvic acid, which is made of the following raw materials in weight ratio: 200 parts of urea, 100 parts of monoammonium phosphate, 130 parts of potassium sulfate, 10 parts of superphosphate, 40 parts of fulvic acid 1 part, 1 part of pullulan-polyglutamic acid cross-linked polymer, 5 parts of sodium selenite, 10 parts of EDTA, 1 part of superfine oyster powder, 5 parts of magnesium sulfate, 1 part of compound microbial agent;
[0029] The pullulan-polyglutamic acid cross-linked polymer is prepared by the following method: the pullulan solution is added dropwise to the polyglutamic acid solution at a rate of 5 drops / s, and at 30° C. Stir the reaction for 2 hours, precipitate the mixed solution with absolute ethanol, collect the precipitate by vacuum filtration, dissolve the precipitate with deionized water, place it in a dialysis bag for dialysis for 2 hours, and freeze-dry the dialysis retentate to obtain pullulan...
Embodiment 2
[0041] A water-soluble compound fertilizer with trace elements in fulvic acid, which is made of the following raw materials in the weight ratio: 400 parts of urea, 200 parts of monoammonium phosphate, 140 parts of potassium sulfate, 20 parts of superphosphate, and 60 parts of fulvic acid 10 parts of pullulan-polyglutamic acid cross-linked polymer, 10 parts of sodium selenite, 20 parts of EDTA, 5 parts of superfine oyster powder, 15 parts of magnesium sulfate, 10 parts of compound microbial agent;
[0042] The pullulan-polyglutamic acid cross-linked polymer is prepared by the following method: the pullulan solution is added dropwise to the polyglutamic acid solution at a rate of 5 drops / s, and at 30° C. Stir the reaction for 2 hours, precipitate the mixed solution with absolute ethanol, collect the precipitate by vacuum filtration, dissolve the precipitate with deionized water, place it in a dialysis bag for dialysis for 2 hours, and freeze-dry the dialysis retentate to obtain p...
Embodiment 3
[0054] A water-soluble compound fertilizer with trace elements in fulvic acid, which is made of the following raw materials in weight ratio: 300 parts of urea, 150 parts of monoammonium phosphate, 135 parts of potassium sulfate, 15 parts of superphosphate, and 50 parts of fulvic acid 5 parts, 5 parts of pullulan-polyglutamic acid cross-linked polymer, 8 parts of sodium selenite, 18 parts of EDTA, 3 parts of superfine oyster powder, 10 parts of magnesium sulfate, 5 parts of compound microbial agent.
[0055] The pullulan-polyglutamic acid cross-linked polymer is prepared by the following method: the pullulan solution is added dropwise to the polyglutamic acid solution at a rate of 5 drops / s, and at 30° C. Stir the reaction for 2 hours, precipitate the mixed solution with absolute ethanol, collect the precipitate by vacuum filtration, dissolve the precipitate with deionized water, place it in a dialysis bag for dialysis for 2 hours, and freeze-dry the dialysis retentate to obtain...
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