Preparation method and application of in-situ nitrogen-doped carbon microsphere adsorbent

A microsphere adsorption, nitrogen and carbon technology, applied in chemical instruments and methods, adsorption water/sewage treatment, other chemical processes, etc., can solve the problems of poor universality, small adsorption capacity, slow adsorption rate of water treatment adsorbents, etc. Achieve the effect of solving the bottleneck problem, large adsorption capacity and broad market application prospects

Active Publication Date: 2018-02-16
HARBIN INST OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This patented technology improves upon existing methods for removing harmful substances from contaminated waters through strong binding between specific atoms or molecules on its surface. It also simplifies the manufacturing processes needed during production while maintaining their stability over multiple uses. Overall, this new approach provides better results compared to previous techniques that were previously effective at reducing certain types of chemical compounds (like pesticides).

Problems solved by technology

This patented describes various ways for improving the performance of activate carbons when removing harmful substances from contaminating waters or other liquids containing these compounds. These improvements can be achieved through different types of activation processes that enhance their ability to remove specific components while reducing their negative effects on human body systems.

Method used

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  • Preparation method and application of in-situ nitrogen-doped carbon microsphere adsorbent
  • Preparation method and application of in-situ nitrogen-doped carbon microsphere adsorbent
  • Preparation method and application of in-situ nitrogen-doped carbon microsphere adsorbent

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specific Embodiment approach 1

[0038] Specific embodiment 1: This embodiment is a method for preparing an in-situ nitrogen-doped carbon microsphere adsorbent, which is specifically prepared according to the following steps:

[0039] 1. Synthesis of nitrogen-containing polymer microspheres:

[0040] ①. Add a buffer and a nitrogen-containing polymer monomer to the ethanol solution to obtain a reaction solution; then use a hydrogen chloride aqueous solution with a concentration of 100 mmol / L to 200 mmol / L to adjust the pH of the reaction solution to 7.5 to 9 to obtain the pH value A reaction solution with a pH of 7.5-9; the reaction solution with a pH of 7.5-9 is reacted at a temperature of 20°C to 40°C and a rotation speed of 50r / min-100r / min for 36h-72h to obtain a reaction product;

[0041] The volume ratio of absolute ethanol to water in the ethanol solution described in step 1 ① is 1:(3-8);

[0042] The concentration of the nitrogen-containing polymer monomer in the reaction solution described in step 1 ① is 1 g / ...

specific Embodiment approach 2

[0060] Embodiment 2: The difference between this embodiment and Embodiment 1 is that the shielding gas in step 2 is nitrogen or argon, and the flow rate of the shielding gas is 100 mL / min to 300 mL / min. The other steps are the same as in the first embodiment.

specific Embodiment approach 3

[0061] Specific embodiment three: This embodiment is different from specific embodiment one or two in that the protective gas in step three is nitrogen or argon, and the flow rate of the protective gas is 100 mL / min to 300 mL / min. The other steps are the same as the first or second embodiment.

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Abstract

The invention provides a preparation method and an application of an in-situ nitrogen-doped carbon microsphere adsorbent, relates to a preparation method and an application of an adsorbent and aims tosolve the problems of low adsorption rate, small adsorption capacity and poor universality of an existing water treatment adsorbent. The method comprises steps as follows: step one, synthesizing nitrogen-containing polymer microspheres; step two, performing high-temperature carbonization; step three, performing high-temperature alkaline activation to obtain the in-situ nitrogen-doped carbon microsphere adsorbent. A method for purifying micro-pollution emergency water comprises steps as follows: the in-situ nitrogen-doped carbon microsphere adsorbent is added to the micro-pollution emergency water, the water is stirred and subjected to a reaction for 2-5 min, and after the adsorbent is filtered, the treated water is obtained. A method for enriching trace pollutants in water by the in-situnitrogen-doped carbon microsphere adsorbent comprises steps as follows: the in-situ nitrogen-doped carbon microsphere adsorbent is added to water containing the trace pollutants, the water is stirredand subjected to a reaction for 2-5 min, and the treated water is obtained. The in-situ nitrogen-doped carbon microsphere adsorbent can be obtained.

Description

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Claims

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Application Information

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Owner HARBIN INST OF TECH
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