Processes and compositions for improving corrosion performance of zirconium oxide pretreated zinc surfaces
A composition, technology of zinc surface, applied in multi-step coating method and bath composition used therein, in the field of cyclic corrosion, can solve the problems of inability to provide, good corrosion resistance, inability to provide metal objects and the like
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Embodiment 1
[0083] Test methods include:
[0084] Method 1 Bonderite 958 (commercially available zinc phosphate: control)
[0085] Method 2 TD-1323-HB / HC standard method (control)
[0086] Method 3 Alkaline Co / Fe pre-cleaner + TD-1323-HB / HC
[0087] Method 4 Fe-containing cleaner + TD-1323-HB / HC
[0088] Method 5 Contains Co / Fe detergent + TD-1323-HB / HC
[0089] *TD-1323-HB / HC is a commercially available zirconia pretreatment bath.
[0090] Standard (12"x4") test panels were obtained from ACT Laboratories, Hillsdale, Michigan USA; cold rolled steel (CRS), electrogalvanized steel (EG), aluminum 6111 (AL6111), hot dip galvanized steel (HDG). Samples of each of the four substrates were processed according to one of the following methods. The method steps used to test the pre-cleaner are as follows:
[0091] Method 1 (control) Bonderite 958
[0092] 1. Parco Cleaner 1533 – 120 seconds (spray)
[0093] 2. Wash with warm water - 30 seconds (spray)
[0094] 3. Fixodine Z8-30 seconds (...
Embodiment 2
[0122] Several proposed alkaline pre-cleaner formulations were tested. The concentrate formulation is shown in Table 3 below.
[0123] table 3
[0124]
[0125] Formulations 1A, 2A, 4A, and 5A used Co and Fe, and Formulations 3A and 6A used Fe only. Formulations 4A-6A used added silicate and Formulations 1A-6A contained no phosphate. Formulations 1A and 2A were similar to Formulations 4A and 5A, but with different levels of complexing agent.
[0126] Standard (12"x4") test panels were obtained from ACT Laboratories, Hillsdale, Michigan USA; cold rolled steel (CRS), electrogalvanized steel (EG), aluminum 6111 (AL6111), hot dip galvanized steel (HDG). The method steps are summarized in Table 5 below. For each concentration and time in Table 4, three panels of each of the four substrates were processed.
[0127] Table 4
[0128]
[0129] Table 5: Method steps:
[0130]
[0131] test panel using DuPont's VI electrophoretic coating (e-coat) performs wet-on-wet ele...
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