High wet-skid resistance elastomer nanocomposite for solid vehicle tire and preparation method
A technology of nanocomposite materials and rickshaw tires, which is applied in the field of high wet skid resistant elastomer nanocomposite materials and their preparation
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Embodiment 1
[0071] The preparation process of the high anti-wet skid elastomer nanocomposite in this embodiment is as follows:
[0072] 1) Preparation of naphthalene lithium initiator: with reference to the literature "Research on Negative Dilithium Initiator System" (Han Bingyong et al., Synthetic Rubber Industry, 1999-01-15, 22 (1): 5-8) Preparation: the polymerization bottle was pumped Vacuum, flame baking and filling with argon are repeated 3 times, then add naphthalene, lithium, polar additives, benzene, react at room temperature, finally add butadiene or isoprene, and filter to get naphthalene lithium short chain initiator. The initiator concentration was calibrated by double titration method, and the initiator concentration was 1mol / L.
[0073] 2) Distillation of ethylene oxide: Get 100g of calcium hydride and grind it into powder, add it to 1L of ethylene oxide and soak it for 24h, and steam the ethylene oxide at room temperature under a nitrogen atmosphere.
[0074] 3) Preparati...
Embodiment 2
[0079] The preparation process of the high anti-wet skid elastomer nanocomposite in this embodiment is as follows:
[0080] 1) Preparation of naphthalene lithium initiator: prepare with reference to the literature "Research on Anion Dilithium Initiator System" (Han Bingyong et al., Synthetic Rubber Industry, 1999-01-15, 22(1): 5-8), and the polymerization bottle was pumped Vacuum, flame baking and filling with argon are repeated 3 times, then add naphthalene, lithium, polar additives, benzene, react at room temperature, finally add butadiene or isoprene, and filter to get naphthalene lithium short chain initiator. The initiator concentration was calibrated by double titration method, and the initiator concentration was 1mol / L.
[0081] 2) Distillation of ethylene oxide: Get 100g of calcium hydride and grind it into powder, add it to 1L of ethylene oxide and soak it for 24h, and steam the ethylene oxide at room temperature under a nitrogen atmosphere.
[0082]3) Preparation of...
Embodiment 3
[0087] The preparation process of the example high anti-wet skid elastomer nanocomposite of the present embodiment is as follows:
[0088] 1) Preparation of naphthalene lithium initiator: prepare with reference to the literature "Research on Anion Dilithium Initiator System" (Han Bingyong et al., Synthetic Rubber Industry, 1999-01-15, 22(1): 5-8), and the polymerization bottle was pumped Vacuum, flame baking and filling with argon are repeated 3 times, then add naphthalene, lithium, polar additives, benzene, react at room temperature, finally add butadiene or isoprene, and filter to get naphthalene lithium short chain initiator. The initiator concentration was calibrated by double titration method, and the initiator concentration was 0.8mol / L.
[0089] 2) Distillation of ethylene oxide: Get 100g of calcium hydride and grind it into powder, add it to 1L of ethylene oxide and soak it for 24h, and steam the ethylene oxide at room temperature under a nitrogen atmosphere.
[0090]...
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