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High-temperature-resistant stainless steel

A stainless steel and high temperature resistant technology, applied in the field of high temperature resistant stainless steel, can solve the problems of coarse grains, poor high temperature steam corrosion resistance, inability to meet the material requirements of ultra-supercritical boilers, and achieve good creep strength and excellent toughness. Effect

Active Publication Date: 2018-06-29
TAIZHOU XINLONGXIANG METAL PROD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Existing high-temperature-resistant stainless steel grades and their steel pipes do not meet the above requirements, such as 1Cr18Ni9 used in subcritical units and 1Cr19Ni11Nb stainless steel and steel pipes widely used in supercritical units. Due to their low high-temperature strength, the finished steel pipes have coarse grains (Generally 4-7 grades), poor high temperature steam corrosion resistance and other shortcomings, can not meet the requirements of ultra-supercritical boilers for the use of materials

Method used

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  • High-temperature-resistant stainless steel
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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0045] (1) Melting

[0046] Pour the stainless steel melt with a carbon content of 0.7% and a temperature of 1570°C melted in an intermediate frequency induction furnace with a frequency of 1150Hz and a capacity of 180Kg into the AOD furnace;

[0047] (2) De-C

[0048] Top-blown oxygen for de-C treatment, AOD blowing nitrogen for stirring, adding lime 70Kg / t steel and dolomite 15Kg steel during the de-C process, comparing the chromium content of the mixed molten steel with the standard chromium content, and fine-tuning the content;

[0049] (3) Restoration

[0050] Add ferrosilicon 10Kg / t steel, lime 12Kg / t steel, CaF into AOD furnace 2 10Kg / t steel for reduction and desulfurization of molten steel;

[0051] (4) Slag removal, slag adjustment, and adjustment of molten steel composition

[0052] After reduction, carry out slag removal, adjust the slag basicity, measure the temperature of molten steel, and take samples to analyze the content of alloy elements in molten steel...

Embodiment 2

[0065] The manufacture method of high temperature resistant stainless steel, it comprises the following sequential steps:

[0066] (1) Melting

[0067] Pour the stainless steel melt with a carbon content of 1% and a temperature of 1580°C melted in an intermediate frequency induction furnace with a frequency of 1150Hz and a capacity of 180Kg into the AOD furnace;

[0068] (2) De-C

[0069] Top-blown oxygen for de-C treatment, AOD blowing nitrogen for stirring, adding lime 75Kg / t steel and dolomite 18Kg / t steel during the de-C process, comparing the chromium content of the mixed molten steel with the standard chromium content, and fine-tuning the content;

[0070] (3) Restoration

[0071] Add ferrosilicon 12.5Kg / t steel, lime 12.5Kg / t steel, CaF into AOD furnace 2 12.5Kg / t for reduction and desulfurization of molten steel;

[0072] (4) Slag removal, slag adjustment, and adjustment of molten steel composition

[0073] After reduction, carry out slag removal, adjust the slag...

Embodiment 3

[0086] (1) Melting

[0087] Pour the stainless steel melt with a carbon content of 1.2% and a temperature of 1590°C melted in an intermediate frequency induction furnace with a frequency of 1800Hz and a capacity of 260Kg into the AOD furnace;

[0088] (2) De-C

[0089] Top-blown oxygen for de-C treatment, AOD blowing nitrogen for stirring, adding lime 80Kg / t steel and dolomite 20Kg / t steel during de-C, comparing the chromium content of the mixed molten steel with the standard chromium content, and fine-tuning the content;

[0090] (3) Restoration

[0091] Add ferrosilicon 15Kg / t steel, lime 15Kg / t steel, CaF into AOD furnace 2 15Kg / t for reduction and desulfurization of molten steel;

[0092] (4) Slag removal, slag adjustment, and adjustment of molten steel composition

[0093] After reduction, carry out slag removal, adjust the slag basicity, measure the temperature of molten steel, and take samples to analyze the content of alloy elements in molten steel. According to t...

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Abstract

The invention relates to high-temperature-resistant stainless steel, which is prepared from the components in percentage by mass: 0.01 to 0.05 percent of C, 0.10 to 0.3 percent of Si, 2.10 to 2.50 percent of Mn, less than or equal to 0.0020 percent of S, less than or equal to 0.002 percent of P, 0.01 to 0.02 percent of Al, 19.0 to 22.0 percent of Ni, 22.0 to 23.50 percent of Cr, 0.01 to 0.02 percent of Nb, 0.050 to 0.60 percent of Ta, 0.001 to 0.20 percent of Nd, 0.0002 to 0.00050 percent of B, 0.03 to 0.05 percent of N, 0.02 to 0.05 percent of rare earth Ce, and the balance iron and inevitable impurities, wherein a value obtained by dividing the content of the Nb to the content of the Ta is 4.2 to 5.5, and Ta plus 0.5Nd is equal to 0.050 to 0.70 percent. The austenite grain size is 20 to25 micrometers.

Description

technical field [0001] The invention relates to high-temperature resistant stainless steel, in particular to high-temperature resistant stainless steel used in high-temperature and strong oxidizing environments such as boiler tubes for coal power generation. Background technique [0002] Among various energy resources in my country, coal resources are the most abundant. Coal-fired thermal power generation units account for more than 75% of the total capacity of generating units, occupying a dominant position. In recent years, with the rapid development of my country's national economy, the demand for electricity has also increased significantly. The development of high-parameter, large-capacity ultra-supercritical power generation technology has become the only way for my country's thermal power units to improve energy utilization and reduce pollutant emissions. However, increasing the parameters and capacity of thermal power units puts forward very high requirements on the...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C38/58C22C38/02C22C38/06C22C38/48C22C38/54C21C7/068C21C7/064C22C33/06C21D8/00
CPCC21C7/0006C21C7/064C21C7/068C21D8/005C22C33/06C22C38/001C22C38/005C22C38/02C22C38/06C22C38/48C22C38/54C22C38/58
Inventor 周弛逍
Owner TAIZHOU XINLONGXIANG METAL PROD