water-based nail polish
A nail polish and water-based technology, which is applied in the field of water-based nail polish, can solve the problems that water-based nail polish cannot take into account the peelability of the entire sheet, matte anti-scratch properties, etc.
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Embodiment 1
[0046] Preparation of silicone-modified water-based polyurethane dispersion: Add polyethylene glycol (molecular weight 1000) and sandan oil into a three-necked flask at a molar ratio of 2:1, raise the temperature to 100°C, remove the water in the system by vacuuming, and cool down Standby; add 222g IPDI into an empty three-necked flask, start stirring, and heat up to 70°C; then add 370g of the dried mixture of the above-mentioned polyethylene glycol and sandan oil to IPDI, after 30min dropwise, continue the reaction, and add Add 100ml methyl ethyl ketone to the system and react at 70°C for 2.5h to generate a prepolymer with -NCO terminal group; measure the value of -NCO to meet the requirements.
[0047] According to the molar ratio of unreacted NCO to N-methyldiethanolamine in the reaction system is 4:1, N-methyldiethanolamine is added dropwise, and the chain extension reaction is continued at 70°C for 2 hours to obtain cationic end-NCO polyurethane; detect NCO After reaching...
Embodiment 2
[0057] The preparation of organosilicon modified aqueous polyurethane dispersion is the same as embodiment 1;
[0058] Preparation of water-based nail polish:
[0059] Weigh each component according to the proportion, mix and disperse organosilane-modified polyurethane dispersion and water-based acrylic emulsion for 10 minutes at a speed of 300 rpm, then add optional wetting and leveling agent, defoaming agent under stirring Agent, film-forming aid, thickener, deionized water, stirred for 10 minutes, then added pigment and optional matting agent, adjusted the speed to 600 rpm, and stirred for 15 minutes to obtain water-based nail polish.
[0060] The ingredients and content are as follows:
[0061] product name parts by mass Silicone modified waterborne polyurethane dispersion 40 Hydroxyl modified pure acrylic emulsion (molecular weight 5000) 20 Wetting and leveling agent BYK190 2 Defoamer Airex 901W 2 Zinc Chrome Yellow 4 Matting...
Embodiment 3
[0065] The preparation of organosilicon modified aqueous polyurethane dispersion is with embodiment 1;
[0066] Preparation of water-based nail polish:
[0067] Weigh each component according to the proportion, mix and disperse organosilane-modified polyurethane dispersion and water-based acrylic emulsion for 10 minutes at a speed of 300 rpm, then add optional wetting and leveling agent, defoaming agent under stirring Agent, film-forming aid, thickener, deionized water, stirred for 10 minutes, then added pigment and optional matting agent, adjusted the speed to 600 rpm, and stirred for 15 minutes to obtain water-based nail polish.
[0068] The ingredients and content are as follows:
[0069] product name parts by mass Silicone modified waterborne polyurethane dispersion 40 Hydroxyl modified pure acrylic emulsion (molecular weight 6000) 20 Wetting and leveling agent Silok 332 2 Defoamer BYK028 2 Titanium cobalt green 4 Matting agen...
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