Dye-sensitized photoelectric conversion element

A technology for photoelectric conversion elements and photoelectric conversion units, applied in the field of dye-sensitized photoelectric conversion elements, can solve problems such as slow reduction in power generation performance, and achieve the effects of excellent light resistance, excellent photoelectric conversion characteristics and light resistance, and excellent photoelectric conversion characteristics.

Active Publication Date: 2018-01-26
THE FUJIKURA CABLE WORKS LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] In the dye-sensitized photoelectric conversion element, as the oxide semiconductor layer, for example, TiO 2 At the same time, due to the ultraviolet rays contained in the incident light, the oxide semiconductor layer produces photocatalysis and promotes the decomposition of photosensitizing dyes and organic substances in the electrolyte, so the power generation performance may gradually decrease

Method used

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  • Dye-sensitized photoelectric conversion element
  • Dye-sensitized photoelectric conversion element

Examples

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Embodiment 1

[0117] Hereinafter, although an Example is given and the content of this invention is demonstrated more concretely, this invention is not limited to a following Example.

Embodiment 1~9 and comparative example 1~3

[0119]

[0120] (1) Electrolyte

[0121] Electrolytes 1 to 4 having the following compositions were prepared.

[0122] Electrolyte 1

[0123] Iodine (I 2 )0.002M

[0124] 1,2-Dimethyl-3-propylimidazole Iodide (DMPImI) 0.6M

[0125] n-Butylbenzimidazole (NBB) 0.1M

[0126] Solvent composed of 3-methoxypropionitrile (MPN)

[0127] Electrolyte 2

[0128] 1-Hexyl-3-methylimidazolium iodide (HMImI) 0.6M

[0129] n-Methylbenzimidazole (NMB) 0.3M

[0130] Guanidine Thiocyanate (GuSCN) 0.1M

[0131] Solvent composed of 3-methoxypropionitrile (MPN)

[0132] Electrolyte 3

[0133] Iodine (I 2 )0.005M

[0134] 1,2-Dimethyl-3-propylimidazole Iodide (DMPImI) 0.6M

[0135] n-Butylbenzimidazole (NBB) 0.1M

[0136] Solvent composed of 3-methoxypropionitrile (MPN)

[0137] Electrolyte 4

[0138] Iodine (I 2 )0.01M

[0139] 1,2-Dimethyl-3-propylimidazole Iodide (DMPImI) 0.6M

[0140] n-Butylbenzimidazole (NBB) 0.1M

[0141]Solvent composed of 3-methoxypropion...

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Abstract

Provided is a dye-sensitized photoelectric conversion element provided with at least one dye-sensitized photoelectric conversion cell. The dye-sensitized photoelectric conversion cell in this dye-sensitized photoelectric conversion element is provided with: a first electrode substrate provided with a transparent substrate, and a transparent conductive film provided on the transparent substrate; asecond electrode which faces the first electrode substrate; an oxide semiconductor layer provided to the first electrode substrate or the second electrode; a photosensitized dye adsorbed on the oxidesemiconductor layer; and an electrolyte provided between the first electrode substrate and the second electrode. The first electrode substrate is further provided with an ultraviolet absorption layer.The transmittance TA(%) of the electrolyte at a wavelength corresponding to the band gap of the oxide semiconductor forming the oxide semiconductor layer, and the transmittance TB(%) of the first electrode substrate at said wavelength satisfy formula (1), namely 0.01*TA*TB*42, and formula (2), namely 3.5<=TB<=70.

Description

technical field [0001] The invention relates to a dye-sensitized photoelectric conversion element. Background technique [0002] The dye-sensitized photoelectric conversion element was developed by Graetzel in Switzerland, etc. It has the advantages of high photoelectric conversion efficiency and low manufacturing cost, so it is a new generation of photoelectric conversion element that has attracted much attention. [0003] The dye-sensitized photoelectric conversion element generally has at least one dye-sensitized photoelectric conversion unit, and the dye-sensitized photoelectric conversion unit includes a first electrode substrate having a transparent substrate and a transparent conductive film provided on the transparent substrate, and a first electrode substrate opposite to the first electrode substrate. The second electrode provided, the oxide semiconductor layer provided on the first electrode substrate or the second electrode, and the photosensitizing dye adsorbed o...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01G9/20
CPCH01G9/20Y02E10/542H01G9/2013H01G9/2031H01G9/2059H10K50/865H01G9/2004H01G9/204
Inventor 中真实
Owner THE FUJIKURA CABLE WORKS LTD
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